Occurrences, uses, and properties of chromium
- PMID: 9380835
- DOI: 10.1006/rtph.1997.1132
Occurrences, uses, and properties of chromium
Abstract
Chromium is the 21st most abundant element in the Earth's crust with a mean concentration in United States soils of about 40 mg/kg. Although it exists in several oxidation states, the zero, trivalent, and hexavalent states are the most important in commercial products and the environment. Nearly all naturally occurring chromium is in the trivalent state, usually in combination with iron or other metal oxides. Although only about 15% of the chromium mined is used in the manufacture of chemicals, most applications of chromium utilize the chemistry of chromium. For instance, the "stainless" nature of stainless steel is due to the chemical properties of the chromium oxides which form on the surface of the alloy. Similarly, the protective properties of chrome plating of metals, chromated copper arsenate (CCA) treatment of wood, and chrome tanning of leather are all dependent on chromium chemistry. The key to these uses is that under typical environmental and biological conditions of pH and oxidation-reduction potential, the most stable form of chromium is the trivalent oxide. This form has very low solubility and low reactivity resulting in low mobility in the environment and low toxicity in living organisms. In this paper the chemical properties of chromium are discussed for the major commercial products in the context of the Eh-pH diagram for chromium.
Copyright 1997 Academic Press.
Similar articles
-
Bioaccessibility studies of ferro-chromium alloy particles for a simulated inhalation scenario: a comparative study with the pure metals and stainless steel.Integr Environ Assess Manag. 2010 Jul;6(3):441-55. doi: 10.1002/ieam.32. Integr Environ Assess Manag. 2010. PMID: 20821706
-
Particles, sweat, and tears: a comparative study on bioaccessibility of ferrochromium alloy and stainless steel particles, the pure metals and their metal oxides, in simulated skin and eye contact.Integr Environ Assess Manag. 2010 Jul;6(3):456-68. doi: 10.1002/ieam.66. Integr Environ Assess Manag. 2010. PMID: 20821707
-
Implication of chromium speciation on disposal of discarded CCA-treated wood.J Hazard Mater. 2006 Feb 6;128(2-3):280-8. doi: 10.1016/j.jhazmat.2005.08.004. Epub 2005 Sep 13. J Hazard Mater. 2006. PMID: 16165268
-
Chemistry and toxicology of building timbers pressure-treated with chromated copper arsenate: a review.J Appl Toxicol. 2005 Jan-Feb;25(1):1-7. doi: 10.1002/jat.1005. J Appl Toxicol. 2005. PMID: 15669035 Review.
-
Activated carbons and low cost adsorbents for remediation of tri- and hexavalent chromium from water.J Hazard Mater. 2006 Sep 21;137(2):762-811. doi: 10.1016/j.jhazmat.2006.06.060. Epub 2006 Jun 29. J Hazard Mater. 2006. PMID: 16904258 Review.
Cited by
-
Successive use of microorganisms to remove chromium from wastewater.Appl Microbiol Biotechnol. 2020 May;104(9):3729-3743. doi: 10.1007/s00253-020-10533-y. Epub 2020 Mar 14. Appl Microbiol Biotechnol. 2020. PMID: 32172324 Review.
-
Acute particulate hexavalent chromium exposure induces DNA double-strand breaks and activates homologous recombination repair in rat lung tissue.Toxicol Sci. 2024 Sep 1;201(1):1-13. doi: 10.1093/toxsci/kfae076. Toxicol Sci. 2024. PMID: 38867691
-
Hydrogeochemical processes and impact of tanning industries on groundwater quality in Ambur, Vellore district, Tamil Nadu, India.Environ Sci Pollut Res Int. 2016 Dec;23(23):24364-24383. doi: 10.1007/s11356-016-7639-4. Epub 2016 Sep 21. Environ Sci Pollut Res Int. 2016. PMID: 27655619
-
Comparative behavior of two gram positive Cr6+ resistant bacterial strains Bacillus aerius S1 and Brevibacterium iodinum S2 under hexavalent chromium stress.Biotechnol Rep (Amst). 2019 Jan 15;21:e00307. doi: 10.1016/j.btre.2019.e00307. eCollection 2019 Mar. Biotechnol Rep (Amst). 2019. PMID: 30705835 Free PMC article.
-
Encapsulation of Pannonibacter phragmitetus LSSE-09 in alginate-carboxymethyl cellulose capsules for reduction of hexavalent chromium under alkaline conditions.J Ind Microbiol Biotechnol. 2011 Oct;38(10):1709-18. doi: 10.1007/s10295-011-0960-5. Epub 2011 Mar 27. J Ind Microbiol Biotechnol. 2011. PMID: 21442414
Publication types
MeSH terms
Substances
LinkOut - more resources
Full Text Sources