Samchun Chemicals

Material Safety Data Sheet

Buffer solution pH 4.00
Section 1 – PRODUCT AND COMPANY IDENTIFICATION

1. Product Identifier Buffer solution pH 4.00

2. Recommended Use Uses for Laboratory and R&D only
& Uses advised against
3. Information of Supplier SAMCHUN PURE CHEMICAL CO.,LTD
ADDRESS; (Mogok-dong) 117, Sandan-ro 16Beon-gil, Pyeongtaek-si,
Gyeonggi-do, Korea
Emergency Phone; 82-31-668-0700/3
Department; Safety & Environment dep.
Web site; http://www.samchun.com

Section 2 – HAZARDS and DANGER IDENTIFICATION

1.GHS Classification· Identification Non-described
2. Label and Mark including Precautionary Statement

◦Label elements Non-described

◦Signal word Non-described

◦Hazard · Danger statement Non-described

◦Precautionary statement
Precaution Non-described
Measures Non-described
Storage Non-described
Dispose Non-described
3. Other Hazard-Risk which are not included in the classification criteria
NFPA index(0~4steps) : Health=N/A, Fire=N/A, Reaction=N/A

Section 3 – COMPOSITION AND INFORMATION ON INGREDIENTS

Chemical Name Other Name CAS No. Content (%)

Water Dihydrogen oxide 7732-18-5 > 98
Potassium hydrogen phthalate Potassium biphthalate 877-24-7 1~2
Sodium azide Hydrazoic acid 26628-22-8 0 ~ 0.03

Section 4 – FIRST AID MEASURES

1. Eye Contact Rinse with plenty of water for at least 15minutes and get medical
attention immediately.
2. Skin Contact Take off contaminated cloths and shoes immediately, wash with plenty
of water and soap for at least 15minutes.
3. Inhalation Move victim to fresh air. If breathing is difficult, give artificial
respiration and get medical attention immediately.
4. Ingestion Do not induce vomiting. Get medical advice/attention immediately.
5. Immediate medical attention and Keep the medical personnel aware of the materials involved and take
Notes for physician protective action.

Section 5 – FIRE-FIGHT MEASURES

1. Suitable extinguish media Water spray, alcohol resistant foam, powder extinguishing agent, carbon
dioxide
Inappropriate Extinguishing Media: N/A
2. Special hazards arising from N/A
the substance
3. Special protective equipment and Move containers from fire area if you can do it without risk. When
Precautions for fire-fighters extinguishing a fire, be sure to wear personal protective equipment.
If it is not possible to extinguish the fire, withdraw immediately. Keep
containers cool by spraying with water for a long time, even after the
fire is out. Isolate hazardous areas and deny access to people.

Section 6 – ACCIDENTIAL RELEASE MEASURES

1.Personal precautions and Do not touch spilled material. Avoid inhalation and skin contact. In case
Emergency procedures of confined space, wear air respirator and ventilate and remove all
sources of ignition.
2. Environmental precautions Minimize leak/spill, collect and keep leak/spill in container
3. Methods and material for Soak up with sand, clay and other inert absorbent material
containment and cleaning up

Section 7 – HANDING AND STORAGE

1. Precautions for safe Handling Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. All
containers should be grounded.
2. Conditions for safe storage Keep container tightly closed in a dry, cool and well-ventilated place.

Section 8 – EXPOSURE CONTROLS AND PERSONAL PROTECTION

1.Occupational exposure limit, biological exposure limit

National law of Safety management of
Industrial Safety and Health Act
<Sodium azide>
STEL : C0.29mg/m3
2. Appropriate Ensure compliance with applicable exposure limits and operate local exhaust
Engineering controls ventilation when working.
3. Personal protective equipment
◦Respiratory protection Respiratory protective equipment must be certified by the Korea Occupational
Safety and Health Agency
Since there may be undisclosed harmful risks, wear a gas mask or respiratory
protective equipment combined with a gas filter in consideration of
physicochemical characteristics
◦Eye-protection Install eyewash facilities and emergency eyewash devices near chemical handling
areas
Wear safety goggles when handling as there may be unrecognized harmful
hazards
Safety glasses must be certified by the Korea Occupational Safety and Health
Agency
◦Hand protection Wear safety gloves for chemicals when handling as there may be undisclosed
harmful risks.
Safety gloves for chemical substances must be certified by the Korea Occupational
Safety and Health Agency
◦Skin and body There may be undisclosed harmful hazards, so wear protective clothing for
proticion chemicals when handling
Protective clothing for chemicals must be certified by the Korea Occupational
Safety and Health Agency
Section 9 – PHYSICAL AND CHEMICAL PROPERTIES

1.Physical state and color Liquid(Colorless) 2.Odor Odorless

3.threshold N/A 4. pH 4.0
5.Melting/Freezing point 0℃ 6.Boiling point/range 100℃
7. Flashing point Non-described 8. Evaporation speed N/A
9. Flammability(solid,gas) Non-described 10. Flash or Explosion Non-described
limit upper / lower
11. Vapor pressure About 23.8mmHg 12. Solubility Soluble
(25℃)
13. Vapor density N/A 14.Gravity Approx 1.00
15. n-octanol-water N/A 16. Self ignition temp(℃) Non-described
Partition coefficient
17. Cracking temp(℃) N/A 18. Viscosity N/A
19. Molecular Weight N/A

Section 10 – STABILITY AND REACTIVITY

1.Chemical stability and Stable under normal temp. and pressure

Possibility of Hazardous
Reactions
2. Conditions to Avoid N/A
3. Incompatible Materials N/A
4. Hazardous N/A
Decomposition Products

Section 11 – TOXICOLOGICAL INFORMAION

1. Information on the likely routes of exposure.

N/A
2. Health hazard information
◦Acute toxic Oral : LD50 63980.66mg/kg Rat(Estimate)
Skin : Non-described
inhalation : Dust/Mist LC50 2600000mg/m3 Rat 4hr(Estimate)
◦Serious skin corrosive / irritation N/A
◦Serious eye damage / irritation N/A
◦Respiratory sensitization N/A
◦Skin sensitization N/A
◦ Carcinogenicity Industrial Safety and Health Act : N/A
Notice of Ministry of Employment and Labor : N/A
IARC : N/A
OSHA : N/A
ACGIH : Sodium azide(A4)
NTP : N/A
EU CLP : N/A
◦ Germ cell Mutagenicity N/A
◦ Reproductive toxic N/A
◦Specific target organ toxicity N/A
(single exposure )
◦Specific target organ toxicity N/A
(repeated exposure )
◦Aspiration hazard N/A

Section 12 – ECOLOGICAL INFORMATION

1.Acquatic and Fish toxicity : N/A
Terrestrial eco toxicity
Invertebrate toxicity : N/A
Sea algae : N/A
2.Persistence and Persistence : N/A
degradability
Degradability : N/A
3.Bioaccumulative potential Concentrations : N/A
Bioaccumulative : N/A
4.Mobility in soil N/A
5.Other adverse effects N/A

Section 13 – Disposable considerations

1.Waste methods Dispose in accordance with local regulations.

2.Waste warning Dispose prohibited substances and waste separately from others.

Section 14 – TRANSPORT INFORMATION

1. UN No. Non-described
2.Proper shipping Name Non-described
3.Hazard class Non-described
4.Packing group Non-described
5.Marine pollutnat Non-described
6.Particular safety
Measures for Non-described
transportation

Section 15 – REGULATARY INFORMATION

1.Occupation safety and health acts Standard material of exposure

2. Chemical Substances Control Act Non-described
3. National law of Safety management of Non-described
hazardous material
4.National law of management of Wastes Waste reagent for research and inspection(09-02-00)
5.Other domestic and European Union (EC) regulations: Non-described
foreign law

Section 16 – OTHER INFORMATION

1. Material source A chemical information MSDS Safety and Health Agency

National Institute of Environmental Research Chemical Information Systems
Korea Industrial Technology National Fire Hazardous Materials Information System
1. The 1st edition 2002.07.30
2. Revision and 12 / 2023.10.19
The final revision
. Other references
* The information provided on this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a guide
for safe handling, use, processing, storage, transportation, disposal and release and is not to be
considered as a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other material or in
any process, unless specified in the text.