VITEEE

SOLVED PAPER 2013

(a) 2k/x 3 (b) –2k/x 3

PART - I (PHYSICS) (c) k/x (d) –k/x
1. The amplitude of an electromagnetic wave in 7. A copper wire of length 2.2 m and a steel wire of
vaccum is doubled with no other changes made length 1.6 m, both of diameter 3.0 mm are
to the wave. As a result of this doubling of the connected end to end. When stretched by a
amplitude, which of the following statement is force, the elonation in length 0.50 mm is produced
correct? in the copper wire. The stretching force is
(a) The frequency of the wave changes only (Ycu = 1.1 × 1011 N/m2 , Ysteel = 2.0 × 1011 N/m2)
(b) The wave length of the wave changes only (a) 5.4 × 102 N (b) 3.6 × 102 N
(c) The speed of th e wave propagation (c) 2.4 × 10 N 2 (d) 1.8 × 102 N
changes only 8. If v , rms and p represent the mean speed,
(d) Alone of the above is correct
root mean square and most probable speed of
2. An element with atomic number Z = 11 emits
the molecules in an ideal monoatomic gas at
K a – X-ray of wavelength . The atomic
temperature T and if m is mass of the molecule,
number which emits K a – X-ray of wavelength
then
4 is
(a) vp < v < vrms
(a) 4 (b) 6
(b) no molecule can have a speed greater than
(c) 11 (d) 44
3. Mobilities of electrons and holes in a sample of 2vrms
intrinsic germanium at room temperature are
(c) no molecule can have a speed less than
0.36m2 V-1s-1 and 0.17m2V–1s–1. The electron
and hole densities are each equal to 2.5 × 1019 vp / 2
m3. The electrical conductivity of germanium is (d) None of the above
(a) 4.24 Sm-1 (b) 2.12 Sm-1 9. Two balls of equal masses are thrown upwards
(c) 1.09 Sm -1 (d) 0.47 Sm-1 along the same vertical direction at an interval
4. If a radio-receiever amplifiers all the signal of 2 s, with the same initial velocity of 39.2 m/s.
frequencies equally well, it is said to have high The two balls will collide at a height of
(a) sensitivity (b) selectivity
(a) 39.2 m (b) 73.5 m
(c) distortion (d) fidelity
(c) 78.4 m (d) 117.6 m
5. If a progressive wave is represented as
10. The dimensional formula of magnetic flux is
æ t xö
y = 2sin p çç - ÷÷÷ where x is in metre and t is (a) [M1L2T–1 A–2] (b) [M1L2T–2 A–1]
çè 2 4 ø (c) [M1L2T–1 A–1] (d) [M1L0T–2 A–1]
in second, then the distance travelled by the 11. The time dependence of a physical quantity P is
wave in 5 s is given by P = P0 e a (– a t2 ), where is a
(a) 5 m (b) 10 m constant and t is time. The constant a
(c) 25 m (d) 32 m (a) is a dimensionless
6. The gravitational potential at a place varies (b) has dimensions of P
inversely with x2(i.e.,V = k/x2), the gravitational (c) has dimensions of T-2
field at that place is (d) has dimensions of T2
12. If the potential energy of a gas molecule is 17. A body of mass 5 m initially at rest explodes into
M N 3 fragments with mass ratio 3:1:1. Two of
U= - , M and N being positive fragments each of mass ‘m’ are found to move
r 6 r12 with a speed of 60 m/s is mutually perpendicular
constants, then the potential energy at directions. The velocity of third fragment is
equilibrium must be
(a) zero (b) NM2 /4 (a) 10 2 (b) 20 2
(c) MN /42 (d) M2 /4N (c) 20 3 (d) 60 2
13. A table fan rotating at a speed of 2400 rpm is
18. A body of mass 2 kg moving with velocity of
switched off and the resulting variation of
6 m/s strikes in elastically with another body of
revolution/minute with time is shown in figure.
same mass mass at rest. The amount of heat
The total number of revolutions of the fan before
evolved during collision is
it, comes to rest is
(a) 18 J (b) 36 J
(c) 9 J (d) 3 J
2400 19. Two particles of equal mass m go round a circle
rpm of radius R under the action of their mutual
gravitational attraction. The speed of each
particle is
600
1 Gm 4Gm
0 8 24 (a) (b)
t (s) 2 R R
(a) 160 (b) 280
(c) 380 (d) 420 Gm 1 1
(c) (d)
14. In the adjoining figure, the position time graph 2R 2 R Gm
of a particle of mass 0.1 kg is shown. The impulse 20. Four equal charges Q each are placed at four
at t = 2 s is corners of a square of side a each. Work done in
carrying a charge –q from its centre to infinity is
6
x(m) 4 2q
(a) zero (b)
pe 0 a
2
0 1 2 3 4 5 6 q2 2q 2
Time (c) (d)
2pe 0 a pe 0 a
(a) 0.02 kg m/s (b) 0.1 kg m/s
(c) 0.2 kg m/s (d) 0.4 kg m/s 21. A network of resistances, cell and capacitor
15. The pressure on a square plate is measured by C( = 2 m F) is shown in adjoining figure.In steady
measuring the force on the plate. If the maximum state condition, the charge on 2 m F capacitor is
error in the measurement of force and length are Q, while R is unknown resistance. Values of Q
respectively 4% and 2%, then the maximum error and R are respectively
in the measurement of pressure is
(a) 1% (b) 2% 2V R 4 C
(c) 4% (d) 8% 10 V 4V
A I=1A 2µF B
16. The centre of a wheel rolling on a plane surface
moves with a speed n 0. A particle on the rim of 2
the wheel at the same level as the centre will be
moving at speed
(a) zero (b) v 0
(a) 4 m C and 10 W (b) 4 m C and 4 W
(c) 2v0 (d) 2v0 (c) 2 m C and 2 W (d) 8 m C and 4 W
22. As the electron in Bohr’s orbit of hydrogen atom 27. A lead shot of 1 mm diameter falls through a
passes from state n = 2 to, n =1, the KE (K) and long column of glycerine. The variation of the
the potential energy (U) changes as velocity with distance covered (s) is correctly
(a) K four fold, U also four fold represented by
(b) K two fold, V also two fold
(c) K four fold, U two fold
(d) K two fold, U four fold v v
23. To get an OR gate from a NAND gate, we need (a) (b)
(a) Only two NAND gates
(b) Two NOT gates obtained from NAND gates s s
and one NAND gate
(c) Four NAND gates and two AND gates v v
obtained from NAND gates
(d) None of the above (c) (d)
24. If a current I is flowing in a loop of radius r as
s s
shown in adjoining figure, then the magnetic field
induction at the centre O will be 28. If e 0 and m 0 represent the permittivity and
permeability of vaccum and and µ represent
the permittivity and permeability of medium, then
refractive index of the medium is given by

I e 0m 0 em
I (a) (b)
em e 0m 0
r
m 0 e0 m 0 e0
(c) (d)
e m
m0 I q 29. A students plots a graph between inverse of
(a) Zero (b)
4pr magnification 1/m produced by a convex thin
m 0 I sin q 2m 0 I sin q lens and the object distance u as shown in figure.
(c) (d) What was the focal length of the lens used?
4pr 4pr 2
25. Two indentical magnetic dipoles of magnetic
moment 1.0 Am2 each,placed at a separation of 1/m
2 m with their axes perpendicular to each other.
The resultant magnetic field at a point midway
b
between the dipoles is
(b) 5 × 10-7 T a c
(a) 5 ´10-7 T u
(c) 10 T -7 (d) 2 × 10-7 T
26. The natural frequency of the circuit shown in b bc
(a) (b)
adjoining figure is ca a
C C c b
(c) (d)
b c
30. Two waves y 1 = A 1 sin (wt -b1 ) and
L L
y2 = A2 sin (wt -b2 ) superimpose to form a
resultant wave whose amplitude is
1 1 (a) A1 + A2
(a) (b) (b) |A1 + A2|
2p LC 2p 2LC
(c) A12 + A22 - 2 A1 A2 sin (b1 - b2 )
2
(c) (d) zero
2p LC (d) A12 + A22 + 2 A1 A2 cos (b1 - b2 )
31. When a certain metallic surface is illuminated 36. A long glass capillary tube is dipped in water. It
with monochromatic light of wavelength , the is known that water wets glass. The water level
stopping potential for photoelectric current rises by h in the tube. The tube is now pushed
3V0.When the same surface is illuminated with a down so that only a length h/2 is outside the
light of wave length 2 , the stopping potential is water surface. The angle of contact at the water
V0. The threshold wavelength for this surface surface at the upper end of the tube will be
to photoelectric effect is (a) tan -12 (b) 60º
(a) 4 (b) 6 (c) 30º (d) 15º
4 37. In the adjoining circuit, if the reading of voltmeter
(c) 8 (d) V1 and V2 are 300 volts each, then the reading
3
32. In the V-T diagram shown in adjoining figure, voltmeter V3 and ammeter A are respectively
what is the relation between p1 and p2? C
L R = 100 W

p2
V
V1 V2 V3
p1
A

~
T 220 V, 50 Hz
(a) p2 = p1 (b) p2 < p1
(a) 220 V , 2.2 A (b) 100 V, 2.0 A
(c) p2 > p1 (d) insufficient data
(c) 220 V , 2.0 A (d) 100 V, 2.2 A
33. If a gas mixture contains 2 moles of O2 and 4
38. If the work done in turning a magnet of magnetic
moles of Ar at temperature T, then what will be
moment M by an angle of 90º from the magnetic
the total energy of the system (neglecting all
meridian is n times the corresponding work done
vibrational modes)
(a) 11 RT (b) 15 RT to turn it through an angle of 60º, then the value
(c) 8 RT (d) RT of n is
34. In the adjoining figure, two pulses in a stretched (a) 1 (b) 2
string are shown. If initially their centres are 1 1
8 cm apart and they are moving towards each (b) (d)
2 4
other, with speed of 2cm/s, then total energy of 39. The capacitance of a parallel plate capacitor with
the pulses after 2 s will be air as dielectric is C. If a slab of dielectric constant
K and of the same thickness as the separation
between the plates is introduced so as to fill
8 cm
1/4th of the capacitor (shown in figure), then the
(a) Zero new capacitance is
(b) Purely kinetic
(c) Purely potential
(d) Partly kinetic and partly potential K Air t
35. When two waves of almost equal frequency n 1
and n2 are produced simultaneously, then the
time interval between succesive maxima is t
1 1 1
(a) (b) + C C
n1 + n2 n1 n2 (a) (K + 2)
4
(b) (K + 3)
4
1 1 1 C
(c) - (d) (c) (K + 1) (d) None of these
n1 n2 n1 - n2 4
40. Seven resistance are connected between points 43. Benzene diazonium chloride on treatment with
A and B as shown in adjoining figure. The hypophosphorous acid and water yield benzene.
equivalent resistance between A and B is Which of the following is used as a catalyst in
10 this reaction?
(a) LiAlH4 (b) Red p
(c) Zn (d) Cu+
44. Consider the following reaction sequence,
10 3
A B Alcoholic
P/Br 2 KOH O3, H2O
CH2COOH A B C
5 8 6
CF3CO 3H
CH2COOH D Alkaline
E
KMno4

(a) 5 W (b) 4.5 W Isomers are

(c) 4 W (d) 3 W (a) C and E (b) C and D
(c) D and E (d) C,D and E
PART - II (CHEMISTRY) 45. When a monosaccharide forms a cyclic
41. Which of the following does not undergo hemiacetal, the carbon atom that contained the
benzoin condensation? carbonyl group is identified as the …. Carbon
atom,because
CH2CHO CHO (a) D,the carbonyl group is drawn to the right
(b) L, the carbonyl group is drawn to the left
(c) acetal,it forms bond to an –OR and an –
(a) (b) OR’
(d) anomeric, its substituents can assume an
b or position
CHO CHO
46. Which of the following is/ are - amino acid?

NH3
(c) (d) (a) (b) Q
Q
CO2 CO2
N
OCH3 CH3 H H
(c) Both (a) and (b) (d) None of these
47. Calculate pH of a buffer prepared by adding 10
42. COOH + NaHCO3 ® mL of 0.10 M acetic acid to 20 mL of 0.1 M sodium
acetate [pKa (CH3COOH) = 4.74]
(a) 3.00 (b) 4.44
CO2 + COONa + (c) 4.74 (d) 5.04
48. The equivalent conductance of silver nitrate
* solution at 250°C for an infinite dilution was
C is with the product found to be 133.3 –1 cm2 equiv-1. The transport
(a) CO2 number of Ag+ ions in very dilute solution of
AgNO3 is 0.464. Equivalent conductances of Ag+
(b) COONa and NO-3 (in –1 cm2 equiv–1) at infinite dilution
are respectively
(c) Both (a) and (b) (a) 195.2, 133.3 (b) 61.9, 71.4
(d) None of the above (c) 71.4, 61.9 (d) 133.3, 195.2
49. Treating anisole with the following reagents, the
major product obtained is
I. (CH3)3 CCl, AlCl3 II. Cl2, FeCl3 (a) (b)
III. HBr, Heat
(c) Both (a) and (b) (d) None is correct
OH Br KHSO HCIO
53. Glycerol 4
A B,
Br Br A –A and B respectively are
(a) (b)
O O
(a) CH2 CH CH
C(CH3)3 C(CH3)3
Cl OH
OCH3 OH
O O
Br Cl
(c) (d) (b) CH2 CHCH
OH Cl
C(CH3)3 C(CH3)3
OH
(c) CH3CH2CHO CH3CH2CH
50. Ketones [R—C—R’] where, R = R’ = alkyl Cl

O O
group can be obtained in one step by (d) CH2 CHCH
(a) Hydrolysis of esters
(b) Oxidation of primary alcohols ClO
(c) Oxidation of secondary alcohols 54. Phenol is heated with phthalic anhydride in the
(d) Reaction of acid halide with alcohols presence of conc. H2SO4. The product gives
51. An optically active compound ‘X’ has molecular pink colour with alkali. The product is
formula C4H8O3. It evolves CO2 with aqueous (a) phenolphthalein (b) bakelite
NaHCO3. ‘X’ reacts with LiAlH4 to give an
(c) salicylic acid (d) flurorescein
achiral compound.’X’ is
CuCN
(a) CH 3CH 2CHCOOH 55. C6H5NH2 0ºC X
+
H O/H
OH Y 2 Z, Z is identified as
(b) CH 3CHCOOH (a) C6H5 — NH—CH3
(b) C6H5 — CH2—NH2
OMe (c) C6H5 — CH2—COOH
(c) CH 3CHCOOH (d) C6H5—COOH
56. B can be obtained from halide by van-Arkel
method. This involves reaction
(d) CH 3CHCH2C OOH
(a) 2Bl3 Red hot W or Ta
OH
Red hot W or Ta
(b)
OH
52. conc.H2SO4
products. (c) Both (a) and (b)
(d) None of the above
Product is/are
57. NH4Cl(s) is heated in a test tube. Vapours are 64. Select the correct statements(s).
brought in contact with red litmus paper, which (a) LiAlH4 reduces methyl cyanide to methyl
changes it to blue and then to red. It is because amine
of
(b) Alkane nitrile has electrophilic as well as
(a) formation of NH4OH and HCl
nucleophilic centres
(b) formation of NH3 and HCl
(c) saponification is a reversible reaction
(c) greater diffusion of NH3 than HCl
(d) greater diffusion of HCl than NH3 (d) Alkaline hydrolysis of methane nitrile forms
methanoic acids
58. Out of H2S2O3, H2S2O4, H2SO5 and H2S2O8
peroxy acids are
conc.HNO3 + conc.H2SO4 Cl2/FeCl3
(a) H2S2O3, H2S2O8 (b) H2SO5, H2S2O8 65. X Y
(c) H2S2O4, H2SO5 (d) H2S2O3, H2S2O4
59. The density of solid argon is 1.65 g per cc at - The product Y is
233°C. If the argon atom is assumed to be a (a) p-chloro nitrobenzene
sphere of radius 1.54 × 10-8 cm, what per cent of (b) o-chloro nitrobenzene
solid argon is apparently empty space?
(c) m-chloro nitrobenzene
(Ar = 40)
(a) 16.5% (b) 38% (d) o, p-dichloro nitrobenzene
(b) 50% (d) 62% 66. End product of the following reaction is
60. When 1 mole of CO2(g) occupying volume 10L
at 27°C is expanded under adiabatic condition, O O + HBr
temperature falls to 150 K. Hence,final volume is
(a) 5 L (b) 20 L
(c) 40 L (d) 80 L
61. Acid hydrolysis of ester is first order reaction (a) O O
and rate constant is given by
Br
2.303 V -V0
k= log ¥ where, V0, Vt and V¥
t V¥ - Vt
OH
are the volumle of standard NaOH required to
neutralise acid present at a given time, if ester is
50% neutralised then (b) HO
(a) V¥ = Vt (b) V¥ = (Vt –V0)
(c) V¥ = 2Vt –V0 (d) V¥ = 2Vt + V0 Br
62. A near UV photon of 300 nm is absorbed by a
gas and then re-emitted as two photons. One
photon is red with wavelength of the second (c) Br OH
photon is
(a) 1060 nm (b) 496 nm
HO
(c) 300 nm (d) 215 nm
63. Which of these ions is expected to be coloured
in aqueous solution?
(d) HO OH
I. Fe3 + II. Ni2+ III. Al3+
(a) I and II (b) II and III
(c) I and III (d) I, II and III Br
67. Following compounds are respectively …
OH O
geometrical isomers
Cl
(a)
Cl Cl

Cl O O
P Cl Cl
Q R (b)
P Q R
(a) cis cis trans O
H3C O
(b) cis trans trans
(c) H3C
(c) trans cis cis
(d) cis trans cis
68. Which is more basic oxygen in an ester?
CH3 CH3
O
(d)
R— C—O—R
(a) Carbonyl oxygen, OH OH
(b) Carboxyl oxygen, b 72. For the cell reaction 2Ce4+ + Co ® 2Ce3+ +
(c) Equally basic
(d) Both are acidic oxygen Co3+ ; Eºcell cell is 1.89 V. If ECo2 + /Co is – 0.28 V,,
69. In a Claisen condensation reaction (when an º
ester is treated with a strong base) what is the value of E Ce4 + /Ceo3+ ?
(a) a proton is removed from the -carbon to (a) 0.28 V (b) 1.61 V
form a resonance stabilised carbanion of (c) 2.17 V (d) 5.29 V
the ester 73. A constant current of 30 A is passed through an
(b) carbanion acts as a nucleophile in a aqueous solution of NaCl for a time of 1.00 h.
nucleophilic acyl substitution reaction with
What is the volume of Cl2 gas at STP produced?
another ester molecule
(c) a new C—C bond is formed (a) 30.00 L (b) 25.08 L
(d) All of the above statements are correct (c) 12.54 L (d) 1.12 L
70. An organic compound B is formed by the reaction 74. Consider the following reaction,
of ethyl magnesium iodide with a substance A,
kA
followed by treatment with dilute aqueous acid, kB
Compound B does not react with PCC or PDC in Chair
Boat
dichloromethane. Which of the following is a
possible compound for A? The reaction is of first order in each diagram,
with an equilibrium constant of 104. For the
O O
conversion of chair form to boat form e–Ea/RT =
(a) CH—CH
2 2 (b) CH3CH2CCH3 4.35 × 10-8 m at 298 K with pre-exponential factor
of 1012 s-1. Apparent rate constant (= kA / kB)
O at 298 K is
(c) CH 3CH (d) H2C O (a) 4.35 × 104 s-1 (b) 4.35 × 108 s-1
(c) 4.35 × 10 s-8 -1 (d) 4.35 × 1012 s-1
O O
71. || || 75. If for the cell reaction, Zn + Cu2+ Cu+ Zn2+
CH3 C CH 2CH 2 COCH 2 CH3
Entropy change Sº is 96.5 J mol-1K-1, then
(i) CH3MgBr(one mole) temperature coefficient of the emf of a cell is
(ii) H 2O
A formed in this (a) 5 × 10-4 VK-1 (b) 1 ×10-3 VK-1
reaction is (c) 2 × 10-3 VK-1 (d) 9.65 × 10-4 VK-1
76. What transition in the hydrogen spectrum would
have the same wavelength as the Balmer
transition, n = 4 to n = 2 of He+ spectrum?
(a) n = 4 to n = 2 (b) n = 3 to n = 2
(c) n = 2 to n = 1 (d) n = 4 to n = 3
77. What is the degeneracy of the level of H-atom (d)
æ R ö
that has energy çç- H ÷÷÷ ?
çè 9 ø
(a) 16 (b) 9
(c) 4 (d) 1
78. Match the following and choose the correct 80. What is the EAN of [Al(C4O4)3]3–?
option given below. (a) 28 (b) 22
Compound/Type Use (c) 16 (d) 10
A. Dry ice I. Anti-knocking PART - III (MATHEMATICS)
compound
B. Semiconductor II. Electronic diode 81. The relation R defined on set A = {x : | x | < 3, x e I }
or triode by R = {(x, y) : y = | x |} is
C. Solder III. Joining circuits (a) {–2, 2), (–1, 1), (0, 0), (1, 1), (2, 2) }
D. TEL IV. Referigerant for (b) {(–2, –2), (–2, 2), (–1, 1), (0, 0), (1, –2), (1, 2),
preserving food (2, –1), (2, –2)}
A B C D (c) {0, 0), (1, 1), (2, 2)}
(a) I II IV III
(d) None of the above
(b) II III I IV
82. The solution of the differential equation
(c) IV III II I
(d) IV II III I dy yf '( x) - y 2
79. Which of the following ligands is tetradentate? = is
dx f ( x)
N (a) f(x) = y+C (b) f(x) = y(x+C)
H
(a) (c) f(x) = x+C (d) None of the above
NH2 NH2 83. If a,b and c are in AP, then determinant

x+ 2 x+3 x + 2a
x+3 x+4 x + 2b is
N x+4 x+5 x + 2c
(b) (a) 0 (b) 1
N N (c) x (d) 2x
84. If two events A and B. If odds against A are as
N
H2
2:1 and those in favour of A È B are as 3:1, then
1 3 5 3
NH (a) £ P( B) £ (b) £ P( B) £
2 4 12 4
(c) 1 3
(c) £ P(B) £ (d) None of these
4 5
NH
85. The value of 2 tan–1 (cosec tan–1 x – tan cot–1 x)
NH2 is
(a) tan–1 x (b) tan x
(c) cot x (d) cosec–1 x
86. The proposition ~ ( p Û q) is equivalent to (a) 4 £ x2 + y2 £ 64
(a) (p ~ q) Ù (q Ù ~ p) (b) x2+ y2 £ 25
(b) (p Ù ~ q) (q Ù ~ p)
(c) x2+ y2 ³ 25
(c) (p Ù ~q) Ù (q Ù ~ p)
(d) None of the above (d) 3 £ x2 + y2 £ 9
87. If truth values of P be F and q be T. Then, truth 94. A tower AB leans towards west making an angle
value of ~(~ p q) is with the vertical.The angular elevation of B,
(a) T (b) F the top most point of the tower is b as observed
(c) Either T or F (d) Neither T not F from a point C due east of A at a distance ‘d’
88. The rate of change of the surface area of a sphere from A. If the angular elevation of B from a point
of radius r, when the radius is increasing at the D due east of C at a distance 2d from C is r, then
rate of 2 cm/s is proportional to 2 tan can be given as
1 1 (a) 3 cot b – 2 cot (b) 3 cot – 2 cot b
(a) (b) (c) 3 cot b – cot (d) cot b – 3 cot
r r2
(c) r (d) r2 95. If and b are the roots of x2 – ax + b = 0 and if
89. If N denote the set of all natural numbers and R n + b n = V , then
n
be the relation on N × N defined by (a, b) R (c, d),
(a) Vn+1 = aVn + bVn-1
if ad (b + c) = bc (a + d ), then R is
(b) Vn+1 = aVn + aVn–1
(a) symmetric only
(c) Vn+1 = aVn – bVn–1
(b) reflexive only
(c) transitive only (d) Vn+1 = aVn-1 – bVn
(d) an equivalence relation 96. The sum of the series
90. A complex number z is such that arg æ 1 3r 7r 15r ö
çç + + + +...m terms÷÷is
å
n
r n
(–1) Crç ÷
æ z - 2 ö÷ z è2 2 ø÷
r 2r 3r 4r
çç 2 2
÷ = . The points representing this r =0
èç z + 2 ø÷ 3
complex number will lie on 2 mn -1 2 mn -1
(a) (b)
(a) an ellipse (b) a parabola 2 mn (2 n -1) 2 n -1
(c) a circle (d) a straight line
91. If a1, a2 and a3 be any positive real numbers, 2mn + 1
(c) (d) None of these
then which of the following statement is true? 2n + 1
(a) 3a1a2 a3 £ a13 + a23 + a33 97. The angle of intersection of the circles x2+ y2
– x + y – 8 = 0 and x2 + y2 + 2x + 2y – 11 = 0 is
a1 a2 a3
+ + ³3 æ19 ö
(a) tan–1 ççç ÷÷÷
(b)
a2 a3 a1 (b) tan –1(19)
è9ø
æ1 1ö
(a1 + a2 + a3 )ççç + + ÷÷÷ ³ 9
1 æ9ö
(c)
çè a1 a2 a3 ÷ø (c) tan–1 ççç ÷÷÷ (d) tan–1 (9)
è19 ø
æ1 98. The vector b = 3j + 4k is to be written as the sum
1 a ö
3

(d) (a1. a2 . a3 )ççç + + 3 ÷÷÷ ³ 27 of a vector b1 parallel to a = i + j and a vector b2

è a1 a2 a3 ÷ø perpendicular to a. Then b1 is equal to
92. If | x2 – x – 6 | = x + 2, then the values of x are 3 2
(a) –2, 2, –4 (b) –2, 2, 4 (a) (i + j) (b) (i + j)
2 3
(c) 3, 2, –2 (d) 4, 4, 3
93. The centres of a set of circles, each of radius 3, 1 1
lie on the circle x2 + y2 = 25. The locus of any (c) (i + j) (d) (i + j)
2 3
point in the set is
99. If the points (x1, y1), (x2, y2) and (x3, y3) are
x 1
collinear, then the rank of the matrix (c) xe x C
é x1 y1 1ù
1
x x
ê x y 1ú will always be less than (d) xe x C
ê 2 2 ú 106. If f (x) = x – [x], for every real number x, where [x]
êë x3 y3 1úû
1
(a) 3 (b) 2 is the integral part of x. Then, ò f ( x ) dx is equal
(c) 1 (d) None of these -1
100. The value of the determinant to
1 cos ( ) cos (a) 1 (b) 2
cos ( ) 1 cos is
cos cos 1 1
(c) 0 (d)
2
2 2 2 2
(a) (b) 107. The value of the integral
(c) 1 (d) 0
é ù
1/ 2

êçæ x + 1÷÷ö + çæ x -1 ÷÷ö - 2ú dx is

2 2

ò–1/2 êêçè x -1÷ø çè x +1÷ø úú

1/2
101. The number of integral values of K, for which
ç ç
the equation 7 cos x + 5 sin x = 2K + 1 has a ë û
solution, is
(a) 4 (b) 8 æ4ö æ3ö
(c) 10 (d) 12 (a) log ççèç ø÷÷÷ (b) 4 log çççè ø÷÷÷
3 4
102. The line joining two points A(2,0), B(3,1) is
æ4ö æ3ö
(c) 4 log ççç ÷÷÷ (d) log ççç ÷÷÷
rotated about A in anti-clockwise direction
through an angle of 15°. The equation of the line è3ø è4ø
in the now position,is
4
(a) 3x–y–2 3 =0 108. If a tangent having slope of - to the ellipse
3
(b) x – 3 y – 2 = 0
x2 y 2
+ = 1 intersects the major and minor axes
(c) 3 x+y–2 3 =0 18 32
(d) x + 3y – 2 = 0 in points A and B respectively, then the area of
OAB is equal to (O is the centre of the ellipse)
103. The line 2x + 6y = 2 is a tangent to the curve (a) 12 sq units (b) 48 sq units
x2–2y2 = 4. The point of contact is (c) 64 sq units (d) 24 sq units
109. The locus of mid points of tangents intercepted
(a) (4, – 6) (b) (7, – 2 6)
x2 y2
(c) (2, 3) (d) ( 6,1) between the axes of ellipse + = 1 will be
a2 b2
104. The number of integral points (integral point
means both the coordinates should be integer) a2 b2 a 2 b2
(a) + =1 (b) + =2
exactly in the interior of the triangle with vertices x2 y2 x2 y2
(0, 0), (0, 21) and (21, 0) is
(a) 133 (b) 190 a 2 b2 a 2 b2
(c) + =3 (d) + =4
(c) 233 (d) 105 x2 y2 x2 y2

ò (1 + x - x ) e x+ x 110. If PQ is a double ordinate of hyperbola

—1
—1
105. dx is equal to
x2 y2
x x 1 - = 1 . Such that OPQ is an equilateral
(a) ( x 1) e C a2 b2
triangle, O being the centre of the hyperbola,
x 1
(b) ( x 1)e x C then the eccentricity ‘e’ of the hyperbola satisfies
2
e=
2 ìï p
(a) 1 < e < (b) ïï(1+ | sin x |)a /|sin x| , - < x < 0
3 3 ïï 6
117. If f (x) = í b , x=0 , then
2 ïï p
e=
3
(d) e > ïe tan 2 x /tan 3 x
, 0< x <-
(c)
2 3 ïîï 6
111. The sides AB, BC and CA of a ABC have the value of a and b, if f is continuous at x = 0,
respectively 3, 4 and 5 points lying on them.The are respectively.
number of triangles that can be constructed
using these points as vertices is 2 3 2 2/3
(a) , (b) ,e
(a) 205 (b) 220 3 2 3
(c) 210 (d) None of these 3 3/ 2
(c) ,e (d) None of these
a + bx 2
112. In the expansion of , the coefficient of
ex 118. The domain of the function
x r is 1
f ( x) = + x + 2 is
a-b a - br log10 (1- x )
(a) (b)
r! r!
(a) ] 3, 2.5 2.5, 2[
a - br
(c) (-1) r (d) None of these (b) [ 2, 0 0, 1[
r!
(c) ]0, 1[
113. If n = (1999) !, then å log n x is equal to
1999
(d) None of the above
x=1 119. The solution of the differential equation
(a) 1 (b) 0 1 dy
(1+ y2) + ( x etan y ) 0, is
(c) 1999
1999 (d) –1 dx
114. P is a fixed point (a, a, a) on a line through the (a) (x – 2) = Ke tan 1
y
origin equally inclined to the axes, then any plane
through P perpendicular to OP, makes intercepts (b) 1 2 –1
2 xe tan y = e tan y + K
on the axes, the sum of whose reciprocals is
(c) xetan–1y = tan–1 y + K
equal to
(d) xe2tan–1y = etan–1y + K
3 120. If the gradient of the tangent at any point (x, y)
(a) a (b)
2a æ pö
of a curve which passes through the point ççç1, ÷÷÷
3a è 4ø
(c) (d) None of these
2
ïìï y æ öüï
2 y ֕
is íï - sin èççç ÷÷øýï , then equation of the curve is
115. For which of the following values of m, the area
of the region bounded by the curve y = x – x2 îï x x þï
9 (a) y = cot –1 (log e x)
and the line y = mx equals
2
æ x ö÷
(a) – 4 (b) – 2 y = cot –1 ççloge ÷
èç e ø÷
(b)
(c) 2 (d) 4
116. If f : R R be such that f (1) =3 and f (1) = 6.
(c) y = x cot –1 (log e ex )
ïìï f (1 + x ) ïüï
1/ x

Then, lim íï ý equals to æ e ö÷

y = cot –1 ççloge ÷
x®0 ï î f (1) ïïþ (d)
èç x ø÷
(a) 1 (b) e 1/2
(c) e 2 (d) e 3
SOLUTIONS
PART - I (PHYSICS) 2 8
and or = 8 m v=
= 2 m/s
1. (d) As we know, velocity of electromagnetic 4 4
So, the distance travelled by wave in t
1
wave, c = = 3 × 108 m/s second = vt = 2 × 5 = 10 m
0 0 6. (a) Gravitational intensity,
It is in dependent of amplitude of dv d k 2k
electromagnetic wave, frequency and I=
wavelength of electromagnetic wave. dx dx x 2 x3
2. (b) According to Moseley’s law v = a (z – b) 7. (d) For Cu wire, l1 = 2.2 m, r1 = 1.5 mm
= 1.5 × 10–3n
or v = a2 (z – b)2 Y1 = 1.1 × 1011 N/m2
c For steel wire, l2 = 1.6m, r2 = 1.5 mm
or = a2 (z – b)2 = 1.5 × 10–3 m
Y2 = 2.0 × 1011 N/m2
1 (z 2 1) 2 Let F be the stretching force in both the
(z1 1)2 wires the
2
Here 1 = ,, 2 = 4 , z1 = 11 and z2 = ? F l1
For Cu wire, Y1 =
r12 l1
1 (z 2 1) 2
4 (11 1) 2 Y1 r12 l1
F=
or (z2 – 1)2 = 25 or z2 = 6 l1
3. (b) As we know, conductivity,
1 1.1 10 11 22
( = × (1.5 × 10–3)2 × 0.5 × 103
= ene n nn ) 2.2 7
= 1.6 × 10–19 [0.36 + 0.17] (2.5 × 1019)] = 1.8 × 102 N
= 2.12 Sm–1 8kT
4. (d) If a radio receiver amplifies all the signal 8. (a) Mean speed, v = 0.92v rms
m
frequencies equally well, it is said to have
high fidelity. 3kT
rms speed, v rms
t x m
5. (b) Given, y = 3 sin Most probable speed vp
2 4
t x 2kT
= 3 sin = 0.816vrms
2 4 m
Comparing it with standard equation i.e., v p v vrms
2 9. (b) Let two balls collide at a height s from the
y = r sin (vt x)
ground after t second when second ball is
thrown upwards.
2 vt 2 x
= rsin Time taken by first ball to reach the point
of collision = (t + 2) s
2 v 1
We have, or v = s = 39.2 (t + 2) + (–9.8) (t + 2)2
2 4 2
= 39.2 (t + 2) – 4.9 (t + 2)2 ...(i) to time axis i.e., body comes to rest.
For second ball Change in velocity = dx = 2 m/s
1 Impulse = Change in momentum
s = 39.2t + (–9.8) t2 = mdv = 0.1 × 2 = 0.2 kg m/s
2
= 39.2t – 4.9 t2 ...(ii) force F
From eqs. (i) and (ii) 15. (d) Pressure =
area L2
39.2 (t + 2) – 4.9 (t + 2)2 = (39.2) t – 4.9t2
On solving we get, t = 3s p F 2 L
From Eq. (ii), = 4% + 2 (2%)
p F L
s = 39.2 × 3 – 4.9 × (3)2 = 117.6 – 44.1 = 73.5
m or percentage error, = 8%
16. (d) The situation can be shown as
F
10. (b) Magnetic flux, = B.A = .A
I
[M1L 1T 2 ]L2
= = [M1 L2 T–2 A–1] v0 R
[A.L] O O P
11. (c) Given, P = P0 exp (– t2) R R r
As P and P0 have the same units, therefore v
t 2 must be dimensionless for which
Here v0 = R
1 2
= T At. P, v = r
T2
= (R 2 R 2 ) 2R 2v0
M N
12. (d) Given, U = 6 17. (b) Using principle of conservation of linear
r r12
momentum,
du d M N
F= 3m × v = (m 60) 2 (m 60) 2
dr dr r 6 r12
6M 12N 6M 12N = m 60 2
= =
r7 r13 r7 r13 v = 20 2 m/s
For equilibrium position, F = 0 m1v1 m 2 v 2
6M 12N 18. (a) Common velocity, v =
6
2N m1 m 2
13 or r =
r7 r M
2 6 2 0
= = 3 m/s
M N M2 2 2
Hence, U =
(2N/ M) (2N / M) 2 4N Initial kinetic energy (E1)
13. (b) Total number of revolutions = area under 1 1 1
n–t graph = m1v12 m 2 v 22 2 (6) 2 = 36J
2 2 2
1 1800 600 1 600
= 8 8 16 1 1
2 60 60 2 60 = (m1 m 2 )V 2 (2 2)(3) 2 = 18J
2 2
= 120 + 80 + 80 = 280
14. (c) From the graph we can say, upto t = 2.0 s, Heat evolved = (36 – 18) J = 18 J
the body moves with a constant velocity 19. (a) From given condition
4 Gmm mv2 Gm 1 Gm
Slope of position-time graph = = 2m/s 2
,v
2 (2R) R 4R 2 R
After t = 2.0 s, position-time graph is parallel
20. (d) At the centre O of the square due to four or K1 = 4K2
equal charges q at the corners, potential
a U 2 l2 1
q q U1 22 4
or U1 = 4U2
O 23. (b) To obtain OR gate from NAND gates we
a a need two NOT gates obtained from NAND
gates and one NAND gate as figure.

q q A
a
4q 2q Y
V= 4 (a 2) / 2 =
0 0a
W0 =– W 0 B

2q Boolean expression = A.B. = A B

= – (–q)V =
0a = A + B OR gate
21. (a) In the steady state, current through 02 I
capacitor 24. (b) Magnetic field B =
4 r
10V 2V R C 4 4V Here, 2 =
A I B 0 I
2µF B=
4 r
2 25. (a) Since axes are perpendicular so mid point
lies on axial line of one magnet and on
equitorial line of other magnet
I
2M 7
0 10 2 1
D B1 = 3 = 3 = 2 × 10–7 T
4 d 1
Using Kirchhof’s voltage law to the circuit
ACD 7
0 M 10 1
We have, 10 – 2 + 1 × R + 1 × 2 = 0 and B2 = = = 10–7 T
4 d 3 3
or R = 10 1
Potential difference across C and D
As B1 B2
VC – VD = 2 × 1 = 2V
As VD = 0V Resultant magnetic field
So, VC = 2V
Potential difference across capacitor
= B12 B22 5 10 7 T
= 4 – 2 = 2V 26. (a) In the given circuit, two condensors and
Charge on capacitor Q = CV = 2 F × 2 = 4 C the inductor are in series.
1 Ls = L + L = 2L
22. (a) KE of an electron in nth orbit : Kn 1 1 1 2 C
n2 Cs
and C C C C 2
and PE of an electron in nth orbit : s
1 Natural frequency of the circuit
Un
n2 1 1
When an electron passes from state v= 2 L s Cs 2 2L C/2
n = 2 to n = 1
1
K2 l2 1 =
2 LC
K1 22 4
27. (a) In the beginning due to gravity pull, the 32. (b) In an isobaric process, p = constant
lead shot will be accelerated and hence will Hence, V T
move, with increasing velocity for some time
When the viscous force balance the gravity nR
i.e., V = T
pull, then the shot will move with constant P
velocity. As in the beginning, the velocity
of shot is not fully linear with the effective 1
distance covered by the shot. V–T graph is a straight line with slope
p
(slope)2 > (slope)1
28. (b) Refractive index of a medium = p2 < p1
0 0
33. (a) Total energy
1 1 1
29. (c) Lens formula, n1 n2
v u f U= 2 RT 4 RT
2 2
u u
or 1 For O2, n = 5 and for Ar, n 2 = 3
v f
5 3
1
1
u U= 2 RT 4 RT = 11RT
T
2 2
m f
34. (b) Given, speed of each pulse = 2 cm/s
1 1 Therefore distance travelled by both pulses
or u 1
m f in 2s = 4 cm toward each other. On their
this is the equation of a straight line whose superposition, the resultant displacement
slope at every point will be zero.
1 b c Hence, total energy will be purely kinetic.
f= 35. (d) Time interval between two successive
f c b
30. (d) Amplitudes A1 and A2 are added as vectors. maxima = time interval between two
Angle between the two vectors is the phase 1
difference ( 1 – 2) between them. successive beats = n n
Resultant wave, 1 2

R= A12 A 22 2A1A 2 cos( 2s cos 0 2s

1 2) 36. (b) Here, h = ...(i)
r g r g
hc
31. (a) Here, case (i) e(3V0) = 0 ...(i) According to question,
h 2scos
...(ii)
hc 2 rpg
Case (ii) eV0 = 0 ...(ii)
2 Dividing eq. (ii) by (i) we get,
From eqs. (i) and (ii),
1
3hc hc cos
3 2
0 0
2 or = 60°
3hc hc hc 37. (a) Given, V1 = V2 = 300V; V3 = ?, i = ?
or 3 0 0 = 2 0
2 2
As, V = V32 (V1 V2 ) 2
hc
or, 0= 4 220 = V32 V3 V3 = 220V
Threshold wavelength
V3 220
hc
hc I= = = 2.2A
0= = 4 4 R 100
0 hc
38. (b) We have, W = – MB(cos 2 – cos 1)
So, W1 = –MB (cos 90° – cos0°) = MB *
42. (a) COOH NaHCO3
1
and W2 = – MB (cos 60° – cos 0°) = MB
2
As W1 = nW2 *
COONa CO2 H 2O
W1 MB
n= =2
W2 1 N=NCl
MB
2
Cu
43. (d) H 3 PO 2 H 2O
0A
39. (b) Capacitance, C =
d
As one–fourth of capacitor is filled with
dielectric of constant K, then, + N2 + HCl
K 0A / 4
C1 = 44. (c)
d
CH2COOCH P/Br2 BrCHCOOCH
3A / 4
and C2 = HVZ-reaction
d CH2COOCH CH2COOCH
A
Both C1 and C2 are in parallel.
K 0A 3 0A
Alc. KOH CHCOOCH
CP = C1 + C2 =
4d 4d CHCOOH
B (maleic acid)
0A C
= (K + 3) (K 3)
4d 4
40. (c) The equivalent circuit of the given circuit COOH
is CHCOOH COOH
HO—C—H CF3CO3H O3
H2O
2
5 C 3 H—C—OH CHCOOH COOH
A B B C
COOH
Alkaline
KMnO4

(oxalic acid)
D
d(+) and l(–)
5 8 3 tartaric acid
(racemic mixture) COOH

D H—C—OH
H—C—OH
This is a balanced Wheatstone bridge.
Therefore, the arm CD becomes in effective. COOH
E
Hence 5 and 3 are in series and they meso-tartaric acid
together are in parallel with (5 + 3)
(5 3) (5 3) 45. (d) When two cyclic forms of a carbohydrate
Net resistance = 4
(5 3) (5 3) differ in configuration only at hemiacetal
carbons, they are said to be anomers. Thus,
PART - II (CHEMISTRY) anomers are cyclic forms of carbohydrates
that are epimeric at hemiacetal carbon and
41. (a) Benzoin condensation is performed by
aromatic aldehydes (i.e., compounds in this carbon (C–1 of aldose) is called
which –CHO group is directly attached with anomeric carbon, e.g.,
benzene ring).
50. (c) Oxidation of Ketones, yield secondary
Anomeric carbon alcohol
R [O] R
HO—C—H CHOH C=O
H—C—OH R K2Cr2O 7/H2SO4 R
H—C—OH H—C—OH
R R
HO—C—H PCC C= O
HO—C—H CHOH
R CH2Cl2 R
H–C O H—C—OH
CH2OH R CH3
H—C O CHOH + C=O
-D-glucose
CH2OH R CH3
-D-glucose [(CH 3)3CO]3Al R
C=O
46. (c) – amino acids are bifunctional organic R
compounds. They contain a basic amino
group (–NH2) on the –carbon and one 51. (c) Since, X NaHCO3 CO 2
acidic carboxyl group (–COOH). Hence, it must contain —COOH group.
47. (d) [CH3COOH] = millimoles of CH3COOH
Achiral carbon
= 0.1 × 10 = 1.0
CH2OH CH3
[CH3COONa] = millimoles of CH3COONa
LiAlH 4
= 0.1 × 20 = 2.0 H—C—COOH H—C—CH2OH
From, Henderson Hasselbalch equation,
CH3 CH2OH
[conjugate base]
pH = pKa + log 52. (a)
[acid]
2 OH2
= 4.74 + log = 4.74 + 0.30 = 5.04 OH conc. H2SO4
1

–H2O
48. (b) (Ag + ) = tr an sport number of
Ag+ × A(AgNO3 )
= 0.464 × 133.3 = 61.9 –1 cm2 equiv–1
By Kohlrausch’s law H can be lost only from this
carbon (3° carbocation (X)
(AgNO3 ) 1, 2-methyl shift
(Ag ) (NO3 )

(NO3 ) (AgNO3 ) (Ag )

(3° carbocation (Y))
= 133.3 – 61.9 = 71.4 –1 cm2 equiv–1
49. (d) Y is less soluble than (X) due to lack of
symmetry Chiral carbon. This is reduced
OCH3 OCH 3 to —CH2OH
Activating
group 53. (b)
(CH3)3CCl/AlCl3
Friedel-Crafts CH2OH CH2 CH2
KHSO4 –
C(CH 3) 3 CHOH CH CH
OCH3 CH2OH CHO CHO
Cl Cl CH2OH
Cl2/FeCl3 HBr, –
OH–Cl CHCl
CHO
C(CH3) 3 C(CH3)3
54. (a)
O O
H2S2O4
O HO—S—S—OH
C O O
O C H2SO5 HO—S—O—O—H
O O
O C O O
H + H
conc.
H2S2O8 HO—S—O—O—S—OH
H2 SO4
O O
59. (d) Volume of one molecule
OH OH OH OH 4 3 4
(phenolphthalein) = r = (1.54 × 10–8)3 cm3
3 3
NaOH (Phenolphthalein = 1.53 × 10–23 cm3
test) Volume of molecules in 1.65 g Ar
Pink colour
1.65
= N0 1.53 10 23 = 0.380 cm3
55. (d) 40
Volume of solid containing 1.65 g Ar = 1 cm3
NaNO2 /HCl
Empty space = 1 – 0.380 = 0.620
NH2 0°C
N NCl Per cent of empty space = 62%
60. (d) In adiabatic expansion
1
CuCN
CN T2 V1
T1 V2
Y
+ for CO2 (triatomic gas) is,
H2O/H
= 1.33
0.33
COOH 150 10
300 V2
56. (a) According to Van–Arkel method, pyrolysis 0.33
of BI3 is carried out in the presence of red 1 10
hot W or Ta filament. 2 V2
2BI3 Red hot w or Ta filament 2B + 3I2 3
1 10
57. (c) NH 4 Cl(s) NH 3 HCl 2 V2
Graham’s law of diffusion says, lighter gas
will diffuse most rapidly. Therefore, NH3 1 10
will be (mol. wt. = 17) diffused rapidly than 8 V2
HCl. (mol. wt. = 36.5). V2 = 80 L
58. (b) Peroxy acids contain —O—O— linkage.
61. (c) H
O RCOOR H2O RCOOH R OH
At t = 0, a 0 0
H2S2O3 H—O—S—O—H At time t, a – x x x
O At time , a – a a a
At t = 0, V0 = volume of NaOH due to H+ (catalyst)
Vt = x + V0
V = a + V0 66. (d)

a
If ester is 50% hydrolysed then, x =
2 H Br –
O O O O– 1,4-addition
a
or Vt = V0
2 Br Br
or a = 2Vt – 2V0
V = 2Vt – 2V0 + V0 Enolisation
O OH HO OH
= 2Vt – V0
62. (b) Energy values are additives.
E = E1 + E2 67. (a)
hc hc hc
Cl Cl Cl
1 2

1 1 1 Cl
Cl' Cl'
300 760 2 cis cis trans
p. Q. R
1 1 1
2 300 760 O
= 495.6 nm = 496 nm 68. (a)
R—C—O—R
63. (a) I. Fe2+ = Ar –O oxygen atom can donate lone pair of
6 electron more easily, therefore, it is more
3d basic than –oxygen.
4 unpaired electrons,
Coloured ion, 69. (d) When two molecules of an ethylacetate
undergo condensation reaction, in presence
II. Ni2+ = Ar of sodium ethoxide involving the reaction
8 is called as Claisen condensation and
3d
2 unpaired electrons, product is a –keto ester.
Coloured ion O
III. Al3+ = [Ne] (i) CH3O–
No unpaired electron in 3d, colourless ion. 2CH3CH2COCH3 +
(ii) H

64. (b) CH3C N: CH3C = N :

O O
electrophilic nucleophilic
65. (c)
NO2 CH3
conc. HNO3 + conc. H 2SO 4
Mechanism
Step I
X
NO2 O O
CH3CHCOCH3 CH3CHCOCH3 + CH3OH
Cl2/FeCl 3
H –
CH3O
Cl
Y
Step II 71. (c) Keto group is more reactive for addition of
Grignard reagent.
O O O O
|| ||
CH3CHCOCH
– 3 + CH3CH2COCH3 CH3 C CH3 CH 2 C OCH 2 CH3
–
O
(i)CH3MgBr(one mole)
CH3CH2COCH3 (ii) H3O
CH3CHCOCH3
CH3 CH3
O
CH3—C—CH2CH2 CH3—C—CH2
Step III
OH C=O O CH2
–
O
O O C2H5O C
CH3CH2C—OCH3
CH3CH2CCHCOCH3
– O
CH3CHCOCH3 + CH3O
CH3 72. (b) E cell E ox E red
O
70. (b) B is a tertiary alcohol based on given = E Co / Co 2 E
Ce4 / Ce3
properties.
1.89 = – (–0.28) + E Ce 4 / Ce3
H3O
(a) CH2 CH2 CH3CH2MgI
E = – 1.879 – 0.28 = 1.61 V
Ce 4 / Ce3
CH 3CH 2CH 2 CH 2OH 73. (c) Due to electrolysis
1 alocohol
2H 2 O(l ) 2e H 2 ( g ) 2OH ( aq)
O
2Cl (aq) Cl2 ( g ) 2e
(b) CH3CH2CCH3 CH3CH2 Mgl
2H2 O(l ) 2Cl ( aq) H2 ( g ) Cl2 ( g )
OH + 2OH– (aq)
CH3CH2CHCH2CH3 OH– formed = NaOH formed = Z i t
H3O E
CH3 = i t
3°alcohol 96500
40
H 3O = 30 1 60 60 = 44.77 g
(c) CH 3CHO CH 3 CH 2 Mgl 96500
44.77
CH3 CH CH2 CH3 = = 1.12 mol
40
-Carbon atom OH
1
2° alcohol Cl 2 formed = mol of NaOH
2
(d) HCHO CH 3 CH 2 Mgl H3 O 1.12
= = 0.56 mol
2
CH 3 CH 2 CH 2 OH = 0.56 × 22.4 L at STP = 12.54 L
1 alcohol
74. (b) KB = Ae E a / RT R H Z2
En =
= 1012 × 4.35 × 10–8 n2
= 4.35 × 104 s–1 where, Z = atomic number, n2 = degeneracy
kA R H (1)2
Also equilibrium constant, k = k = 104 For H–atom, En =
B n2
kA = kB × 104 = 4.35 × 108 s–1 RH RH
dE 9 n2
75. (a) G = H – nFT dT n2 = 9
P
and G = T–T S 78. (d)
Compound Symbol/ Uses
S dE
formla
nF dT P
A. Dry ice CO2 Referigerant
96.5 dE for preserving
or food
2 96500 dT P B. Semicon Ge Electronic diode
3
ductor and triode in
dE cell 1 10 computer
= 5 × 10–4 VK–1
dT P 2 C. Solder Sn/Pb Joining circuits
D. TEL (C2H5)4 Pb Antiknocking
76. (c) We have to compare wavelength of
compound for
transition in the H–spectrum with the Balmer
petroleum
transition n = 4 to n = 2 of He+ spectrum.
products
H= He 79. (c)

2 1 1 1 1
R H ZH R H Z2
n12 n 22 He 2 2
42 N
H N
1 1 1 1 NH2 NH2; N
1 4 N
n12 n 22 4 16 (a) tridentate (b) tridentate

1 1 4 1 NH2 CH3
4
n12 n 22 16 NH C=O

1 1 3 NH CH2

n12 n 22 4 C=O
NH2
If n1 = 1, then n2 = 2, 3, .... CH3
(c) tetradentate (d) bidentate
For first line n2 = 2, n1 = 1
1 1 1 1 3 80. (b) Effective atomic number EAN = Atomic
number – oxidation number + 2 ×
12 22 1 4 4
coordination number
Hence, trnasition n2 = 2 to n1 = 1 will give For [Al (C2O4)3]3–
spectrum of the same wavelength as that Z = 13
of Balmer transition, n2 = 4 to n1 = 2 in He+. ON = 3
77. (b) Energy of the electron in the nth orbit in CN = 6
terms of RH is EAN = 13 – 3 + 2 × 6 = 22
PART - III (MATHEMATICS) 3
P(B) P (A B) =
81. (a) A = { x : |x| < 3, x I} 4
A = {x : – 3 < x < 3, x I} = {–2, –1, 0, 1} 5 3
Also, R = {(x, y) : y = |x|} P(B)
12 4
R = {(–2, 2), (–1, 1), (1, 1), (0, 0), (2, 2)}
85. (a) 2 tan –1 (cosec tan–1 x – tan cot–1 x)
2
dy yf (x) y
82. (b)
dx f (x) –1 1 x2
= 2 tan–1 cosec cosec
yf (x) dx – f(x) dy = y2 dx x

yf (x)dx f (x)dy
= dx 1 1
y2 tan tan
x
f (x)
d = dx 1 x2 1
y = 2 tan–1
x x
On integration, we get
f (x)
=x+C 1 x2 1
y = 2 tan–1
f (x) = y (x + C) x

x 2 x 3 x 2a sec 1
= 2 tan–1 (put x = tan )
83. (a) Let = x 3 x 4 x 2b tan
x 4 x 5 x 2c
1 cos
= 2 tan–1
x 2 x 3 x 2a sin
1
= 0 0 2(2b a c)
2 2sin 2
x 4 x 5 x 2c
=2 tan–1 2
(using R2 2R2 – R1 – R3)
2sin .cos
But a, b and c are in AP using 2b = a + c, we 2 2
get
x 2 x 3 x 2a = 2 tan–1 tan
1 2
= 0 0 0 =0
2
x 4 x 5 x 2c 1
= 2. tan x
Since, all elements of R2 are zero. 2
86. (b) ~ (p q) ~ [( p q) (q p)]
1 3
84. (b) P (A) = , P (A B) = ~ (p q) (~ (q p))
3 4
P (A B) = P(A) + P (B) – P (A B) ( De–Morgan’s law)
P(A) + P (B) (p ~ q) (q ~ p)
3 1 87. (b)
P(B) p q ~ p ~ p q ~ (~ p q )
4 3
F T T T F
5
P(B)
12
Also, B A B Truth value of ~ (~ p q) is F..
88. (c) Surface area of sphere, 91. (d) We know that, GM HM
S = 4 r2
3
dr (a1.a2.a3)1/3
and =2 1 1 1
dt
a1 a2 a3
ds dr
4 2r 8 r 2 16 r
dt dt 27
(a1.a2.a3) 3
ds 1 1 1
r
dt a1 a2 a3
89. (d) For (a, b), (c, d) N × N
3
(a, b) R (c, d) 1 1 1
ad (b + c) = bc (a + d) (a1.a2.a3) 27
a1 a2 a3
Reflexive : ab (b + a) = ba (a + b), ab N
(a, b) R (a, b) 92. (b) |x2 – x – 6| = x + 2, then
So, R is reflexive, Case I : x2 – x – 6 < 0
Symmetric : ad (b + c) = bc (a + d) (x – 3) (x + 2) < 0
bc (a + d) = ad (b + c) –2<x<3
cd (d + a) = da (c + b) In this case, the equation becomes
(c, d) R (a, b) x2 – x– 6 = –x – 2
So, R is symmetric. or x2 – 4 = 0
Transitive : For (a, b), (c, d), (e, f) N × N x=±2
Let (a, b) R (c, d), (c, d) R (e, f) Clearly, x = 2 satisfies the domain of the
ad (b + c) = bc(a + d), cf (d + e) = de (c + f) equation in this case. So, x = 2 is a solution.
adb + adc = bca + bcd ...(i) Case II : x2 – x – 6 0
and cfd + cfe = dec + def ...(ii) So, x – 2 or x 3
On multiplying eq. (i) by ef and eq. (ii) by In this case, the equation becomes
ab and then adding, we have x2 – x – 6 = 0 = x + 2
adbef + adcef + cfdab + cfeab
i.e., x2 – 2x – 8 = 0 or x = –2, 4
= bcaef + bcdef + decab + defab
Both these values lie in the domain of the
adcf (b + e) = bcde (a + f)
equation in this case, so x = –2, 4 are the
af (b + e) = be (a + f)
(a, b) R (e, f) roots.
So, R is transitive. Hence, roots are x = –2, 2, 4.
Hence R is an equivalence relation. 93. (a) Let (h, k) be any point in the set, then
equation of circle is
z 2 (x – h)2 + (y – k)2 = 9
90. (c) arg
z 2 3
8
x 2 iy
arg
x 2 iy 3
2
arg (x – 2 + iy) – arg (x + 2 + iy) =
3
y 1 y
tan–1 tan
x 2 x 2 3
(h, k) lies on x2 + y2 = 25, then h 2 + k2 = 25
4y 2 Distance between the two circles 8
3
x2 y2 4 2 h2 k2 8
3(x 2 2
y ) 4y 4 3 = 0 4 h 2 + k2 64
Locus of (h, k) is 4 (x2 + y2) 64
which is an equation of a circle.
94. (c) By m – n theorem at C
1 1 1
(d + 2d) cot = d cot – 2d cot (90° + ) + ... upto m terms
2n 4n 8n
Y(N)
1 1
1
2 n
2 mn 2mn 1
B =
1
1 2mn (2n 1)
n
2

(W)X' X(E) 97. (c) Angle of intersection between two circles

A d C 2d D is given by

17 10
r12 r22 d 2 13
cos = 2 4
Y'(S) 2r1r2 17
2 . 13
2
3d cot = d cot + 2d tan
3 cot = cot + 2 tan
2 tan = 3 cot – cot
2 2
95. (c) Multiplying x2 – ax + b = 0 by xn–1, we get 1 1
here, r1 8
xn+1 – axn + bxn–1 = 0 ...(i) 2 2
are roots of x2 – ax + b = 0, therefore
they will satisfy (i). 17
,
Also, n+1 – a n + b n–1 = 0 ...(ii) 2
and n+1 – a n + b n–1 = 0 ...(iii) r2 13
On adding eqs. (ii) and (iii), we get
10
( n+1 + n+1) – a ( n + n) and d c1c 2
+ b( n–1 + (n–1)) = 0 2
Vn+1 – aVn + bVn–1 = 0 ( n + n = Vn)
Vn+1 = aVn – bVn–1
19
n cos =
( 1)r .n Cr 442
96. (a)
r 0
9
r r or tan =
1 3 7 19
...upto m terms
2r 22r 23r
9
= tan–1
19
n
1 n
3r
( 1)r .n Cr ( 1)r .n C r .
2r 22r 98. (a) b1|| a b1 = a (i + j)
r 0 r 0
b2 = b – b1 = (3 – a) i – aj + 4k
n
7r Also, b2 . a = 0
( 1) r .n C r . ...
r 0 23r 3
(3 – a) – a a=
2
n n n
1 3 7
1 1 1 3
2 4 8 b1 = (i + j)
2
... upto m terms
Thus, slope of new line is tan (45° + 15°)
x1 y1 1
= tan 60° = 3
x2 y2 1
99. (b) The given matrix is , ( it is rotated anti-clockwise, so the angle
x3 y3 1
will be 45° + 15° = 60°)
using R2 R2 – R1, R3 R3 – R1
Y C
x1 y1 1
B (3, 1)
= x2 x1 y2 y1 0 =0
x3 x1 y3 y1 0

°
15
( points are collinear i.e., area of triangle = 0)
45°
X
x2 x1 y2 y1 A (2, 0)
x3 x1 y3 y1 = 0
Hence, the equation is y = 3 x + c
So, the rank of matrix is always less than 2.
But it passes through (2, 0),
100. (d) On solving the determinant, we have
1 (1 – cos2 ) – cos ( – ) [cos ( – ) So, c = – 2 3
– cos . cos ] + cos [ cos . cos ( – ) Thus, required equation is y = 3x 2 3
–cos ] 103. (a) Solving the equation of line and curve, we
= 1 – cos2 – cos2 – cos2 ( ) get
+ 2 cos . cos .cos ( – ) 2
= 1 – cos2 – cos2 + cos ( – ) 2 2x
x2 2 =4
[2cos .cos – cos( – )] 6
= 1 – cos2 – cos2 + cos ( – )cos( + )
1
[cos ( + ) + cos ( – ) – cos ( – )] x2 – × 4 (1 + x2 – 2x) = 4
3
= 1 – cos2 – cos2 + cos2 . cos2
3x2 – 4 – 4x2 + 8x = 12
– sin2 . sin2 x2 – 8x + 16 = 0
= 1 – cos – cos (1 – cos2 )
2 2
(x – 4)2 = 0 x = 4
– sin2 .sin2
2 2
and 6 .y = 2 – 2 (4) = – 6
= 1 – cos – cos sin – sin2 .sin2
2

= (1 – cos2 ) – sin2 sin2 + cos2 ) y=– 6

= sin2 – sin2 1) = 0 Point of contact is (4, – 6 ).
101. (b) – 2 2 2 2 104. (b) x + y = 21
7 5 (7cos x 5sin x) 7 5
The number of integral solutions to the
74 (2K 1) 74 equations are x + y < 21, i.e., x < 21 – y

8.6 (2K 1) 8.6 B(0, 21)

– 9.6 2K 7.6
– 4.8 K 3.8
So, integral values of K are
–4, –3, –2, –1, 0, 1, 2, 3 (eight values)
1 C A
102. (a) Slope of AB = (0, 0)
1 (21, 0)
tan = m1 = 1 or = 45°
Number of integral coordinates 0 x 1/2 x
= 19 + 18 + ... + 1 = 4 2
dx 4 dx
1/2 1 x 0 1 x2
19(19 1) 19 20
= = 190
2 2 = 2{log(1 x 2 )}0 1/2 2{log(1 x 2 )}1/2
0

x 1 1 1
105. (c) (1 x x 1 )ex dx
= 2log 1 2log 1
4 4
x x 1 1 x 1
= [x.e 1 2
ex ]dx 3 4
x = 4log 4log
4 3
[ xf (x) f (x)dx xf (x) C] 108. (d) Let P (x1, y1) be a point on the ellipse.

x 1 x 1 x2 y2
(1 x x 1)e x dx xe x C =1
18 32
106. (a) f(x) = x – [x], – 1 x < 0
f (x) = x + 1 x12 y12
When 0 x < 1 = 1... (i)
18 32
f(x) = x
The equation of the tangent at (x1, y1) is
1 0 1
f (x)dx f (x)dx f (x) dx xx1 yy1
= 1. This meets the axes at
1 1 0 18 32

0 1 18 32
= (x 1)dx x dx A x ,0 and B 0, y . It is given that
1 1
1 0
4
0 1 slope of the tangent at (x1, y1) is –
x2 x2 3
= 2 x
2
1 0 x1 32 4
So, – . =–
18 y1 3
( 1) 2 1
=0 1 1
2 2 x1 3
y1 = 4
2 2 1/ 2
1/ 2 x 1 x 1
107. (c) 2 dx x1 y1
1/ 2 x 1 x 1 =K (say)
3 4
x1 = 3K and y1 = 4K
2 1/ 2
1/ 2 x 1 x 1 Putting x1, y1 in (i), we get
= dx
1/ 2 x 1 x 1 K2 = 1
1
1/ 2 4x Area of OAB = OA.OB
dx 2
= 1/ 2 x2 1
1 18 32 1 (18)(32) 24
= . . = = 2
0 4x 1/ 2 4x 2 x1 y1 2 (3K)(4K) K
= dx dx
1/ 2 1 x2 0 1 x2 = 24 sq units ( K2 = 1)
109. (d) Let mid–point of part PQ which is in 4b2 tan2 = a2sec2 b2tan2
between the axis is R (x 1 , y1 ), then 3b2 tan2 = a2 sec2
coordinates of P and Q will be (2x1, 0) and 3b2 sin2 = a2
(0, 2y1), respectively. 3a2 (e2 – 1) sin2 = a2
3 (e2 – 1) sin2 = 1
x y
Equation of line PQ is =1
2x1 2y1 1
2
= sin2 < 1,( sin 2 < 1)
3(e 1)
y1
y= x 2y1 1 4
x1 1
3 e2 1 e2
e 2
1 3 3
If this line touches the ellipse
2
x2 y2 e>
=1 3
a 2 b2
111. (a) There are 3 + 4 + 5 = 12 points in a plane.
then it will satisfy the condition,
The number of required triangles
c2 = a2m2 + b2
= (The number of triangles formed by these
2 12 points) – (The number of triangles formed
y1
So, (2y1 )2 = a2 b2 by the collinear points)
x1 = 12C3 – (3C3 + 4C3 + 5C3)
= 220 – (1 + 4 + 10) = 205
a 2 y12 112. (c) (a + bx) e–x
4y12 = b2
x12 = (a + bx)

x x2 x3 xn
a 2
b 2
a 2
b 2 1 ... ( 1)n ...
4= =4 1! 2! 3! n!
x12 y12 x12 y12
The coefficient of xr = a.
Required locus of (x1, y1) is
( 1)r ( 1)r 1 ( 1)r
a 2
b 2 b = (a br)
r! (r 1)! r!
2 =4
x y2
1999
110. (d) Let P (a sec , b tan ), Q (a sec , – b tan ) 113. (a) log n x
be end points of double ordinates and x 1
(0, 0) is the centre of the hyperbola. = log(1999)! 1+ log(1999)! 2 + ... + log(1999)! 1999
So, PQ = 2b tan = log(1999)! (1.2.3.... 1999)
= log(1999)! (1999)! = 1
114. (d) Since, the line is equally inclined to the axes
P
(0, 0) (a sec , b tan ) and passes through the origin, its direction
O ratios are 1, 1,1.
x y z
Q So, its equation is .
1 1 1
(a sec , – b tan )
A point P on it is given by (a, a, a). So,
equation of the plane through P (a, a, a)
OQ = OP = a 2 sec 2 b2 tan 2 and perpendicular to OP is
Since, OQ = OP = PQ 1 (x – a) + 1 (y – a) + 1 (z – a) = 0
( OP is normal to the plane)
i.e., x + y + z = 3a 1
lim [log f (1 x) log f (1)]
x y z 116. (c) ex 0 x
=1
3a 3a 3a
f (1 x) / f (1 x)
Intercepts on axes are 3a, 3a and 3a, lim
ex 0 1
therefore sum of reciprocals of these =
intercepts. f (1) / f (1)
=e e613 e2
1 1 1 1
=
3a 3a 3a a
117. (b) (1 sin x )
a/ sin x
, x 0
115. (b) The equation of curve is y = x – x2
6
x2 – x = y
f (x) b , x 0
2
1 1 e tan 2x/tan 3x ,0 x
x y
2 4 6

1 1 For f (x) to be continuous at x = 0

which is a parabola whose vertex is ,
2 4
lim f (x) = f (0) = lim f (x)
x 0 x 0

Y 1 1
, lim (1 + |sin x|)a / | sinx |
2 4 y = mx x 0

a
lim |sin x|
x 0 |sin x|
X =e = ea
O (1 – m)
tan 2x / tan 3x
Now, lim e
x 0
Hence, finding the point of intersection of
the curve and the line, tan 2x tan 3x
2x 3x
x – x2 = mx x (1 – x – m) = 0 2x 3x
= lim e
i.e., x = 0 or x = 1 – m x 0

9 1 m
(x x 2 mx)dx = lim e
2/ 3
e
2 /3
2 0
x 0

1 m Since, f(x) is continuous at x = 0.

x2 x3 x2
= 2 m
3 2 2
0 ea = e2/3 a=
3
(1 m)2 (1 m)3 (1 m)3 and b = e2/3
= (1 – m)
2 3 6 118. (b) x + 2 0, i.e., x –2 or –2 x
log10 (1 – x) 0
6 9
(1 – m)3 = = 27 1–x 1 x 0
2
Again, 1 – x > 0
1 – m = (27)1/3 = 3
1>x x<1
m=–2
Combining all the results for values of x, we
Also, (1 – m)3 – (3)3 = 0
get
(1 – m)3 = 33 1 – m = 3
or m = – 2 – 2 x < 0 and 0 < x < 1
tan 1
y dy dv
119. (b) (1 + y2) + (x e ) =0 v+x = v – sin2 v
dx dx
dx 1 dx
(1 + y2) x e tan y
– cosec2v dv =
dy x
1
Integrating both sides, we get
dx x e tan y
dx
dy 1 y2 (1 y 2 ) – cosec 2 vdv
x
1 cot v = log x + C
dy 1
1 y2
IF = e e tan y y
cot = log x + C
x
1
e tan y 1
.e tan y .dy
1
tan y
x. e = 2 Curve passes through the point 1,
1 y 4
1 C=1
tan 1 y e 2tan y
x(e ) c y
2 cot = log x + logee
x
1 1
2xe tan y
e 2 tan y
K y
cot log xe
dy y y x
120. (c) sin 2 y = x cot–1 (log xe)
dx x x

dy dv
Put y = vx v x
dx dx