SAFETY DATA SHEET

Date Printed: March 6, 2018

Version: 3
Revision date: March 7, 2018
Regulation: In accordance with Commission Regulation (EU) CLP 1272/2008

1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY

1.1 Product identifier
1.1.1 Product name: eco-DEHCH
1.1.2. EC No.: Confidential
1.1.3. (Pre)REACH Registration No.: -
1.1.4. CAS No.: Confidential

1.2 Relevant identified uses of the substance or mixture and uses advised against
1.2.1 Identified Uses: Not available
1.2.2. Recommended use: Chemical additive of PVC, plastic, rubber, ink, glue, paint, lubricant
1.2.3. Restrictions on use: Do not use for purposes other than those recommended.
1.3 Details of the supplier of the safety data sheet
1.3.1 Manufacturer
Company name: Hanwha Chemical Co, Ltd.
Address: Ulsan plant, Hanwha Chemical Co, Ltd., 22, Yongyeon-ro 230beon-gil, Nam-gu, Ulsan, Korea
Prepared by: Production of plasticizer team(3rd Ulsan plant)
Contact Telephone: +82-52-279-1023

1.3.2 Supplier&Distributor
Company name: Hanwha Chemical Co, Ltd.
Address: Hanwha Bldg., Janggyo-dong, Jung-gu, Seoul, Korea
Prepared by: Sales of plasticizer team
Contact Telephone: +82-2-729-2676
1.3.3. Fax: +82-2-729-5347

1.4 Emergency telephone number

1.4.1. Emergency Telephone: +82-2-729-1056

2. Hazard(s) identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 (CLP)

Physical / Chemical Hazards:

Classification according to Regulation (EC) 1272/2008 (CLP): Not classified
Health Hazards:
Classification according to Regulation (EC) 1272/2008 (CLP): Not classified
Environmental Hazards:
Classification according to Regulation (EC) 1272/2008 (CLP): Not classified

2.2 Label elements

Hazard pictograms: Not applicable
Signal word: Not applicable
Hazard statements: Not applicable
Additional precautionary statements: Not applicable
Precautionary statements:
- Precaution : Not applicable
- Treatment: Not applicable
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- Storage: Not applicable
- Disposal: Not applicable

2.3 Other hazards

- Additional precautionary statements: Not applicable
- National Fire Protection Association (NFPA)
Health: Not available
Flammability: Not available
Reactivity: Not available

3. Composition/information on ingredients
Classification according to (Pre)
Component CAS No. EC No. Conc. /%
1272/2008/EEC Registration No.
Bis(2-ethylhexyl)
01-2119987572-
cyclohexane-1,4- 84731-70-4 283-829-2 > 99 Not classified
24-0000
dicarboxylate

4. First-aid measures
4.1 Description of first aid measures
4.1.1. General information:
- Clean body thoroughly.
4.1.2. Following inhalation:
- Specific medical treatment is urgent.
- Move victim to fresh air.
- Give artificial respiration if victim is not breathing.
- Administer oxygen if breathing is difficult.
4.1.3. Following skin contact:
- In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
- Remove and isolate contaminated clothing and shoes.
- Get immediate medical advice/attention.
4.1.4. Following eye contact
- In case of contact with substance, immediately flush eyes with running water at least 20 minutes.
4.1.5. Following ingestion
- Do not let him/her eat anything, if unconscious.
- Get medical advice/attention.
4.1.6. Self-protection of the first aider:
- First aider: Pay attention to self-protection.

4.2 Most important symptoms and effects, both acute and delay Acute effects:
- None known

4.3 Indication of immediate medical attention and notes for physician

- Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
themselves.

5. Fire-fighting measures
5.1 Extinguishing media
- Suitable extinguisher: Use dry sand, dry fire extinguisher, water spray, normal foam, Carbon Dioxide,
when fighting fires involving this material.
- Unsuitable extinguisher: High Pressure Water Jet.
5.2 Special hazards arising from the substance or mixture
- May be ignited by heat, sparks or flames.
- Containers may explode when heated.
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- Some of these materials may burn, but none ignite readily.
- Fire will produce irritating and/or toxic gases.
- If inhaled, may be harmful.

5.3 Advice for firefighters

- Move containers from fire area if you can do it without risk.
- Some may be transported hot.
- Runoff from fire control may cause pollution.
- Contact with substance may cause severe burns to skin and eyes.
- Dike fire-control water for later disposal; do not scatter the material.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
- Eliminate all ignition sources.
- Stop leak if you can do it without risk.
- Ventilate the area.
- Do not touch or walk through spilled material.

6.2 Environmental precautions

- Prevent entry into waterways, sewers, basements or confined areas.

6.3 The methods of purification and removal

- Small Spill; Flush area with flooding quantities of water. And take up with sand or other non-combustible
absorbent material and place into containers for later disposal.
- Large Spill; Dike far ahead of liquid spill for later disposal.
- With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.

7. Handling and storage

7.1 Precautions for safe handling
- Wash your hands thoroughly after handling.
- Please work with reference to engineering controls and personal protective equipment.
- Be careful to high temperature.

7.2 Conditions for safe storage, including any incompatibilities

- Store in a closed container.
- Store in cool and dry place.

8. Exposure controls/personal protection

8.1 Control parameters
<Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate>
Occupational Exposure limits
ο EU regulation: Not available
ο U.S regulation: Not available
ο ACGIH: Not available
ο Biological exposure index: Not available
ο Other: Not available
ο DNELs, PNECs:

Exposure DNELs, DMELs, PNECs

route of
Industrial Professional Consumer
relevance

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Long Long Short Short Long Long Short Short Long Long Short Short
term, term, term, term, term, term, term, term, term, term, term, term,
Local systm local syste Local syste local syste Local syste local syste
effect iceffe effect mic effect micef effect mic effect micef effect mic
s cts s effect s fects s effect s fects s effect
Human: oral
(mg/kg - - - - - - - - - 5 - -
bw/day)
Human:
inhalation - 35.3 - - - - - - - 8.7 - -
(mg/m³)
Human:
dermal
- 10 - - - - - - - 5 - -
(mg/kg
bw/day)
Environment:
100 µg/L (Freshwater), 10 µg/L (Marine water)
water
Environment:
-
air
Environment:
85.07 mg/kg soil dw
soil
Environment:
426.62 mg/kg sediment dw (freshwater), 42.66 mg/kg sediment dw (marine water)
Sediment
Environment:
100 mg/L
STP
Environment:
222 mg/kg food
Predators

<Bis(2-ethylhexyl) terephthalate>
Occupational Exposure limits
ο EU regulation: Not available
ο U.S regulation: Not available
ο ACGIH: Not available
ο Biological exposure index: Not available
ο Other: Not available
ο DNELs, PNECs:
Exposure DNELs, DMELs, PNECs
route of
relevance Industrial Professional Consumer
Long Long Short Short Long Long Short Short Long Long Short Short
term, term, term, term, term, term, term, term, term, term, term, term,
Local systm local syste Local syste local syste Local syste local syste
effect iceffe effect mic effect micef effect mic effect micef effect mic
s cts s effect s fects s effect s fects s effect
Human: oral
(mg/kg - - - - - - - - - 3.95 - -
bw/day)
Human:
inhalation - 23.2 - - - - - - - 6.86 - -
(mg/m³)
Human:
dermal
- 6.58 - - - - - - - 3.95 - -
(mg/kg
bw/day)
Environment:
80 ng/L (Freshwater), 8 ng/L (Marine water)
water
Environment:
-
air
Environment:
15 µg/kg soil dw
soil

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Environment:
8.28 mg/kg sediment dw (freshwater), 828 µg/kg sediment dw (marine water)
sediment
Environment:
1 mg/L
STP
Environment:
52.7 mg/kg food
Predators

8.2 Exposure controls

Appropriate engineering controls
- Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Respiratory protection
- Follow the European Standard EN149. Use a European Standard EN 149 approved respirator if exposure limits
are exceeded or if irritation or other symptoms are experienced.
Eye protection
- Wear safety goggles as follow if eye irritation or other disorder occur.
; In case of gaseous state organic material: enclosed safety goggles
; In case of vapour state organic material: safety goggles or breathable safety goggles
; In case of particulate material: breathable safety goggles
- An eye wash unit and safety shower station should be available nearby work place.
Hand protection
- Wear appropriate protective gloves by considering physical and chemical properties of chemicals.
Body protection
- Wear appropriate protective clothing by considering physical and chemical properties of chemicals.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Description: Liquid
Color: colorless
Odor: odorless
Odor threshold: Not available
pH: 7
Melting point/freezing point: -40.7 ˚C
Initial boiling point and boiling range: 406.4 ˚C
Flash point: 217 ˚C (Cleveland opencup)
Evaporation rate: Not available
Flammability (solid, gas): Not applicable
Upper/lower flammability or explosive limits: Not available
Vapor pressure: < 1.5mmHg (50 ˚C)
Vapor density: Not available
Relative density 0.954 (20 ˚C)
Solubility(ies): Insoluble
Partition coefficient: n-octanol/water: logKow ≥ 6.2
Auto-ignition temperature: Not available
Decomposition temperature Not available
Viscosity: 44.2 cP (20 ˚C)
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Explosive properties: Not available
Oxidizing properties: Not available
Molecular weight: 396.6mol/g

10. Stability and reactivity

10.1 Reactivity/Chemical stability/Possibility of hazardous reactions:
- Fire may produce irritating and/or toxic gases.
- If inhaled, may be harmful.

10.2 Conditions to avoid:

- Keep away from heat/sparks or flames.

10.3 Incompatible materials:

- Combustion materials

10.4 Hazardous decomposition products: Irritating, Toxic gases

11. Toxicological information

11.1 Information on toxicological effects

(a) Acute toxicity Not classified
Not classified

Oral - Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate:

Rat(female), LD50>2,000 mg/kg bw (OECD TG 423,
GLP)
Not classified

Dermal - Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate:

Rat(female), LD50>2,000 mg/kg bw (OECD TG 402,
GLP)
Inhalation Not available
Not classified
- Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate: The
test substance induced no dermal irritation when applied
(b) Skin Corrosion/ Irritation to male New Zealand white rabbits and was therefore
considered a non-irritant. In addition, there was no
mortality and no treatment-related clinical signs were
observed. (erythema score=0, edema score=0) (OECD
TG 404, GLP)
Not classified
- Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate: The
(c) Serious Eye Damage/ Irritation test item was considered to be non-irritating to eyes in
three New Zealand white rabbits. (cornea score=0, iris
score=0, conjunctivae score=0, chemosis score=0)
(OECD TG 405, GLP)
(d) Respiratory sensitization Not available
Not classified
(e) Skin Sensitization - Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate: The
highest concentration of the test item (100 %) induced

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no skin irritation was used in the patch exposure for
second induction and challenge. (OECD TG 406, GLP)
Not classified
(f) Carcinogenicity - IARC, ACGIH, NTP, OSHA, EU CLP 1272/2008: Not
listed
Not classified
<Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate>
in vitro: Mammalian Chromosome Aberration Test(OECD
(g) Mutagenicity TG 473, GLP), Bacterial Reverse Mutation
Test(OECD TG 471, GLP): with/without
metabolic activation : Negative
in vivo: Mouse, Mammalian Erythrocyte Micronucleus
Test(OECD TG 474, GLP): Negative
Not classified
- Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate: Rats
(h) Reproductive toxicity dosed by oral gavage during organogenesis at dose levels
of 100, 300 and 1000 mg/kg bw/day did not result in any
toxicologically significant effects at any dose level.
(OECD TG 414, GLP)
(i) Specific target organ toxicity (single exposure) Not available

(j) Specific target organ toxicity (repeat exposure) Not available

(k) Aspiration Hazard Not available

12. Ecological information

12.1 Toxicity
Not classified
<Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate>
Fish: Oryzias latipes, LC50(96h) >100 mg/L semi-static
Acute toxicity (OECD TG 203, GLP)
Invertebrate: Daphnia magna, EC50(48h) >0.17 mg/L
(OECD TG 202, GLP)
Algae: Pseudokirchneriella subcapitata, EC50(72h) >0.27
mg/L static (OECD TG 201, GLP)

Chronic toxicity Not available

Persistence:
- High persistency (log Kow is more than 4 estimated.)
12.2 Persistence and degradability (LogKow ≥ 6.2)
Degradability:
- Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate:
0.487day
Bioaccumulation:
- Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate:
Bioaccumulation is expected
12.3 Bio-accumulative potential
to be low according to the BCF <500 (BCF = 9) (OECD
TG 305, GLP)
Biodegradation:
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- Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate: As not
well-biodegraded, it is expected to have high
accumulation potential in living organisms (54.1%
biodegradation was observed after 28 days) (OECD TG
301 C, GLP)
- Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate: High
potency of mobility to soil.
12.4 Mobility in soil
(logKoc ≥5.63 (Estimated), 40°C) (OECD TG 121,
GLP)
Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate
12.5 Results of PBT and vPvB assessment
is not PBT / vPvB.
12.6 Hazardous to the ozone layer Not classified
12.7 Other adverse effects Not available

13. Disposal considerations

13.1 Waste treatment methods
- Waste must be disposed of in accordance with federal, state and local environmental control regulation.

13.1.1 Product/Packaging disposal:

- Consider the required attentions in accordance with waste treatment management regulation.

13.1.2 Waste treatment-relevant information:

- Waste must be disposed of in accordance with directive 2008/98/EC.

13.1.3 Sewage disposal-relevant information:

- Release to the environment or sewage system is prohibited. Must be treated as hazardous waste.

13.1.4 Other disposal recommendations: Not available

14. Transport information

14.1 UN No.: Not applicable

14.2 UN Proper shipping name: Not applicable

14.3 Transport Hazard classes:

ADR: Not applicable
IMDG: Not applicable
ICAO/IATA: Not applicable
RID: Not applicable

14.4 Packing group: Not applicable

14.5 Environmental hazards: Not applicable

14.6 Special precautions for user :

in case of fire: Not applicable
in case of leakage: Not applicable

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15. Regulatory information
15.1 Safety, health and environmental regulation/legislation specific for mixture
< Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate >
EU Regulatory Information
EU classification
EU 1272/2008(CLP)
Classification: Not classified
Risk phrases: Not classified
Safety phrases: Not classified
EU SVHC list: Not regulated
EU Authorization list: Not regulated
EU Restriction list: Not regulated
Waste Framework Directive 2008/98/EC: Not regulated

Foreign Inventory Status

- Korea management information: Existing Chemical Substance : Present (2013-3-5632)
- Japan management information: Existing and New Chemical Substances (ENCS): Present ((3)-2435))
- China management information: Inventory of Existing Chemical Substances (IECSC): Not regulated
- Australia management information: Australian Inventory Inventory of Chemical Substances (AICS): Not
regulated
- Canada management information: Domestic Substances List (DSL): Not regulated
- New Zealand management information: New Zealand Inventory of Chemicals (NZIoC): Not regulated
- Philippines management information: Philippine Inventory of Chemicals and Chemical Substances (PICCS):
Not regulated

15.2 Chemical safety assessment: Not available

16. Other information

Product safety data sheet for prepared in accordance with Regulation (EU) 1272/2008
16.1 Indication of changes:
Preparation date: May 18, 2017
Version: 3
Revision date: March 7, 2018

16.2 Key literature reference and sources for data:

○ National chemicals information systems; http://ncis.nier.go.kr
○ TSCA; http://iaspub.epa.gov/sor_internet/registry/substreg/searchandretrieve/searchbylist/search.do
○ EU Regulation 1272/2008
○ TOMES;LOLI ; http://csi.micromedex.com/fraMain.asp?Mnu=0
○ UN Recommendations on the transport of dangerous goods 17th
○ IARC Monographs on the Evaluation of Carcinogenic Risks to Humans;http://monographs.iarc.fr
○ ECHA CHEM; http://echa.europa.eu/web/guest/information-on-chemicals/registered-substances
○ EPA; http://www.epa.gov/iris
○ EPISUITE Program ver.4.1
○ National Emergency Management Agency-Korea dangerous material inventory management system;
http://hazmat.mpss.kfi.or.kr/material.do
○ Waste Control Act enforcement regulation attached [1]
○ EPISUITE Program ver.4.1

16.3 Classification and procedure used to derive the classification for mixtures according to Regulation
(EC) 1272/2008(CLP):

Classification according to Regulation (EC) 1272/2008 (CLP) Classification procedure

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- -

16.4 Abbreviations
ACGIH: American Conference of Governmental Industrial hygienists
NIOSH: The National Institute for Occupational Safety and Health
OSHA: Occupational Safety & Health Administration
IARC: International Agency for Research on Cancer
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
IMDG: International Maritime Dangerous Goods
ICAO/IATA: International Civil Aviation Organization/ International Air Transport Association
RID: Regulations Concerning the International Transport of Dangerous Goods by Rail

16.5 Other
- Product should be handled, stored, and used in accordance with the generally accepted industrial hygiene
practices and in conformity with all the applicable legal regulations.
- The information provided herein is based on the knowledge possessed at this present time from the view point
of safety requirements.
- It should, therefore, not be construed as guaranteeing specific properties.

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