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Volumetric Analysis - Class Assignment Part 01 PDF

The document provides a list of chemical compounds and asks the reader to determine the oxidation state of each element in bold. It then provides additional chemistry questions related to oxidation states, including identifying oxidizing and reducing agents in reactions, calculating molar ratios in chemical formulas, balancing redox reactions, and determining the formulas of compounds given the oxidation states of elements.

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70 views2 pages

Volumetric Analysis - Class Assignment Part 01 PDF

The document provides a list of chemical compounds and asks the reader to determine the oxidation state of each element in bold. It then provides additional chemistry questions related to oxidation states, including identifying oxidizing and reducing agents in reactions, calculating molar ratios in chemical formulas, balancing redox reactions, and determining the formulas of compounds given the oxidation states of elements.

Uploaded by

yug agarwal
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Class Assignment (JEE Main/Advance/NEET)

Chemistry TOPIC: Volumetric Analysis (Part 01) by Vikrant Kumar (VCH)

01. Find the oxidation state of each element marked in bold.


001. HCl 002. NaCl 003. BaCl2 004. PbCl2
005. SnCl4 006. HClO4 007. HClO3 008. HClO2
009. HOCl 010. HBrO4 011. ClO3- 012. KClO3
013. MnCl2 014. Ba(ClO4)2 015. [NiCl4]2- 016. Ca(OCl)Cl
017. KI3 018. 𝑰+
𝟑 019. 𝑰−
𝟑 020. Pb(I3)2
021. CO 022. CO2 023. CO32- 024. C2O42-
025. CH4 026. C2H6 027. C2H2 028. CN-
029. HCN 030. HNC 031. Ba(CN)2 032. CaC2
033. CH3Cl 034. CH2Cl2 035. CHCl3 036. CCl4
037. NH3 038. NH4+ 039. N2H4 040. N2H5+
041. NH4Cl 042. (NH4)2SO4 043. NO3- 044. NH4NO3
045. SO42- 046. H2SO3 047. SO3 048. S2O32-
049. S8 050. SO32- 051. H2S 052. Na2S2O3
053. H2S2O7 054. Na2S 055. FeS 056. FeS2
057. S2F2 058. FeO 059. Fe2O3 060. FeSO4
061. FeC2O4 062. Fe2(SO4)3 063. Fe(CO)5 064. Fe2(C2O4)3
065. Fe0.95O 066. K4[Fe(CN)6] 067. [Ag(CN)2]- 068. K3[Fe(CN)6]
069. Zn1.03O 070. [Fe(CN)6]3- 071. Fe4[Fe(CN)6]3 072. [Fe(H2O)5NO+]SO4
073. P4 074. H3PO4 075. H3PO3 076. H3PO2
077. PCl5 078. PH3 079. P2H4 080. P4H2
081. P4O10 082. NO[ClO4] 083. Fe3O4 084. Pb3O4
085. K2O 086. KO2 087. H2O2 088. BaO2
089. OF2 090. O2F2 091. O3 092. KO3
093. Na2O2 094. O2[BF4] 095. O2[PtF6] 096. Na2S4O6
097. C3O2 098. Br3O8 099. CrO42- 100. K2Cr2O7
101. Cr2O72- 102. MnO4- 103. KMnO4 104. K2MnO4
105. MnSO4 106. K3MnO4 107. HgCl2 108. Hg2Cl2
109. K2HgI4 110. Na2ZnO2 111. Cr2(SO4)3 112. AsO43-
113. H4P2O7 114. MnO2 115. [Cr(NH3)6]Cl3 116. [Ni(CO)4]
117. CuCl2 118. Cu2Cl2 119. CuSO4.5H2O 120. [Cu(NH3)4]2+
121. Cu2S 122. Pb(N3)2 123. As2S3 124. Ba(MnO4)2
125. ClF3 126. ICl3 127. IF7 128. [PCl4]+
129. [PCl6]- 130. I(CN)2- 131. WO3 132. [W(CN)6]4-
133. UO22+ 134. UO2+ 135. K[AuCl4] 136. CrO2Cl2
137. HV6O113- 138. NH2OH 139. Xe[PtF6] 140. XeO64-
141. XeO2F2 142. XeOF4 143. CaH2 144. Na3AlF6
145. OsO4 146. HN3 147. Cr(OH)4- 148. NaH2PO2
149. Na2SnS3 150. FeCr2O4 151. Mg2P2O7 152. (NH4)2Cr2O7
153. [CoCl4]- 154. CO(NH2)2 155. [Co(CN)6]3- 156. SO2Cl2
157. (NH4)2S 158. LiAlH4 159. Na3[Ag(S2O3)2] 160. H2S2O8
161. H2SO5 162. CrO5 163. H4P2O8 164. K[Co(CO)4]
165. (CH3)2SO 166. NaBiO3 167. [Al(OH)4]- 168. [Co(NH3)4Cl2]+
169. Ba2XeO6 170. HV6O173- 171. N2H6SO4 172. [Fe(H2O)2(C2O4)2]2-
173. HCOO- 174. H3PO5 175. K2C2O6 176. Cs4Na(HV10O28)
177. I4O9 178. Pb(BrO3)2 179. Ph-NH2 180. Ph-NO2
181. Hg2SO4 182. H4XeO6 183. Ba(MnO4)2 184. BaMnO4
185. NOCl 186. UO2(NO3)2 187. K2PtCl6 188. Mg(NH4)PO4

1
02. X, Y and Z are three elements forming a compound in oxidation state of (+2), (+5) and (-2) respectively.
What can be the formula of compound?
(A) X2(YZ)2 (B) X3(YZ4)2 (C) X2(YZ4)3 (D) XYZ
03. Oxidation number of Sulphur varies from (-2) to (+6) but oxidation number of oxygen varies from (-2) to
(+2) only. Explain.
04. Calculate the molar ratio of metal ions with different oxidation states (indicated) in each of the following
oxides:
(i) Fe3O4 (Fe2+: Fe3+) (ii) Mn3O4 (Mn2+:Mn4+) (iii) Pb3O4 (Pb2+:Pb4+)
(iv) Fe0.95O (Fe2+: Fe3+) (v) Fe7S8 (Fe2+:Fe3+) (take S in -2 o.s.)
05. Identify the oxidizing agent and reducing agent in the following reactions.
(i) Pb(NO3)2 + K2CrO4 → PbCrO4 + KNO3
(ii) H2SO4 + NaOH → Na2SO4 + H2O
(iii) Cu + HNO3 → Cu(NO3)2 + NO2 + H2O
(iv) MnO4- + C2O42- + H+ → Mn2+ + CO2 + H2O
(v) Br2 + KOH → KBr + KBrO3 + H2O
(vi) Pb3O4 + HCl → PbCl2 + Cl2 + H2O
(vii) H2O2 + O3 → H2O + O2
(viii) N2 + H2 → NH3
(ix) CH4 + O2 → CO2 + H2O
(x) Zn + H2SO4 → ZnSO4 + H2
06. Balance the following redox reactions:
(a) KMnO4 + H2C2O4 + H2SO4 → MnSO4 + K2SO4 + CO2 + H2O
(b) Fe2+ + Cr2O72- + H+ → Fe3+ + Cr3+ + H2O
(c) Br2 + KOH → KBr + KBrO3 + H2O
(d) Cu + HNO3 → Cu(NO3)2 + NO + H2O
(e) I- + IO3- + H+ → I2 + H2O
(f) ClO4- + MnO2 + OH- → ClO- + MnO4- + H2O
(g) Zn + NO3- → Zn2+ + NH4+
(h) MnO2 + HCl → MnCl2 + Cl2 + H2O
(i) UO2+ + Cr2O72- + H+ → UO22+ + Cr3+ + H2O
(j) [Fe(CN)6]3- + H2O2 + OH- → [Fe(CN)6]4- + O2 + H2O
(k) KMnO4 + NH3 → KNO3 + MnO2 + KOH + H2O
(l) I2 + Cr2O72- + H+ → IO3- + Cr3+ + H2O
(m) KMnO4 + H2O2 + H2SO4 → K2SO4 + MnSO4 + O2 + H2O
(n) P2H4 → PH3 + P4H2
(o) As2S3 + HNO3 → H3AsO4 + H2SO4 + NO
(p) P4 + Cr2O72- + H+ → PO43- + Cr3+ + H2O
(q) CuSO4 + KI → Cu2I2 + I2 + K2SO4
(r) WO3 + CN- + H2O → [W(CN)6]4- + O2 + OH-
(s) CuS + NO3- + H+ → Cu2+ + S8 + NO
(t) Mn2+ + S2O82- + H2O → MnO4- + HSO4- + H+
(u) P4 → PH3 + HPO32- (Basic medium)
(v) MnO42- → MnO4- + MnO2 (Basic medium)
(w) Al + NO3- + H2O + OH- → NH3 + [Al(OH)4]-
(x) ClO3- + I2 + H2O → Cl- + IO3- + H+
(y) NaOCl + Bi2O3 + NaOH → NaCl + NaBiO3 + H2O
(z) CrO42- + I- + H2O → IO3- + Cr3+ + OH-

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