Subject Code : 043

CHEMISTRY
Max. Marks : 70
Time: 3hou
General Instructions :
Read the follow ing instructions carefully.
(a) There are 33 questions in this question paper with internal choice.
(b) SECTION A consists of 16 multiple-choice questions carrying 1 mark
each.
(c) SECTION B consists of 5 short answer questions carrying 2 marks each.
(d) SECTION C consists of 7 short answer questions carrying 3 marks each.
(e) SECTION D consists of2 case-based questions carrying4 marks each.
(f) SECTION E consists of 3 long answer questions carrying
5 marks each.
(g) All questions are compulsory.
(h) Use of log tables and calculators is not allowed.

SECTION A
The follow ing questi ons are multiple-choice questions with one
correct answer. Each question carries 1 ma
There is no intern al choice in this section.
1. Ammonolysis of ethyl chloride followed by reaction of the amine
so formed with 1 mole of methyl chlorid
gives an amine that
a. reacts with Hinsberg reagent to form a product soluble in an
alkali
b. on reaction with nitrous acid, produced nitrogen gas
c. reacts with benzenesulphonyl chloride to form a product that
is insoluble in alkali
d. does not react with Hinsberg reagent.
2. Which one of the following has the highest dipole moment?
a. CH 3F
b. CH 3Cl
c. CH3I
d. CH3 Br
3. Match the properties given in column I with the metals in colum
n II.
Column I
Column II
{i) Actinoid having configuration [Rn] s/76d17 2
5 (A) Ce
(ii) L h
ant anoi d which has 4/14 electronic configuration in +3 oxid t'
'") L h t t (B)
(1u ant anoi'd which show +4 oxidation state a 10n s a e LU

a. {i)-(C), (ii)-(B), (iii)-{A) (C) cm

b. (i)-(C), (ii)-(A), (iii)-(B)
c. (i)-(A), (ii)-(B), (iii)-{C)
d. (i)-(B), (ii)-(A), (iii)-(C)
4. Study the graph showing the boiling points ofbromoalkane s and identify the compounds.
Boiling points of bromoalkanes
400 364 - "'375"
350

-
~
...
..s
0
300
250 -
~ 200 -
.s
~ 150 -
0
IXl
100 -
50 -
0 - 4
1 2 3
Bromoalkanes

a. 1 = Bromomethane, 2 = 2-Bromobutane, 3 = 1-Bromobutane, 4 = 2-Bromo-2-methylpropane

b. 1 = 1-Bromobutane, 2 = 2-Bromo-2-methylpropane, 3 = 2-Bromobutane, 4 = Bromomethane
c. 1 = Bromomethane, 2 = 1-Bromobutane, 3 = 2-Bromo-2-methylpropane, 4 = 2-Bromobutane
d. 1 = Bromomethane, 2 = 2-Bromo-2-methylpropane, 3 =2-Bromobutane, 4 = 1-Bromobutane
2
5. The initial concentration of R in the reaction R ➔ Pis 4.62 x 10- mol/L. What is the half life for the reaction
if k = 2.31 x 10-2 mol L- 1s- 1?
a. 30 s b. 3 s
c. 1s d. 10 s

6 When C6H 5COOCOCH3 is treated with H 20, the product obtained is

a. benzoic acid and ethanol
b. benzoic acid and ethanoic acid
c. acetic acid and phenol
d. benzoic anhydride and methanol.
7. Formulation of Cobalt(III) Choride-Ammonia Complexes
Colour Formula Solution conductivity corresponds to

Yellow [Co(NH3)6 ] 3+3cr y

Purple [C0Cl(NH3)s] 2+2cr 1 : 2 electrolyte

Green X 1 : 1 electrolyte

'X and 'Y' in the above table are

a. X = [Co(NH3)6 ]2+3cr, Y = 1: 3 b. X = [Co(NH3)4 Cl 2]+cr, Y = 1 : 3
3
X = [Co(NH3)4 Cl2] +3cr, Y = 1 : 1
c. X = [Co(NH3)4Cl2tCl-, Y = 1: 1 d.
8. Which of the following contains only ~-D-glucose as its monosaccharide unit ?
a. Sucrose b. Cellulose
c. Starch d. Maltose
9. Which one of the following sets correctly represents the increase in the paramagnetic property of the ions?
a. Ti3+ < Fe2+ < Cr3+ < Mn2+ b. Ti3+ < Mn2+ < Fe2+ < Cr3+
c. Mn2+ < Fe2+ < Cr3+ < Ti3+ d. Ti 3+ < Cr3+ < Fe2+ < Mn 2+
14 1
10. A first-order reaction is found to have a rate constant, k = 5.5 x 10- s- . The time taken for completion of
the reaction is
a. 1.26 x 1013 s b. 2.52 x 10 13 s
c. 0.63 x 1013 s d. it never goes to completion.

23
A student was preparing aniline in the lab. She took a compo und «x>
and reduced it in the presence of Ni
ll.
as a catalyst. What could be the compo und "JC,'• .
Nitrobenzene b. l-N1trohexane
a. tril d
c. Benzoni • e • 1-Hexanenitrile
12. Which of the following compo und gives an oxime with hydroxylamine ?
a. CH3COCH3 b. CH3CO OH
c. (CH3CO)i0 d. CH3COCl
3
13 . Assertion (A) : [Mn(CN) 6] - has a magnetic momen t of two unpaire d electrons while [MnC1 ] 3- has a
6
paramagnetic momen t of four unpaired electrons.
Reason (R) : [Mn(CN) ]3- is inner orbital complex involving d2sp 3 hybridi
6 sation, on the other hand,
[MnC~] 3- is outer orbital complex involving sp 3d2 hybridisation.
Select the most appropriate answer from the options given below:
a. Both A and R are true and R is the correct explanation of A.
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
14. Assertion (A) : For strong electrolytes, there is a slow increase in molar
conductivity with dilution and can
be represented by the equation
0
A m =A m -Acl/2
Reason (R): The value of the constant 'A' for NaCl, CaC1 , and MgS0 in
2 4 a given solvent and at a given
temperature is different.
Select the most appropriate answer from the options given below:
a. Both A and R are true and R is the correct explanation of A.
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
15. Assertion (A) : Glucose does not form the hydrogensulphite addition produc
t with NaHS03.
Reason (R) : Glucose exists in a six-membered cyclic structure called pyrano
se structu re.
Select the most appropriate answer from the options given below:
a. Both A and R are true and R is the correct explanation of A.
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
16. Assertion (A) : The half-life for a zero order reaction is indepe ndent
of the initial concentration of the
reactant.
Reason (R) : For a zero order reaction, Rate = k.
Select the most appropriate answer from the options given below:
a. Both A and R are true and R is the correct explanation of A.
b. Both A and Rare true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.

SECT IONB
This section contains 5 questi
ons w ith interna
• . in
l choice . one questio
. n. The followi•ng questio
• ns are very short
answer type and carry 2 marks each.
17
• a. Nitrogen gas is soluble in water. At temperature 293 K the value of Ktt
is 76.48 kbar. How would the
solubility of nit rogen vary ( increas
• e, d ecrease or remam
: the same) at a temperature ab
ove 293 K , if
th e value of KH rises
to 88.8 kbar?
24
Class 12
b. Chloroform (b.p. 61.2 °C) and acetone (b.p. 56 °C) are mixed to form an azeotrope. The mole fraction
of acetone in this mixture is 0.339. Predict whether the boiling point of the azeotrope formed will be
(i) 60 °C (ii) 64.5 °C or (ill) 54 °C. Defend your answer with reason.
OR

a. A soda bottle will go flat (loose its fizz) faster in Srinagar than in Delhi. Is this statement correct? Why
or why not?
b. How does sugar help in increasing the shelf life of the product?

18. a. Write the IUPAC name of the following complex: K[Cr(H2O)i(C2O 4 )i]H2O
b. Name the metal present in the complex compound of (i) Haemoglobin (ii) Vitamin B-12.

19. Observe the following cell and answer the questions that follow:
G
~--)I-----.

X y

~ XCI YC12

a. Represent the cell shown in the figure.

b. Name the carriers of the current in the salt bridge.
c. Write the reaction taking place at the anode.
20. Complete the following reactions by writing the major and minor product in each case (any 2)
a. CH3CH2Br + KCN ➔
b. CH3CH2CH = CH2 + HBr ➔
c. (CH3)iCHCHClCH3 +ale.KOH ➔
21. The presence of Carbonyl group in glucose is confirmed by its reaction with hydroxylarnine. Identify the
type of carbonyl group present and its position. Give a chemical reaction in support of your answer.

SECTIONC
This section contains 7 questions with internal choice in one question. The fallowing questions are short answer
type and carry 3 marks each.
22. a. Write down the reaction occurring on two inert electrodes when electrolysis of copper chloride is done.
What will happen if a concentrated solution of copper sulphate is replaced with copper chloride?
b. Write an expression for the molar conductivity of aluminium sulphate at infinite dilution according to
Kohlrausch law.
23. Account for the following:
a. The lowest oxide of transition metal is basic, and the highest is acidic.
b. Chromium is a hard metal while mercury is a liquid metal.
c. The ionisation energy of elements of the 3d series does not vary much with increasing atomic number.
24. a. Give the chemical reaction involved when p- nitrotoluene undergoes Etard reaction.
b. Why does benzoic acid exist as a dimer in an aprotic solvent?
c. Benzene on reaction with methyl chloride in the presence of anhydrous AlC13 forms toluene. What is
the expected outcome if benzene is replaced by benzoic acid? Give a reason for your answer.
Chemistry 25
OR
An organic compound 'X', does n~t undergo aldol conden_sation
l
. However 'X with compound 'Y' in tht
presence of a strong base react to give the compound 1,3-dipheny
lprop-2-en-l-one.
a. Identify 'X' and 'Y:
b. Write the chemical reaction involved.
c. Give one chemical test to distinguish between X and Y.
25 . a. Give the structure of all the possible dipeptides formed when the following two amino acids
form a
peptide bond.
Alanine
0
H3C +OH
NH 2
Glycine
0
H2N ~OH
b. Keratin, insulin, and myosin are a few examples of proteins presen
t in the human body. Identify which
type of protein is keratin and insulin and differentiate between them
based on their physical properties.
26. Neeta was experimenting in the lab to study the chemical reactiv
ity of alcohols. She carried out a dehydration
reaction of propanol at 140°C to 180°C. Different products were
obtained at these two temperatures.
a. Identify the major product formed at l 40°C and the substi
tution mechanism followed in this case.
b. Identify the major product formed at 180°C and the substi
tution mechanism followed in this case.
27. Various isomeric haloalkanes with the general formula C
4H9Cl undergo hydrolysis reaction. Among them,
compound "A" is the most reactive through SNl mechanism. Identi
fy "A" citing the reason for your choice.
Write the mechanism for the reaction.
28. The equilibrium constant of cell reaction :
sntq) +Ales) ➔ Al3+ + Sni~) is 4.617 x 10 184, at 25
°C
a. Calculate the standard emf of the cell.
(Given: log 4.617 x 10184 = 184.6644)
b. What will be the E° of the half cell Al3+/ Al , if E° of half cell 4
Sn +/Sn2+ is 0.15 V?

SECTIOND
The following questions are case-based questions. Each question
has an internal choice and carries 4 (2+ 1+1)
marks each. Read the passage carefully and answer the questions
that follow.
29. Dependence of the rate of reaction on the concentration of
reactants, temperature, and other factors is the
most general method for weeding out unsuitable reaction mecha
nisms. The term mechanism means all the
individual collisional or elementary processes involving molecules
(atoms, radicals, and ions included) that
take place simultaneously or consecutively to produce the observ
ed overall reaction. For example, when
hydrogen gas reacts with bromine, the rate of the reaction was found
to be proportional to the concentration
ofH2 and to the square root of the concentration ofBr .
2
Furthermore, the rate was inhibited by increasing the concentratio
n of HBr as the reaction proceeded. These
observations arc not consistent with a mechanism involving bimol
ecular collisions of a single molecule of
each kind.
The currently accepted mechanism is considerably more complicated
, involving the dissociation of bromine
molecules into atoms followed by reactions between atoms and
molecules.
It is clear from this example that the mechanism cannot be predic
ted from the overall stoichiometry.
(source: Moore, J. W., & Pearson, R. G. ( 1981 ). Kinetics and mecha
nism. John Wiley & Sons.)
Class 12
a. Predict the expression for the rate of reaction and order for the following:
H 2 + Br2 ➔ 2HBr
What are the units of rate constant for the above reaction?
b. How will the rate of reaction be affected if the concentration of Br2 is tripled?
OR
What change in the concentration of H 2 will triple the rate of reaction?
c. Suppose a reaction between A and B, was experimentally found to be first order with respect to both
A and B. So the rate equation is:
Rate= k[A] [B]
Which of these two mechanisms is consistent with this experimental finding?
Why?
Mechanism 1
A ➔ C + D (slow)
B+ C ➔ E(fast)
Mechanism 2
A + B ➔ C + D (slow)
C ➔ E (fast)

30. Amines are basic in nature. The pKb value is a measure of the basic strength of an amine. Lower the value of
pKb, more basic is the amine. The effect of substituent on the basic strength of amines in aqueous solution
was determined using titrations. The substituent "X,, replaced "-CH/ group in piperidine (compound 1)
and propylamine CH3CH2CH 2NH 2, (compound 2).
Compound 1: H Compound 2: HXCH2CH2NH 2

() X
The experimental data is tabulated below:
Substituent "X" Electro- Substituted piperidine pKa Substituted propylamine pKa
negativity of X compound compound

CH2 2.55 H 11.13 CH3CH2CH2NH2 10.67

0 9.81 NH2CH2CH2NH2 10.08

NH 3.12 H
(N)
N
H
0 3.44 H 8.36 HOCH 2CH2NH2 9.45
.
()0
CH 3CON 3.6 H 7.94 CH3CONHCH2CH2NH2 9.28

()N
I
COCH3
- - r- -
C6H5CON 3.7 H 7.78 C6H5CONHCH2CH2NH 2 -
()N
I
COC6Hs
-
27
(source.. Hall Jr, .H• K• (1956
. ) Field and inductive effects on the base strengths of amine
• s. Journ
American Chcnucal Society, 78(11 ), 2570-2572.) a1oJ
Study the above data and answer the following questions:
a. Plot a graph between the electronegativity of the substituent vs pKb value of the corres ~
substituted propyl amine (given that pKn + pKi, = 14). Is there .
any relation between the electronePOQd·.
of the substituent and its basic strength?
b. The electronegativity of the substituent "C6HsCON" is gati
3. 7, what is the expected pKa value of compou
C6H5CONHCH2CH2NH2?
(i) 9.9 (ii) 9.5 '
(iii) 9.3 (iv) 9.1
c. The pKa value of the substituted piperidine formed with
substituent "X, is found to be 8.2S. Wh
the expected electronegativity of "X' ?
at
(i) 3.5 (ii) 3.4 (iii) 3.8 (iv) 3.1
OR
What is the most suitable pKe1 value of the substituted propy
lamine formed with substituent "X" .1
electronegativity 3.0 ?
w~
(i) 10.67 (ii) 10.08 (iii) 10.15 (iv) 11.10

SECTIONE
11ie following questions are long answer types and carry 5
marks each. All questions have an internal choic
31. a. A purple colour compound A, which is a strong oxidising
agent and used for bleaching of wo
cotton, silk and other textile fibres was added to each of the
three test tubes along with H So . It)
followed by strong heating. 2 4
A B C
1

Oxalic acid PbS KI

In which of the above test tubes; A, B or C:
(i) Violet vapours will be formed.
(ii) The bubbles of gas evolved will extinguish a burni
ng matchstick.
Write an equation for each of the above observations.
b. A metal ion M"+ of the first transition series having d5 config
uration combines with three didentat
ligands. Assuming ~o < P:
(i) Draw the crystal field energy level diagram for the
3d orbit{ll of this complex.
(ii) What is the hybridisation of M"+ in this complex
and why?
(iii) Name the type of isomerism exhibited by this comp
lex.
OR
a. Using, Valence Bond Theory identify A, B, C, D, E and F in
the following table :
--- _ _:_ r---
S.No. Complex Central Configuration Hybridisation Geometry Number ----Magne .--- -i
tic
of
metal of metal ion of metal ion of the unpaired Behaviour
ion complex electron
2
i. [CoF 4] - A 3d7 - + - - - sp3 tetrahedral B Paramagnetic
ii. I[Cr(H2Oh (CiO ) ] Cr3+ 3d3
4 2 C octahedral 3 D
iii. l[Ni( C0) 4] Ni 3d84s2 Diamagne!!:-
E F 0
b. Write the ionic equations for the reaction of acidified K Cr207
2 with
(i) H2S and (ii) FeSO4
Class 1
32. a. Give reasons for the following:
(i) The reaction of ethanol with acetyl chloride is carried out in the presence of pyridine.
(ii) Cresols are less acidic than phenol.
b. Williamson's process is used for the preparation of ethers from alkyl halide. Identify the alkyl bromide
and sodium alkoxide used for the preparation of 2-Ethoxy-3-methylpentane.
c. Convert:
(i) Toluene to 3-nitrobenzoic acid.
(ii) Benzene to m-nitroacetophenone.
OR
a. Out of formic acid and acetic acid, which one will give the HVZ reaction?
Give a suitable reason in support of your answer and write the chemical reaction involved.
b. Alcohols are acidic but they are weaker acids than water. Arrange various isomers of butanol in the
increasing order of their acidic nature. Give a reason for the same.
c. An organic compound A, which is a Grignard reagent is used to obtain 2-methylb utan-2-ol on
reaction with a carbonyl compound 'B: Identify 'A' and 'B: Write the equation for the reaction between
A andB.
33. a. An experiment was carried out in the laboratory, to study depression in freezing point. 1 M aqueous
solution of Al(N03h and 1 M aqueous solution of glucose were taken. From the given figure identify
solution 1 and solution 2. Give a plausible reason for your answer.
A

---------
I
I
I
I
I
1-, I
::s I
I
0 I
0... I
I

~ I
I
I

T2 T1 :T

Temperature JI>

b. The osmotic pressure of a solution of cane sugar was found to be 2.46 atm at 300 K. If the solution was
diluted five times, calculate the osmotic pressure at the same temperature.
How can the osmotic pressure of the given cane sugar solution be decreased without changing its
volume? Give a reason for your answer.
OR
a. While giving intravenous injections to the patients, the doctors take utmost care of the concentration
of the solution used. Why is it necessary to check the concentration of the solution?
2
b. A solution of phenol was obtained by dissolving 2 x 10- kg of phenol in 1 kg of benzene. Experimentally
it was found to be 73 % associated. Calculate the depression in the freezing point recorded.

Chemistry
SOLUTIONS
I. (c) : 2° amine will be formed that will react with On increasing temperature nitrogen gas becomes less soluble
benzenesulphonyl chloride to form a product that is because its KH value increases. (1/2 mark)
insoluble in alkali. ( 1 mark) (b) (ii) 64.5°C (1/2 mark)
2. (b): The order followed is this CH3 I < CH 3Br < CH 3F Chloroform and acetone mixture shows negative deviation
< CH3Cl, though F is most electronegative but the bond from Raoult's law therefore, they form maximum boiling
length is small as compared to C-Cl. azeotropc at a specific composition. The boiling point of
Dipole moment is the product of the charge and the bond the mixture so obtained will be higher than the individual
length. ( 1 mark) components. ( 1/2 mark)
3. (a): (i)-(C), (ii)-(B), (iii)-(A) (1 mark) OR
4. (d): 1 = Bromomethane, 2 = 2-Bromo-2-methylpropane, (a) At higher altitudes i.e., in Srinagar the atmospheric
3 = 2-Bromobutane, 4 = 1-Bromobutane pressure is lower than Delhi. The solubility of a gas in a
Boiling point increases with increase in molecular mass liquid decreases with decrease in atmospheric pressure
I

while decreases with increase in branching. (1 mark) therefore, the carbon dioxide dissolved in water will be
lesser at Srinagar making the soda go flat faster. ( 1 mark)
5. (c) : The order of reaction is zero as the unit of k is (b) Preservation of fruits by adding sugar/salt protects
mol L- 1s- 1. Thus half life, t0 12)
2 against bacterial action. Through osmosis, a bacterium on
= [R] 0 I 2k = 4.62 x 10- /2 x 2.31 x 10-2 = 1 (1 mark) canned fruit loses water, shrivels and dies. ( 1 mark)
6. (b) : C6H 5COOCOCH3 C6H 5COOH+ 18. (a) Potassium diaquadioxalatochromate(III) hydrate
CH 3COOH (1 mark)
(1 mark) (b) (i) Haemoglobin: Iron (ii) Vitamin B-12: Cobalt
(1 mark) (1 mark)
2
8. (b) : Starch contains only a-D-glucose, sucrose 19. (a) Y(s)IY (aq) II Xcaq)I X(s) (1 mark)
contains a-D-glucose and ~-D-fructose, maltose contains (b) Ions are carries of current in salt bridge. (1/2 mark)
(c) Y(s) ➔ Y (aq) + 2e-
2
a-D-glucose and cellulose is a polymer of ~-D-glucose. {1/2 mark)
(1 mark) 20. (a) CH3CH2CN (major), CH3CH 2NC (minor)
9. 3 3 2
(d): Ti + < Cr + < Fe + < Mn + 2 (1/2 + 1/2 mark)
No. of unpaired electrons: Ti 3+ (1), Cr3+ (3), Fe2+ (4) and (b) CH3CH 2CHBrCH 3 (major), CH 3CH 2CH 2 CH 2 Br
Mn2+ (5) (minor)
Paramagnetism increases with increase in number of (1/2 + 1/2 mark)
(c) (CH 3)iC=CHCH3 (major), (CH 3)iCHCH=CH2
unpaired electrons. (1 mark)
(minor)
10. (d): It never goes to completion. (1/2 + 1/2 mark)
First order reaction [R] = [R] 0 e-kt If [R] = 0 then e-kt = 0,
21. The carbonyl group present in glucose is aldehyde and
which is not possible for any finite value oft. Here, tis 00•
at the C 1 atom. ( 1 mark)
(1 mark)
Glucose gets oxidised to six-carbon carbOA)'lic acid (gluconic

11. (a) :
0rN02
V
HifNi
Ethanol V
0rNH2
(1 mark)
acid) with COOH group at the Cl atom on reaction with a
mild oxidising agent like bromine water. This indicates that
12. (a) : Aldehydes and ketones give nucleophilic addition the carbonyl group is present as an aldehydic group.
reactions with hydroxylamines. ( 1 mark) (1 mark)
13. (a) (1 mark) 22. (a) Product of electrolysis of copper chloride:
14. (d): Ac:n Am - A c112 is an incorrect equation, the
=
At cathode:
correct equation is Am= A~ - A c112. (1 mark) Cu2+ + 2e- ➔ Cu(s)
At anode:
15. (b): Due to the absence of a free aldehyde group, it 2cr ➔ Cl2 + 2e- (1 mark)
does not give a reaction with NaHSO 3. ( 1 mark) Product of electrolysis of concentrated copper sulphate :
16. (d): The half- life for a zero order reaction t 112 = [R]o/2k At anode:
. where [R] 0 is the initial concentration of the reactant. 2S0~- ➔ S20)- + 2e-
(1 mark) At cathode:
17. (a) Solubility of gas is inversely proportional to the Cu2+ + 2e- ➔ Cues> (1 mark)
3
value of Henry's constant Ktt, (1/2 mark) (b) A:,[AI2(SO4h] = 2A:, (Al +) + 3A:,(so~-) (1 mark)

Chemistry
23. (a) In case of a lower oxide of a transition metal, the
metal atom has some electrons present in the valence shell
H2N-C H-C OOH + H2N -CH -COQI-{ 'Ii
I
2
(Glycine)
of the metal atom that are not involved in bonding. As a CH3
result, it can donate electrons and behave as a base whereas (Alanine)
in higher oxide of a transition metal, the metal at?m does
not have an electron in the valence shell for don~tton. As a I
result it can accept electrons and behave as an acid. H2N -CH CH2 C
, (1 mark)
I
CH3
- oo,
I

(b) Chromium has unpaired electron~ ~hi~ result in

strong metallic bonding which results m i~ bemg a h~d
solid and the absence of unpaired electrons m Hg results m (b) (i) Keratin is a fibrous protein, fibre-like st (1
it being a liquid. (1 _mark)
formed. Such proteins are generally insoluble in Wat~ I
(c) The increase in effective nuclear charge responsible for
(1/2~
(ii) Insulin is a globular protein. This structure results
steady increase in ionisation energy is counterbalanced by ~
shielding effect of (n-l)d-electrons. the chains of polypeptides coil around to give aspherJ
(1 mark)
shape. These are usually soluble in water. (1/2hlad
0
26. (a) Propanol undergoes a dehydration reactio 1
~-H
140°C, dipropyl ethe.r is formed. The formation of eth;.1
nucleophilic SN2 substitution bimolecular reaction. i
(b) When the temperature exceeds 170°C, (1 + 1123·
propene is
N02 major product following elimination reaction.
(1 mark) . • (1 + 112JDad
(b) Benzoic acid undergoes extensive intermolecu
lar H2S04 ~
hydrogen bonding ; leading to the formation of dimer. 443 K CH2=CH-CH
3
(1 mark)
(c) Benzoic acid does not undergo reaction with CH Cl HSO
3
i.e Friedel Craft reaction because the carboxyl group 413 K
is
deactivating and the catalyst aluminium chloride (Lewis acid)
gets bonded to the carboxyl group. 27. "A" is (CH 3hCCI, the carbocation intermedia
(1 mark) obtained in tertiary alkyl halide is most stable, making
OR most reactive of all possible isomers.
(a) Comp ound 'X' = Benzaldehyde , Co~p ?un~ (1/2 + 1/2 m
'Y' = Acetopherione step 1 ,
CH
(1/2 + 1/2 mark) A3 +er
(b) H3C CH3
CHO ?i .
© X
+© (<\ :Hl dU;O H ~ C H ~
Y (Major)
0
H3C
ACH3
CH3
_ step II
+ OH ----'- -(CH 3hCO H

28. Bcell = Eocell - 2.303RTl K

nF og c
Cross Aldol product •' At298K
(1 mark)
'(c) Chemical test to distinguish between X and Y is the B _ Bo _ 0.0591 K (1/2 madl
cell - cell n 1og c
Tollens' test
Benzaldehyde undergoes silver mirror test with Tollens' At equilibrium Bcell =0, n = 6 (1/2m ~
reagent and forms silver mirror. However, acetophenone does Bocell ___
_ 0.0591 log KC
not react with Tollens' reagent. (1 mark) n
=0.059/6 log 4.617 x 101s4 (l/2madl
25. (a) • I
= 0.00983 X 184.6644
H 2N-C H2-CO OH + H2N-C H-C OOH -H20 (1/2 matil
> = 1.8152
(Glycine) (ii) ~ell= .Esn4+/sn2+ -_E°A13+1Al (I/2 martl
6H3
(Alanine) 1.81 = 0.15 - E°AI3+/Al
E°AlJ+/Al = -1.66 V (1/2 mad!
~ . (1/2 mad!
29. (a) Rate= k [H2] [Br2] 112
H2N -CH 2~C H-C OO H Order= 3/2 (1/2 madll
I mol 1-1s-1 1-i,21112s-1 (1 mati)
CH3 Umts• of k = ...;;.;;. ;~~-=- - mo
(1 mark) . mo1312 L-3/2 - I
c1assd
) • Rate= k [H 2] [Br2] 112 OR
concentration of Br2 is tripled (a) A= Co2+ (1/2 mark)
ate'= k [H2] [3Br2]112 B= 3 (1/2 mark)
Rate'= ✓3 k [H 2] [Br2]
112 C = d2sp 3 (1/2 mark)
D = Paramagnetic (1/2 mark)
Rate' = ✓3 Rate (1 mark)
E = sp3 (1/2 mark)
OR F = tetrahedral (1/2 mark)
112 (b) (i) Cr20~- +SH++ 3H2S ➔ 2Cr3++ 3S + 7H2O
Rate= k [H2] [Br2]
As given rate is tripled by changing concentration of H2 (1 mark)
ltate' = 3 Rate= k [xH2] [Br2]
112 (ii) Cr2O~- + 14H+ + 6Fe2+➔ 2Cr3+ + 6Fe3+ + 7H2O
112 (1 mark) (1 mark)
3 Rate= k [xH2] [Br2l
~ = ~, the concentration of H2 should be tripled. 32. (a) (i) The reaction of ethanol with acetyl chloride is
(c) . ~he slowest step is the rate-determining step. From carried out in the presence of pyridine. Pyridine is a strong
rnechanism 2, organic base. The function of pyridine is to remove HCl
Rate = k [A] [B] while from mechanism 1 Rate = k [A] formed in the reaction. (1 mark)
Therefore, mechanism 2, is consistent with the experimental (ii) The electron releasing groups, such as alkyl groups,
( 1 mark) in general, do not favour the formation of phenoxide ion
finding.
resulting in decrease in acid strength. Thus, cresols are less
30 (a) 5 (l½ marks) acidic than phenol. (1 mark)
4.5
-~
./'
.. ,,,..•'
(b) C2H5Br and CH3CH 2CH(CH 3)CH2CH 2ONa yields
~ 4
0.3_5 ,,, #. 2-ethoxy-3-methylpentane
CH3 COOH COOH
(1 mark)
3

00 2.5 3 3.5 4 (c) (i 6-..;::::: KMn04/0H 6~ HN03 > Q':::::

Electronegativity ) h- h' H2S04 h'
NO 2
Toluene Benzoic acid 3-nitro
....... Is the line of best fit benzoic acid
The pKb increases with an increase in the electronegativity (1 mark)
of the substituent, therefore the basic strength decreases with (ii)
an increase in the electronegativity of the substituent.

(b) (iv): 9.1

(c) (i): 3.5
(1/2 mark)
(1 mark)
{l mark)
0
Benzene
HNO,tH,so, 6 2

nitrobenzene
0
II
CH3 -C-Cl
A1Cl3
N02

~CHi
0
OR m-nitroacetophenone
(iii): 10.15 {l mark) (1 mark)
31. (a) (i) Test tube C OR
lOr + 2MnO4+ 16H+ ➔ 512 + 2Mn2+ + 8H2O (a) Acetic acid will give HVZ reaction. (1/2 mark)
(1 mark) Carboxylic acids having atleast one a-hydrogen are
(ii) Test tube A halogenated at the a-position on treatment with chlorine or
•SC\oi- + 2MnO4 +16H+ ➔ 10CO2 + 2Mn2+ + 8H2O bromine in the presence of a small amount of red phosphorus
to give a-halo carboxylic acids. (1 mark)
(1 mark)
(b) (i) CH3COOH Br2/red P > CH2BrCOOH (1/2 mark)
(b) Isomers ofbutanol are:
,,ITITJeg Butan-1-ol, butan-2-ol, 2-methylpropanol,
r,,----,-~--------. ,,I t I t I t I t I t 1:: d; dx2-y2
2-methylpropan -2-ol. (1/2 mark)
r
~o
Acidic strength in isomeric alcohols varies as follows:
i If If If If If Avd~:;.,~:r~of ', f f f t2g
The acidic character ofalcohols is due to the polar nature of0-H
Free metal ion spherical crystal dxy dyz dzx
field Spliting of d-orbital in bond. An electron-releasing group (-CH 3, -C2H5) increases
octahedral crystal field electron density on oxygen tending to decrease the polarity
(2 marks) of O-H bond 2-methylpropan-2-ok 2-methylpropanol
, Since L1o <Pit will form an outer orbital complex < butan-2-ol < butan-1-ol (1/2 mark)
ns in the 3d orbital will not pair up. ( 1/2 mark) (c) An organic compound A is a Grignard reagent: RMgX
{1/2 mark) Bis a ketone RCOR'
OH 1t2 = 0.528 atm
I (1/2 Ill
A+ B ~ H3C-C -CH 2-C H3 Osmotic pressure is directly proportional to
temperature.
I
CH3 Thus, the osmotic pressure of cane sugar can (1/2
(2-methylbutan-2-ol) be deer
by decreasing the temperature.
(1/2
Ketones lead to the formation of tertiary alcoh
ol, so the OR
compound Bis butan-2-one and A is CH3 MgB
r (a) While giving intravenous injection to
(1/2 + 1/2 mark) the patient&
utmost care of concentration of the solution is
0 to be take
the solution must have same concentration as
II
H3C-C -CH2-CH 3 + CH3MgBr ~
that of ht
cells.
Butanone (1
Methyl magnesium If the solution becomes more concentrated
bromide than
concentration of the blood it will lead to
OMgBr the s • .
I of blood cells and fluid will start flowing out
H+/DU. HCl ) ' becaUSe
H3C-y -CH 2-C H3 endosmosis.
(1 rn
CH3 OH If the solution is less concentrated than the conc
entrati
I of the blood it will lead to swelling of bloo
H 3C-C -CH2-CH d cells. Bo
3 situations are life-threatening.
I (b) 2C6H5OH ~ (C6H5OH)i (1/2
CH3 Initial conce
ntration : C O
2-methylbutan-2-ol Final concentration : C (1 - a) Caln
(1 mark) where a. is degree of association.
33. (a) Depression in the freezing poin Experimentally, phenol is 73% associated.
t is a colligative
property. In dilute solutions the depression of freez Hence a.= 0.73
ing point
(~Ti) is directly proportional to the molal conc Relation between i (van't Hoff factor) and a. is
en~ration of given as:
the solute in a solution. _ (1-i ) •
(1 mark) a= (
From the graph it is interpreted that Solution ) , where n for phenol = 2 as phenol acts as
2 shows more 1 dimer.
depression in freezing point 1--
n
1 M Al(NO3h has higher i value (i = 3) than association is taking place.
1 M glucose (1/ln wt)
(i = 1) Substituting the values :
(1/2 mark)
1 M Al(NO3h will have higher depression,
hence solution 0.73 = (l-i )
2 is Al(NO3h solution and solution 1 is glucose
solution. (+o.5)
(1/lmark) . 0.73
(b) 1t = (n2/V) RT I= 1-- = 0.635
(1/2 mark) (1/2 mark)
Given re= 2.64 atm 2
Let V1 =V Depression in freezing point can be calculated
as:
V2 = SV(On dilution by 5 times) AT1= iK m= iK (
1 1 wb )
7t1 (n/V1
-=- --= --) Mbxwa
7t2 (n/V2) (1 mark) Kt= 5.12 K Kg/mol, wb = 2 x 10-2 kg= 20 g, w
a= 1kg, Mb= 94
2.64 (n/V) (1 mark)
- =-~
7t2(n/5V) 11.y 0.635 X 5.12 X 20
u 1= - - - - - = 0.691 K (1/2 markl
94

, • 1. I.'·:

' Class 12