SDSUS / EN / TSDSUS04

Version: 6.0
Revision Date: 05/14/2015
Initiator: 0001 / PRD
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SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier
Product name: Eastman(TM) EB Solvent

Product No.: EAN 902270. 00650-00, P0065000, P0065001, P0065002, P0065006, E00650E1, E00650E2,
E00650E3, P0065007, P0065009, P0065010, P0065011

Synonyms, Trade Names: 00650-00

Additional identification
Chemical name: 2-butoxyethanol
CAS-No.: 111-76-2

Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Solvent
Uses advised against: None known.

Details of the supplier of the safety data sheet

Manufacturer / Supplier
Eastman Chemical Company
200 South Wilcox Drive
Kingsport, TN 37660-5280 US
+14232292000

Visit our website at www.EASTMAN.com or email [email protected]

Emergency telephone number:

For emergency health, safety, and environmental information, call 1-423-229-4511 or 1-423-229-2000.

For emergency transportation information, in the United States: call CHEMTREC at 800-424-9300 or call
423-229-2000.

SECTION 2: Hazards identification

Hazard Classification:
Physical Hazards
Flammable liquids Category 4
Health Hazards
Acute toxicity (Oral) Category 4
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2A
Aspiration Hazard Category 1

OSHA Specified Hazards: not applicable

Warning label items including precautionary statement:

Pictogram:
©COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 1/10
SDSUS / EN / TSDSUS04
Version: 6.0
Revision Date: 05/14/2015
Initiator: 0001 / PRD
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Signal Words: DANGER!

Hazard Statement(s): H227: Combustible liquid.

H304: May be fatal if swallowed and enters airways.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Precautionary Statement:
Prevention: P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face
protection.

Response: P370+P378: In case of fire; Use water spray, carbon dioxide, dry chemical
or alcohol foam for extinction.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician.
P331: Do NOT induce vomiting.

Storage: P403+P235: Store in a well-ventilated place. Keep cool.

P405: Store locked up.

Disposal: P501: Dispose of contents/container to an appropriate treatment and

disposal facility in accordance with applicable laws and regulations, and
product characteristics at time of disposal.

Hazard(s) not otherwise None known.

classified (HNOC):

SECTION 3: Composition/information on ingredients

Substances / Mixtures

General information:

Chemical name Concentration Additional identification Notes

2-butoxyethanol 100% CAS-No.: 111-76-2 #

©COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 2/10

SDSUS / EN / TSDSUS04
Version: 6.0
Revision Date: 05/14/2015
Initiator: 0001 / PRD
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* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
# This substance has w orkplace exposure limit(s).

SECTION 4: First aid measures

Description of first aid measures

Inhalation: Move to fresh air. If breathing stops, provide artificial respiration. If
breathing is difficult, give oxygen. Get medical attention immediately.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention.

Skin contact: Immediately flush with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention
immediately. Wash contaminated clothing before reuse. Destroy or
thoroughly clean contaminated shoes.

Ingestion: Call a physician or poison control center immediately. Only induce vomiting
at the instruction of medical personnel. Never give anything by mouth to an
unconscious person.

Most important symptoms and May irritate and cause redness and pain.
effects, both acute and
delayed:

Indication of any immediate medical attention and special treatment needed

Hazards: Glycol Ethers: Some glycol ethers cause adverse effects in animals that
include the reproductive system, offspring, blood, kidney and liver.

Treatment: Treat symptomatically.

SECTION 5: Firefighting measures

General Fire Hazards: Combustible liquid and vapor.

Extinguishing media
Suitable extinguishing Water spray. Dry chemical. Carbon Dioxide. Alcohol foam.
media:

Unsuitable extinguishing None known.

media:

Special hazards arising from Forms peroxides of unknown stability.

the substance or mixture:

Advice for firefighters

Special fire fighting Use water spray to keep fire-exposed containers cool.
procedures:

Special protective Self-contained breathing apparatus and full protective clothing must be
equipment for fire-fighters: worn in case of fire.

SECTION 6: Accidental release measures

©COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 3/10

SDSUS / EN / TSDSUS04
Version: 6.0
Revision Date: 05/14/2015
Initiator: 0001 / PRD
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Personal precautions, Wear appropriate personal protective equipment.

protective equipment and
emergency procedures:

Environmental Precautions: Avoid release to the environment.

Methods and material for Eliminate sources of ignition. Absorb spill with vermiculite or other inert
containment and cleaning material, then place in a container for chemical waste. Large Spillages:
up: Flush spill area with water spray. Prevent runoff from entering drains,
sewers, or streams. Dike for later disposal.

Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in
accordance with all applicable regulations.

SECTION 7: Handling and storage:

Precautions for safe handling: Avoid breathing mists or vapors. Avoid contact with eyes, skin, and
clothing. Do not taste or swallow. Use only with adequate ventilation. Wash
thoroughly after handling. Minimize exposure to air. After opening, purge
container with nitrogen before reclosing. Periodically test for peroxide
formation on long-term storage. Do not allow to evaporate to near dryness.
Do not distill to near dryness. Addition of water or appropriate reducing
materials will lessen peroxide formation.

Conditions for safe storage, Keep container tightly closed and in a well-ventilated place. Store away
including any from heat and light.
incompatibilities:

Specific end use(s): Solvent

SECTION 8: Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits

Country specific exposure limits have not been established or are not applicable
unless listed below.

Chem ical name type Exposure Lim it Values Source

2-butoxyethanol TWA 20 ppm US. ACGIH Threshold Limit Values (01 2010)

PEL 50 ppm 240 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)

Biological Limit Values

Chem ical name Exposure Lim it Values Source

2-butoxyethanol 200 mg/g (Creatinine in urine) ACGIH BEL (01 2010)

(Butoxyacetic acid (BAA),
w ith hydrolysis: Sampling
time: End of shift.)

Exposure controls

©COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 4/10

SDSUS / EN / TSDSUS04
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Revision Date: 05/14/2015
Initiator: 0001 / PRD
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Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used.
controls: Ventilation rates should be matched to conditions. If applicable, use
process enclosures, local exhaust ventilation, or other engineering controls
to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an
acceptable level.

Individual protection measures, such as personal protective equipment

General information: Eye bath. Washing facilities. Safety shower.

Eye/face protection: Wear safety glasses with side shields (or goggles) and a face shield. Wear
a full-face respirator, if needed.

Skin protection
Hand Protection: Wear chemical-resistant gloves, footwear, and protective clothing
appropriate for the risk of exposure. Contact health and safety professional
or manufacturer for specific information.

Other: No data available.

Respiratory Protection: If engineering controls do not maintain airborne concentrations below

recommended exposure limits (where applicable) or to an acceptable level
(in countries where exposure limits have not been established), an
approved respirator must be worn. In the United States of America, if
respirators are used, a program should be instituted to assure compliance
with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Air-
purifying respirator with an appropriate, government approved (where
applicable), air-purifying filter, cartridge or canister. Contact health and
safety professional or manufacturer for specific information.

Hygiene measures: Observe good industrial hygiene practices.

Environmental Controls: No data available.

SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties

Appearance
Physical state: liquid
Form: liquid
Color: Colorless
Odor: Mild sweet, ester
Odor Threshold: 0.48 ppm
pH: No data available.
Freezing Point: -75 °C
Boiling Point: 171 °C
Flash Point: 67 °C (Closed Cup)
Evaporation Rate: 0.1
Flammability (solid, gas): No data available.
Flammability Limit - Upper (%)–: No data available.
Flammability Limit - Lower (%)–: No data available.
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SDSUS / EN / TSDSUS04
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Revision Date: 05/14/2015
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Vapor pressure: 1.17 hPa (25 °C)

Vapor density (air=1): 4
Specific Gravity: 0.90 (20 °C)
Solubility(ies)
Solubility in Water: 900 g/l (25 °C)
Solubility (other): No data available.
Partition coefficient (n-octanol/water): Pow: 6.46 log Pow: 0.81
Autoignition Temperature: No data available.
Decomposition Temperature: 124.7 °C (DSC) 21.7 J/g Weak exotherm
Dynamic viscosity: 3.3 mPa.s (20 °C)
Kinematic viscosity: 3.642 mm2/s (20 °C)
Explosive properties: No data available.
Oxidizing properties: Not classified.

Other information
Molecular weight: 118.2 g/mol (C6H14O2)
Minimum ignition temperature: 230 °C (1,013 hPa, ASTM D2155)

SECTION 10: Stability and reactivity

Reactivity: None known.

Chemical Stability: Stable

Possibility of Hazardous Forms peroxides of unknown stability.

Reactions:

Conditions to Avoid: Heat, sparks, flames.

Incompatible Materials: Strong oxidizing agents.

Hazardous Decomposition Carbon Dioxide. Carbon Monoxide.

Products:

SECTION 11: Toxicological information

Information on likely routes of exposure

Inhalation: None known.

Ingestion: Harmful if swallowed. May be fatal if swallowed and enters airways.

Skin contact: Causes skin irritation.

Eye contact: Causes eye irritation.

Information on toxicological effects

Oral
Product: Oral LD-50: (Rat): 1,300 mg/kg
Oral LD-50: (Guinea Pig): 1,400 mg/kg

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SDSUS / EN / TSDSUS04
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Revision Date: 05/14/2015
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Dermal
Product: Dermal LD-50: (Rat): > 2,000 mg/kg

Dermal LD-50: (Guinea Pig): > 2,000 mg/kg

Inhalation
Product: Vapour: LC50 (Rat, 3 h): > 4.9 mg/l
Vapour: LC0 (Guinea Pig, 1 h): > 3.4 mg/l

Repeated dose toxicity

Product: LOAEL (Rat, Oral Study): 69 mg/kg (Target Organ(s): Liver)
NOAEL (Rat, Dermal Study): 150 mg/kg
LOAEC (Rat, Inhalation study:): 152 mg/m³ (Target Organ(s): Blood)

Skin Corrosion/Irritation
Product: (Rabbit, 24 h): moderate

Serious Eye Damage/Eye Irritation

Product: (Rabbit, 24 h): moderate

Respiratory or Skin Sensitization

Product: Skin Sensitization: (Guinea Pig): Not a skin sensitizer.

Carcinogenicity
Product: Rat, Male and Female: Inhalation ; OECD Test No. 451: Carcinogenicity
Studies ; Remarks : negative

Toxicity to reproduction
Product: OECD Test No. 416: Two-Generation Reproduction Toxicity Study (Mouse,
Male and Female); NOAEL: 720 mg/kg; NOAEL: 720 mg/kg; NOAEL: 720
mg/kg; Ingestion

Developmental toxicity
Product: Rat, Male and Female; NOAEL: 100 mg/kg; NOAEL: 30 mg/kg; Ingestion

Germ Cell Mutagenicity

In vitro
Product: Salmonella typhimurium assay (Ames test): negative

In vivo
Product: Chromosomal aberration intraperitoneal injection (Mouse, Male.): negative

Specific Target Organ Toxicity - Single Exposure

Product: Not classified.

Specific Target Organ Toxicity - Repeated Exposure

Product: Not classified.

Aspiration Hazard
Product: Droplets of the product aspirated into the lungs through ingestion or vomiting may
cause a serious chemical pneumonia.

Other effects: No data available.

©COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 7/10
SDSUS / EN / TSDSUS04
Version: 6.0
Revision Date: 05/14/2015
Initiator: 0001 / PRD
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SECTION 12: Ecological information

Ecotoxicity:
Acute hazards to the aquatic environment:
Fish
Product: LC-50 (Oncorhynchus mykiss , 96 h): 1,474 mg/l

Aquatic Invertebrates
Product: EC-50 (Water Flea, 48 h): 1,550 mg/l

Chronic hazards to the aquatic environment:

Fish
Product: NOEC (Zebra Fish, 21 d): > 100 mg/l

Aquatic Invertebrates
Product: NOEC (daphnid, 21 d): 100 mg/l

Toxicity to Aquatic Plants

Product: EC-50 (Algae (Pseudokirchneriella subcapitata), 72 h): 1,840 mg/l

Persistence and Degradability

Biodegradation
Product: 90.4 % (28 d) Readily biodegradable

BOD/COD Ratio
Product: No data available.

Bioaccumulative Potential
Bioconcentration Factor (BCF)
Product: Potential to bioaccumulate is low.

Partition Coefficient n-octanol / water (log Kow)

Product: Log Kow: 0.81 20 °C

Mobility in Soil: Expected to partition to water.

Other Adverse Effects: No data available.

SECTION 13: Disposal considerations

Waste treatment methods

General information: No data available.

Disposal methods: Dispose of waste and residues in accordance with local authority
requirements. Incinerate. Since emptied containers retain product residue,
follow label warnings even after container is emptied.

©COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 8/10

SDSUS / EN / TSDSUS04
Version: 6.0
Revision Date: 05/14/2015
Initiator: 0001 / PRD
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SECTION 14: Transport information

Important Note: Shipping descriptions may vary based on mode of transport, quantities, pack age size,
and/or origin and destination. Consult your company's Hazardous Materials/Dangerous Goods expert for
information specific to your situation.

DOT
Class combustible liquid, Packing group III for quantities of 450 liters (119 gallons) or more; not
regulated for smaller quantities

Possible Shipping Description(s):

NA 1993 Combustible liquid, n.o.s. (ethylene glycol monobutyl ether) combustible

liquid III

IMDG - International Maritime Dangerous Goods Code

Class not regulated

Possible Shipping Description(s):

not regulated

IATA
Class not regulated
Possible Shipping Description(s):

not regulated

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture.:

This product has been classified in accordance with hazard criteria of the Controlled Products
Regulations and the SDS contains all the information required by the Controlled Products Regulations.
WHMIS (Canada) Status: controlled
WHMIS (Canada) Hazard Classification: B/3, D/1/A, D/2/B

SARA 311-312 Hazard Classification(s):

immediate (acute) health hazard
delayed (chronic) health hazard
fire hazard

US EPCRA (SARA Title III) Section 313 - Toxic Chemical List

2-BUTOXYETHANOL (ETHYLENE GLYCOL MONOBUTYL ETHER) (GLYCOL ETHER CATEGORY )

OSHA: hazardous

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TSCA (US Toxic Substances Control Act): This product is listed on the TSCA inventory. Any impurities
present in this product are exempt from listing.

DSL (Canadian Domestic Substances List) and CEPA (Canadian Environmental Protection Act): This
product is listed on the DSL. Any impurities present in this product are exempt from listing.

AICS / NICNAS (Australian Inventory of Chemical Substances a nd National Industrial Chemicals

Notification and Assessment Scheme): This product is listed on AICS or otherwise complies with NICNAS.

MITI (Japanese Handbook of Existing and New Chemical Substances): This product is listed in the
Handbook or has been approved in Japan by new substance notification.

ECL (Korean Toxic Substances Control Act): This product is listed on the Korean inventory or otherwise
complies with the Korean Toxic Substances Control Act.KE-04134

Philippines Inventory (PICCS) : This product is listed on the Philippine Inventory or otherwise complies with
PICCS.

Inventory of Existing Chemical Substances in China: All components of this product are listed on the
Inventory of Existing Chemical Substances in China (IECSC).

SECTION 16: Other information

HMIS® Hazard Ratings: Health - 2*, Flammability - 2, Chemical Reactivity - 1

HMIS® rating involves data interpretations that may vary from company to company. They are intended only for rapid, general
identification of the magnitude of the specific hazard. To deal adequately with the safe handling of this material, all the i nformation
contained in this MSDS must b e considered.

Revision Information: Not relevant.

Key literature references and No data available.

sources for data:
Training information: No data available.

Issue Date: 05/14/2015

SDS No.:
Disclaimer: This information is provided without warranty. The information is believed to
be correct. This information should be used to make an independent
determination of the methods to safeguard workers and the environment.

©COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 10/10