VEER NARMAD SOUTH GUJARAT UNIVERSITY, SURAT

Syllabus for on 2019

F. Y. B.Sc. Chemistry; Semester – I
(Paper : 01 : Inorganic & Physical Chemistry)
Total Hours : 30h

UNIT : 01 : SOLID STATE 10 h

Definition of space lattice, Unit cell, Difference between crystalline and amorphous state,
types of crystals with illustrations, Law of crystallography. Steno’s law and laws of
symmetry, lattice planes, Miller indices, Bravais indices, type of cubic system,
diagrammatic representation of cubic system and d100, d110, d111 planes, Bragg’s equation
(X-ray diffraction), Crystal structure of NaCl, KCl.(Numerical based on Bragg’sequation and
Miller indices)

Reference Books :
1. Essentials of physical chemistry by A. S. Bhal and G. D. Tuli, Pub : S. Chand
2. Advance physical chemistry by D. N. Bajpai, Pub : S. Chand
3. Numerical problems by Dogra and Dogra (for numerical)
4. A textbook of physical chemistry by A. S. Negi and S. C. Anand, Pub : New Age
International (for numerical)

UNIT : 02
A. ACID – BASE THEORIES 04 h
Arrhenius theory, Lowry Bronsted theory, Lewis theory, Solvent – Solute concept of acid-
base, Soft-Hard acid base and its application.
Reference Books :
1. Essentials of physical chemistry by A. S. Bahl and G. D. Tuli, Pub : S. Chand
B. Atomic Structure 06 h
Historical perspective of atomic structure; Ruatherford’s atomic model, Bohr’s theory and
its limitation, Spectrum of Hydrogen atom (Lyman, Balmer, Paschen, Brackett &Pfund),
Quantum numbers, Auf bau, Hund and Pauli exclusion principles, Penetration and
shielding, Effective nuclear charge (Slater rule)
Reference Book :
1. University General Chemistry by C.N.R. Rao, Pub : McMillan
2. Principles of Physical Chemistry by Maron&Pruton, 4th edition, Pub: Oxford & IBH
3. Physical Chemistry by G. M. Barrow
4. Advance inorganic chemistry (Vol. II) by Satya Prakash, G. D. Tuli, S. K. Basu, R. D.
Madan; Pub. S. Chand

UNIT : 03 :
A. CHEMICAL KINETICS 06 h
Chemical kinetics and its scope, rate of reaction, factors affecting rate of reaction :
temperature, concentration, pressure, solvent, light and catalyst, Molecularity of reaction,
Classification of chemical reaction, Order of reaction with illustration (first order, second
order, third order, zero order, pseudo first order) reaction, : second order (a=b), half life
and mean life.
Reference Books :
1. Essentials of physical chemistry by A. S. Bahl and G. D. Tuli, Pub : S. Chand
2. Advance physical chemistry by D. N. Bajpai, Pub : S. Chand
3. Numerical problems by D. V. S. Jain, Pub. McGraw Hill (for numerical)

B. PERIODIC PROPERTIES 04 h
Definition of atomic and ionic radii, ionisation energy, electron affinity and electron
negativity, S-Block elements : Comparative study, diagonal relationship, salient features of
hydrides.
Reference Books :
1. Modern inorganic chemistry by Gurdeep Raj
2. Principals of inorganic chemistry by Puri, Sharma and Kalia; Pub. Vishal publishing
3. Inorganic Chemistry by J. D. Lee
F. Y. B.Sc. Chemistry Practical syllabus 2019
Semester- I
A) ORGANIC SPOTTING
Primary tests, Ignition test, Detection of Elements, Nature of the substance (solubility
test), Functionalgroup tests, C. T., Molecular formula, Structural formula & M. P./ B. P. of
the givensubstance.
ACID – Benzoic, Phthalic acid, Succinic acid.
BASE – Aniline, p – Toluidine
PHENOL – Resorcinol, a Naphthol, b Naphthol
NEUTRAL –
CARBOHYDRATE – Glucose , Fructose
KETONE – Acetone, Acetophenone
ESTER – Methyl salicylate, Methylacetate
ALCOHOL – Methanol , Ethanol
HYDROCARBON – Toluene , Naphthalene
NITRO HYDROCARBON – Nitrobenzene, m-di-nitrobenzene
HALOGENATED HYDROCARBON – Carbon tetrachloride, Chlorobenzene,
AMIDE – Urea, Benzamide
ANILIDE – Acetanilide
N. B. Candidate should perform the analysis of at least 08 substances.

B) VOLUMETRIC EXERCISE
H2SO4 NaHCO3 HNO3
KMnO4 H2C2O4 KOH
KMnO4 FeSO4 K2Cr2O7
K2Cr2O7 Fe-NH4-SO4 KMnO4
H2C2O4 KMnO4 FeSO4

N. B. Candidate should perform at least 3 volumetric exercises.

VEER NARMAD SOUTH GUJARAT UNIVERSITY, SURAT
Syllabus for on 2019
F. Y. B.Sc. Chemistry; Semester – II
(Paper : 01 : Inorganic & Physical Chemistry)
Total Hours : 30h

UNIT : 01
A. CONDUCTANCE AND IONIC EQUILIBRIUM 06 h
Electrical conductance, Specific conductance, equivalent conductance, Molar conductance,
Effect of dilution on concentration, Cell constant, Determination of Cell constant,
Ostwald’s dilution law and its limitations, Acid & Basic buffer actions (Henderson-
Hasselbach equation), Buffer capacity, Numerical.
B. THERMODYNAMICS 04 h
Second law of thermodynamics (in detail), Carnot cycle and its efficiency, Entropy concept,
Change of entropy for reversible isothermic, isobaric, isochoric and adiabatic processes.
Entropy change for ideal gases (T & V as variables, P & T as variables), Numerical.
Reference Book :
1. Physical Chemistry by ArunBahl, B. S. Bahl and G. D. Tuli; Pub. S. Chand
2. Advance physical chemistry by D. N. Bajpai; Pub : S. Chand
3. Text book of physical chemistry by P. L. Soni, O. P. Dharma; Pub. S. Chand

UNIT : 02 : 04 h
A. BASIC PRINCIPLES OF QUALITATIVE ANALYSIS
[I] Dry Reaction : theory behind borax bead test with equation, Flame test (Theory,
structure of non luminous Bunsen flame)
[II] Analysis of Cation : Application of common ion effect, solubility product constant.
Complexometric reactions involved in qualitative analysis;
1. For identification [reaction between Cu(II) ion with ammonia, Fe(III) with thiocyanide,
+
NH4 with Nessler Reagent].
+2 +2
2. For masking [Cd , Cu ].
+2 +2
3. Separation of two ions [Ag-Hg, Zn , Mn ]
Reference Books :
1. Qualitative analysis by R. A. Day and A. L. Underwood
2. Vogel’s qualitative Inorganic analysis
B. Coordination Chemistry 06 h
Shape of d-orbitals, CFT – Basic assumption, splitting of d-orbitals in Octahedral,
x
Tetrahedral, Square planer complexes, distribution of d electrons in Octahedral and
Tertahedral complexes and CFSE.
Reference Book :
1. Inorganic chemistry by Wahid Malik, G. D. Tuli, R. D. Madan; Pub. S. Chand
2. Coordination Chemistry by GurdipChatwal, M. S. Yadav; Pub. Himalaya pub. house
3. Advance inorganic chemistry (Vol. II) by Satya Prakash, G. D. Tuli, S. K. Basu, R. D.
Madan; Pub. S. Chand

UNIT : 03 :
[A] CHEMICAL BONDING 05 h
Definition of chemical bonds (covalent, co-ordinate covalent, ionic, metallic, H-bond, Wan
der walls forces of attraction), Polarisability (Fajan’s rule), Molecular Orbital theory ; LCAO
method, Bonding molecular orbital, non-bonding molecular orbital, anti-bonding
molecular orbital, bond order, magnetic properties and molecular orbital energy level
diagram of hetero diatomic molecule : CO and NO, VSEPR theory.
Reference Book :
1. Consise Inorganic Chemistry (5th ed.) by J. D. Lee
2. Basic Inorganic Chemistry by Cotton & Wilkinson.
3. Inorganic Chemistry – Principles of structure and reactivity by J. E. Huheey, E. A.
Keiter; Pub. Person Education Publishers.
[B] PHYSICAL PROPERTIES AND CHEMICAL CONSTITUTION 05 h
Classification of physical properties (additive, constitutive, colligative, additive-
constitutive), Atomic volume, Molar volume and Chemical constitution, Kopp’s law,
Surface tension, Drop number method, Parachor, Viscosity, Determination of viscosity by
Ostwald viscometer, Define : Refraction, Specific refraction, molar refraction, Numerical.
Reference Book :
1. Principles of Physical chemistry by Puri, Sharma and Madan; Pub. Vishal publishing
2. Essentials of physical chemistry by A. S. Bhal and G. D. Tuli, Pub : S. Chand
3. Advance physical chemistry by D. N. Bajpai, Pub : S. Chand
F. Y. B.Sc. Chemistry Practical syllabus 2019
Semester-II
A. INORGANIC QUALITATIVE ANALYSIS
LIST OF INORGANIC CHEMICALS
CHLORIDES : Cu+2, Fe+3, Mn+2, Co+2, Ni+2, Ca+2, Ba+2, Sr+2, Na+, K+, NH4+.
BROMIDES :Sr+2, Na+, K+, NH4+.
IODIDE :K+
NITRATE :Pb+2, Co+2, Ni+2, Ba+2, Sr+2, Na+, K+, NH4+.
SULPHIDE : Zn+2, Sb+3.
SULPHATE : Cu+2, Al+3, Fe+2, Zn+2, Mn+2, Co+2, Ni+2, Mg+2, Na+, K+, NH4+.
CHROMATE : Na+, K+
CARBONATE : Cu+2, Zn+2, Mn+2, Co+2, Ni+2, Ca+2, Ba+2, Sr+2, Mg+2, Na+, K+,NH4+
PHOSPHATE : Cu+2, Al+3, Fe+3, Zn+2, Mn+2, Ca+2, Ba+2, Sr+2, Mg+2, Na+, K+,NH4+
OXIDE : Sb+3, Zn+2
N. B. Candidate should perform the analysis of at least 8 compounds.

B. PREPARATIO OF STANDARD SOLUTION (BY STUDENTS) OF FOLLOWING.

1. 0.1 N succinic acid against NaOH
2. 0.1 N KHP against NaOH/KOH
3. 0.01 N Na2S2O3 against I2 solution
4. 0.1 N H2C2O4 2H2O against KMnO4 solution
5. 0.1 N K2Cr2O7 against FeSO4.7H2O OrFeSO4,(NH4)2SO4 10H2O solution
N. B. Candidate should perform at least 3 volumetric exercises.
VEER NARMAD SOTH GUJARAT UNIVERSITY, SURAT
Syllabus on 2019
For
F. Y. B. Sc. Semester- I
Paper-II
(Organic Chemistry)
UNIT I:(A) Alkanes and Cycloalkanes: 10 Hrs.
Alkanes : IUPAC nomenclature of branched and unbranched alkanes, Aklyl group,
Classification of carbon atoms in alkanes. Isomerism in Alkanes, sources, methods of
formation special reference to Wurtz reaction, Kolbe reaction and Corey-House reaction
and decarboxylation of carboxylic acids). Physical properties and chemical reactions of
alkanes.Mechanism of free redical halogenations of alkanes: orientation, reactivity &
selectivity.
(B) Cycloalkanes : Nomenclature, methods of formation, chemical reactions, Baeyer's
strain theory and its limitations.Ring strain in small rings (Cyclo propane and cyclo butane),
Theory of strainless ring. The case ofcyclo propane ring: banana bonds

UNIT II : Stereochemistry 10 Hrs.

(a) Isomerism :- Optical activity , Chiral and Achiral molecules,
(b) Optical isomerism of tartaric acid, Enantiomers, diastereomers( Threo&Erythro),
Meso compounds Resolution of Recimates, inversion retention and racemization .
(c) Geometrical Isomerism: Alkene derivative &oximes E & Z system of nomenclature.
(d) Relative and absolute configuration, sequence rules. D & Land R & S system of
nomenclature.

UNIT III (A) Heterocyclic compounds : 5 Hrs.

Nomenclature aromaticity , and synthesis properties uses and canonicai
structures of Pyrrol, Benzopyrol Furan , Benzofuran, Thiophene,
Benzothiophene.
(B) PolynuclearHydrocarbons : 3 Hrs.
Classification aromaticityand Industrial preparation, , properties,uses and canonical
structures of Napthalene , Anthracene and Phenanthrene.
(C) Organic Qualitative Analysis 2 Hrs.

(I) Elemental Analysis (Lassaign’s Test with equation)

(II) Solubility of Organic Compound (Ref. : Vogel’s qualitative organic analysis)
Chemical Methods : Solubility in NaHCO3 ,NaOH and HCl , Acid, Base and
Phenol and amphoteric compounds ( Sulphanilic acid and Anthranilic acid )
VEER NARMAD SOTH GUJARAT UNIVERSITY, SURAT

Syllabus on 2019
For
F. Y. B. Sc. Semester- II
Paper-II
(Organic Chemistry)
UNIT: I: Reaction mechanism :10 Hrs.
(a) Homolytic and Heterolytic fission free radicals carbonium ions ( carbocations ) and
carbanions reactive intermediates carbenes , arynes and nitrenes.
(b) Types of reagents, electrophiles nucleophiles .
(c) Eletromeric, inductive, conjugative effect.
(d) Types of reactions : Addition, substitution, elimination, rearrangments. Addition, and
Substitution with respect to electrophilic and nucleophilic reaction,SN1&SN2
(e) Mechanism of (i) addition reaction to alkenes and dienes (ii) substitution in benzene
Ring, nitration ,sulfonation, alkylation , acylation, halogenation., cyanohydrin formation
andacetal formation,
(f) Mechanism of Perkin reaction, Benzoin Condensation andCannizaro's reaction

UNIT II: (A) Empirical formula, Molecular formula, and Structural formula: 4 Hrs.
Determination of empirical formula and its relation with molecular formula
determination of molecular weight of (a) Organic acid by Silver saltmethod and
(b) organic base by chloroplatinate method and its limitations .
Numerical example.
(B) Carbohydrates: 6 Hrs.
Modern definition of carbohydrates, classification of carbohydrates, function of
Carbohydrates,optical isomers, Diastereoisomers,enantiomersracimatesof
Glucose and Fructose, Stricture of Glucose and Fructoseisomers,mutarotation,
glucoside linkage (Pyranose and Furanose)D & L isomers of Glucose and
Fructose, derivatives of Monosaccharide, step up and stepdown synthesis, kilyani
synthesis, conversion of glucose to Fructose andconversion of Fructose to
glucose.

UNIT – III (A) Alkenes, dienes and alkynes : 10Hrs.

(a) Alkenes : Nomenclature, method of preparation, properties and uses of ethylene and
propyleneMorkwonikoffs rule and Satytzeff rule, polymerization of ethylene styrene
andvinyl chloride. Alkenes.Reactions: Hydroboration, Oxidation, Epoxidation,
Ozonolysis, Oxymercuration, Hydroxylation, Hydrohalogenation,
Dehydrohalogenations, Hydration.
(b) Dienes : Nomenclature, classification of dienes methods of formation of Butadiene
chemical reactions 1,2 and 1,4 additions, Diel's – Alder reaction.
(c) Alkynes : Nomenclature , methods of formation, chemical reactions: Hydroboration,
Oxidation,metal ammonia reduction, oxidation, polymerization. Electrophilic and
nucleophilic addition reactions of acetylene.
Reference Books

(1) Organic chemistry vol.I and vol. II by I.L.Finar (Longman group)

(2) Organic chemistry by P.L.Soni
(3) Organic chemistry by R.T.Morrison and Boyd Prentice Hall India.
(4) Organic chemistry by B.K. Sharma.
(5) Organic chemistry by Bahland Bahl
(6) Organic reaction mechanism by Mukharji and singh
(7)Fundamentals of Organic chemistry by Soloman, John Wiely