Revision date: 18/05/2021

SAFETY DATA SHEET

NEXBASE™ 4+

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name NEXBASE™ 4+

Product number ID 21177

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Distribution of substance (ES01a), Formulation & (re)packing of substances and mixtures
(ES02), Uses in coatings (ES03a-c), Use in cleaning agents (ES04a-c), Use in oil and gas
field drilling and production operations (ES05a-b), Metal working fluids/rolling oils (ES07a-b),
Use as binders and release agents (ES10a-b), Use in agrochemicals (ES11b-c), Rubber
production and processing (ES19), Polymer processing (ES21a-b), Lubricants (ES6a-e),
Laboratory chemical (ES17a-b), Water treatment chemicals (ES22a-b), Explosives
manufacture & use (ES18b), Functional fluids (ES13a-c).

1.3. Details of the supplier of the safety data sheet

Supplier Neste (Suisse) S.A.
16 Chemin des Coquelicots, 1214 Vernier, SWITZERLAND
Tel. +41 22 561 8000
[email protected] (chemical safety)

1.4. Emergency telephone number

National emergency telephone +358 800 147 111, +358 9 471 977, Poison Information Centre
number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Asp. Tox. 1 - H304

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H304 May be fatal if swallowed and enters airways.

Precautionary statements P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

P331 Do NOT induce vomiting.
P501 Dispose of contents/ container in accordance with local regulations.

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Contains Octadecene, reaction products with hexadecene, hydrogenated, Lubricating oils (petroleum),
C20-50, hydrotreated neutral oil-based

2.3. Other hazards

Other hazards Oil mist: May cause eye and respiratory system irritation. Repeated exposure may cause skin
dryness or cracking. Risk of soil and ground water contamination.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Octadecene, reaction products with hexadecene, > 55 %

hydrogenated
CAS number: 2241366-04-9 REACH registration number: 01-
2120836642-54

Classification
Asp. Tox. 1 - H304

Lubricating oils (petroleum), C20-50, hydrotreated neutral oil- < 45 %

based
CAS number: 72623-87-1 EC number: 276-738-4 REACH registration number: 01-
2119474889-13

Classification
Asp. Tox. 1 - H304

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Ingredient notes DMSO < 3% (IP 346).

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Unlikely to be hazardous by inhalation because of the low vapour pressure of the product at
ambient temperature. If spray/mist has been inhaled, proceed as follows. Remove person to
fresh air and keep comfortable for breathing. Get medical attention if symptoms are severe or
persist.

Ingestion Do not induce vomiting. Get medical attention.

Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical
attention if irritation persists after washing. Contact with hot product can cause serious
thermal burns.

Eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical attention if irritation persists after washing.

4.2. Most important symptoms and effects, both acute and delayed
General information Oil mist: May cause eye and respiratory system irritation. Entry into the lungs following
ingestion or vomiting may cause chemical pneumonitis.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

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Suitable extinguishing media Water spray, foam, dry powder or carbon dioxide.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture

Specific hazards Not known.

Hazardous combustion Carbon dioxide (CO2). Carbon monoxide (CO).

products

5.3. Advice for firefighters

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid breathing mist. Wear adequate protective equipment at all operations.

For emergency responders Prevent unauthorized access. Eliminate all ignition sources if safe to do so. Take
precautionary measures against static discharge.

6.2. Environmental precautions

Environmental precautions Avoid release to the environment. Stop leak if safe to do so. Avoid the spillage or runoff
entering drains, sewers or watercourses. Contain spillage with sand, earth or other suitable
non-combustible material. Inform the relevant authorities if environmental pollution occurs
(sewers, waterways, soil or air). Risk of soil and ground water contamination.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Immediately start clean-up of the liquid and contaminated soil. Large spills should be collected
mechanically (remove by pumping) for disposal. Small Spillages: Absorb spillage with sand or
other inert absorbent.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid heat, flames and other sources of ignition. Take precautionary measures against static
discharges. Use only in well-ventilated areas. Avoid inhalation of vapours and contact with
skin and eyes. Use personal protective equipment and/or local ventilation when needed. Do
not eat, drink or smoke when using this product. Wash hands and any other contaminated
areas of the body with soap and water before leaving the work site.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in accordance with local regulations. Store in a demarcated bunded area to prevent
release to drains and/or watercourses. Store in tightly-closed, original container in a dry, cool
and well-ventilated place. Protect from light. Suitable container materials: Stainless steel. Mild
steel.

7.3. Specific end use(s)

Specific end use(s) Not known.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

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Occupational exposure limits

Oil mist: 5 mg/m3 (8h) HTP 2020/FIN.
5 mg/m³, TWA PEL (OSHA) 5 mg/m³, TLV-TWA (ACGIH) 10 mg/m³, TLV-STEL (ACGIH).

PNEC Not available.

Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based (CAS: 72623-87-1)

DNEL Workers - Inhalation; Long term local effects: 5,4 mg/m³, (8h), Aerosol
Consumer - Inhalation; Long term local effects: 1,2 mg/m³, (24h), Aerosol
Available hazard data do not enable the derivation of a DNEL for dermal irritant
effects.
Available hazard data do not support the need for a DNEL to be established for
other health effects.

8.2. Exposure controls

Appropriate engineering Use only in well-ventilated areas. Use personal protective equipment and/or local ventilation
controls when needed.

Eye/face protection Spectacles.

Hand protection Wear protective gloves. It is recommended that gloves are made of the following material:
Polyvinyl chloride (PVC). Nitrile rubber. Protective gloves according to standard EN 374. The
breakthrough time for any glove material may be different for different glove manufacturers.
Change protective gloves regularly.

Other skin and body Protective clothing when needed.

protection

Respiratory protection Oil mist: Respiratory protection must be used if the airborne contamination exceeds the
recommended occupational exposure limit. Wear a respirator fitted with the following
cartridge: Combination filter, type A2/P2. Filter must be changed often enough. Gas and
combination filter cartridges should comply with European Standard EN14387.

Environmental exposure Store in a demarcated bunded area to prevent release to drains and/or watercourses.
controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Colourless. Clear.

Odour Almost odourless.

Odour threshold -

pH -

Melting point Pour point ≤ -12°C

Initial boiling point and range 350 - 550°C

Flash point > 220°C (ASTM D-92).

Upper/lower flammability or -
explosive limits

Vapour pressure < 0,1 hPa @ 20°C

Vapour density -

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Relative density 0.82 - 0.84 @ 15°C (ASTM D-4052).

Solubility(ies) Insoluble in water.

Partition coefficient log Kow: > 6

Auto-ignition temperature -

Decomposition Temperature -

Viscosity Kinematic viscosity typical value 20 mm2/s @ 40°C (ASTM D-445).

Explosive properties Not considered to be explosive.

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Other information Melting/pour point: ≤ - 12°C
Dynamic viscosity 37.1 mPa s @ +20°C
Dynamic viscosity ~ 50 mPa s @ + 15°C

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

Possibility of hazardous No potentially hazardous reactions known.
reactions

10.4. Conditions to avoid

Conditions to avoid Keep away from heat, sparks and open flame.

10.5. Incompatible materials

Materials to avoid Strong acids. Oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological effects Based on available data the classification criteria are not met.

Skin corrosion/irritation
Skin corrosion/irritation Based on available data the classification criteria are not met. Repeated exposure may cause
skin dryness or cracking.

Serious eye damage/irritation

Serious eye damage/irritation Based on available data the classification criteria are not met. Oil mist: May cause eye and
respiratory system irritation.

Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.

Germ cell mutagenicity

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Genotoxicity - in vitro Based on available data the classification criteria are not met.

Genotoxicity - in vivo Based on available data the classification criteria are not met.

Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.

IARC carcinogenicity Not listed.

NTP carcinogenicity Not listed.

Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.

Reproductive toxicity - Based on available data the classification criteria are not met.
development

Specific target organ toxicity - single exposure

STOT - single exposure Not classified as a specific target organ toxicant after a single exposure.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure Based on available data the classification criteria are not met.

Aspiration hazard
Aspiration hazard Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause
chemical pneumonitis.

Toxicological information on ingredients.

Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

Acute toxicity - oral

Notes (oral LD₅₀) LD₅₀ > 5000 mg/kg, Oral, Rat (OECD 401)

Acute toxicity - dermal

Notes (dermal LD₅₀) LD₅₀ > 2000 mg/kg, Dermal, Rabbit (OECD 402)

Acute toxicity - inhalation

Notes (inhalation LC₅₀) LC₅₀ > 5,53 mg/l, Inhalation, Rat (OECD 403)

SECTION 12: Ecological information

12.1. Toxicity
Toxicity Based on available data the classification criteria are not met.

Ecological information on ingredients.

Octadecene, reaction products with hexadecene, hydrogenated

Acute aquatic toxicity

Acute toxicity - fish LL₅₀, 96 hours: > 100 mg/l, (WAF)

Acute toxicity - aquatic LL₅₀, 48 hours: > 100 mg/l, Daphnia magna, (WAF)
invertebrates

Acute toxicity - aquatic EC₅₀, 72 hours: > 100 mg/l, Algae, (WAF)
plants NOEC: 100 mg/L (WAF)

Acute toxicity - NOEC, 3 hours: 1000 mg/l,

microorganisms

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Chronic aquatic toxicity

Chronic toxicity - fish early NOEL, 14 days: > 100 mg/l, (WAF)
life stage

Chronic toxicity - aquatic NOEL, 21 days: 100 mg/l, Daphnia magna, (WAF)
invertebrates

Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

Acute aquatic toxicity

Acute toxicity - fish LL₅₀, 96 hours: > 100 mg/l, Pimephales promelas (Fat-head Minnow)
NOEL, 96 hours: ≥ 100 mg/l,
WAF (OECD 203)

Acute toxicity - aquatic EL50, 48 hours: > 10000 mg/l, Daphnia magna
invertebrates NOEL, 48 - 96 hours: ≥ 10000 mg/l,
LL₅₀, 24 - 96 hours: > 10000 mg/l,
WAF (OECD 202)

Acute toxicity - aquatic NOEL, 72 hours: ≥ 100 mg/l, Pseudokirchneriella subcapitata

plants WAF (OECD 201)

Acute toxicity - NOEL, 10 minutes: > 1,93 mg/l, Micro-organisms (wastewater sludge)
microorganisms (DIN 38412, DIN38409)

Chronic aquatic toxicity

Chronic toxicity - fish early NOELR, 14 days: >= 1000 mg/l, Oncorhynchus mykiss (Rainbow trout)
life stage

Chronic toxicity - aquatic NOEL, 21 days: 10 mg/l, Daphnia magna

invertebrates WAF (OECD 211)

12.2. Persistence and degradability

Persistence and degradability The product is slowly degradable.

Stability (hydrolysis) No significant reaction in water.

Ecological information on ingredients.

Octadecene, reaction products with hexadecene, hydrogenated

Biodegradation Not determined.

Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

Biodegradation Non-rapidly degradable

(OECD 301 B)

12.3. Bioaccumulative potential

Bioaccumulative potential Possibly bioaccumulative.

Partition coefficient log Kow: > 6

12.4. Mobility in soil

Mobility The product is insoluble in water. Mainly non-volatile. Product can penetrate soil until reaching
the surface of ground water. The product contains substances which are bound to particulate
matter and are retained in soil.

12.5. Results of PBT and vPvB assessment

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Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB. (Anthracene < 0,1
assessment %)

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Dispose of this material and its container to hazardous or
special waste collection point. When handling waste, the safety precautions applying to
handling of the product should be considered. Care should be taken when handling emptied
containers that have not been thoroughly cleaned or rinsed out. Waste packaging should be
collected for reuse or recycling.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID). No DOT label requirement noted.

14.1. UN number
UN No. (ADR/RID) -

14.2. UN proper shipping name

Proper shipping name -
(ADR/RID)

14.3. Transport hazard class(es)

ADR/RID class -

14.4. Packing group

ADR/RID packing group -

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations US Federal: Not listed under SARA Section 313.
To the best of our knowledge, this product does not contain any substances listed under
California Proposition 65.

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EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Commission Regulation (EU) No 2015/830 of 28 May 2015.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).

15.2. Chemical safety assessment

A chemical safety assessment has been carried out.

Inventories
EU - EINECS/ELINCS
Yes

US - TSCA
Yes
To the best of our knowledge, the product components are not listed on any US national/regional regulatory lists except the
TSCA inventory.

SECTION 16: Other information

Abbreviations and acronyms PEL = Permissible Exposure Limit

used in the safety data sheet OSHA = Occupational Safety and Health Administration
NTP = National Toxicology Program

Key literature references and Regulations, databases, literature, own research. The manufacturer's SDS. Chemical Safety
sources for data Report Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based, 2017.

Revision comments This is the first issue.

Revision date 18/05/2021

SDS number 6580

Hazard statements in full H304 May be fatal if swallowed and enters airways.

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Exposure scenario
Distribution of Substance

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES01a

1. Title of exposure scenario

Main title Distribution of Substance

Process scope Loading (including marine vessel/barge, rail/road car and IBC loading) and repacking
(including drums and small packs) of substance, including its sampling, storage, unloading
distribution and associated laboratory activities.

Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category ERC5 Use at industrial site leading to inclusion into/onto article
ERC6a Use of intermediate
ERC6b Use of reactive processing aid at industrial site (no inclusion into or onto article)
ERC6c Use of monomer in polymerisation processes at industrial site (inclusion or not
into/onto article)
ERC6d Use of reactive process regulators in polymerisation processes at industrial site
(inclusion or not into/onto article)
ERC7 Use of functional fluid at industrial site

SPERC ESVOC SPERC 1.1b.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including
weighing)
PROC15 Use as laboratory reagent.

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used

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Distribution of Substance

Fraction of EU tonnage used in region: 0.1

Regional use tonnage: 24 000 tonnes/year
Fraction of Regional tonnage used locally: 0.002
Annual site tonnage: 48 tonnes
Maximum daily site tonnage: 2.4 tonnes

Frequency and duration of use

Continuous release.
Emission days: 20 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (initial release prior to RMM): 0.0001

Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 0.000001

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0.00001

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by terrestrial secondary poisoning.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 140 tonne/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 90%.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

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Distribution of Substance

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.017

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.004

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Formulation & (Re)packing of Substances and Mixtures

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES02

1. Title of exposure scenario

Main title Formulation & (Re)packing of Substances and Mixtures

Process scope Formulation, packing and re-packing of the substance and its mixtures in batch or continuous
operations, including storage, materials transfers, mixing, tabletting, compression,
pelletisation, extrusion, large and small scale packing, sampling, maintenance and associated
laboratory activities.

Environment
Environmental release ERC2 Formulation into mixture
category

SPERC ESVOC SPERC 2.2.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC5 Mixing or blending in batch processes
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including
weighing)
PROC14 Tabletting, compression, extrusion, pelletisation, granulation
PROC15 Use as laboratory reagent.

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 24 000 tonnes/year
Fraction of Regional tonnage used locally: 1
Annual site tonnage: 24 000 tonnes
Maximum daily site tonnage: 80 tonnes

Frequency and duration of use

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Formulation & (Re)packing of Substances and Mixtures

Continuous release.
Emission days: 300 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (after typical onsite RMMs consistent with EU Solvent
Emissions Directive requirements): 0.0025

Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 0.00002

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0.0001

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 1 200 tonne/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 0%.

Water Treat onsite wastewater (prior to receiving water discharge) to provide the required removal
efficiency of (%): ≥ 23,4 If discharging to domestic sewage treatment plant, no onsite
wastewater treatment required. Prevent discharge of undissolved substance to or recover
from onsite waste water.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

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3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.02

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.068

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Uses in Coatings - Industrial

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES03a

1. Title of exposure scenario

Main title Uses in Coatings - Industrial

Process scope Covers the use in coatings (paints, inks, adhesives, etc.), including exposures during use
(including materials receipt, storage, preparation and transfer from bulk and semi-bulk,
application by spray, roller, spreader, dip, flow, fluidised bed on production lines and film
formation) and equipment cleaning, maintenance and associated laboratory activities.

Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category

SPERC ESVOC SPERC 4.3a.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC5 Mixing or blending in batch processes
PROC7 Industrial spraying
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC10 Roller application or brushing
PROC13 Treatment of articles by dipping and pouring.
PROC15 Use as laboratory reagent.

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 10 tonnes/year
Fraction of Regional tonnage used locally: 1
Annual site tonnage: 10 tonnes
Maximum daily site tonnage: 0.5 tonnes

Frequency and duration of use

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Continuous release.
Emission days: 20 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (initial release prior to RMM): 0.98

Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 0.00007

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by terrestrial secondary poisoning.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 29 tonne/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 90%.

Water No wastewater treatment required. Prevent discharge of undissolved substance to or recover

from onsite waste water.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

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Risk-driving RCR - air compartment driven RCR(air) ≤ 0.017

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0053

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Uses in Coatings - Professional

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES03b

1. Title of exposure scenario

Main title Uses in Coatings - Professional

Process scope Covers the use in coatings (paints, inks, adhesives, etc.), including exposures during use
(including materials receipt, storage, preparation and transfer from bulk and semi-bulk,
application by spray, roller, brush, spreader by hand or similar methods and film formation)
and equipment cleaning, maintenance and associated laboratory activities.

Environment
Environmental release ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
category indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 8.3b.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC5 Mixing or blending in batch processes
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC10 Roller application or brushing
PROC11 Non industrial spraying
PROC13 Treatment of articles by dipping and pouring.
PROC15 Use as laboratory reagent.
PROC19 Manual activities involving hand contact

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used

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Fraction of EU tonnage used in region: 0.1

Regional use tonnage: 10 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.005 tonnes
Maximum daily site tonnage: 14 g

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.98

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.01

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.01

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 3 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

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Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Uses in Coatings - Consumer

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES03c

1. Title of exposure scenario

Main title Uses in Coatings - Consumer

Process scope Covers the use in coatings (paints, inks, adhesives, etc.), including exposures during use
(including product transfer and preparation, application by brush, spray by hand or similar
methods) and equipment cleaning.

Product category PC1 Adhesives, sealants.

PC4 Anti-freeze and de-icing products.
PC8a Excipient only
PC9a Coatings and paints, thinners, paint removers.
PC9b Fillers, putties, plasters, modelling clay.
PC9c Finger paints.
PC15 Non-metal-surface treatment products.
PC18 Ink and toners.
PC23 Leather treatment products
PC24 Lubricants, greases and release products.
PC31 Polishes and wax blends.
PC34 Textile dyes and impregnating products

Environment
Environmental release ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
category indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 8.3c.v1

2. Conditions of use affecting exposure (Non-industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 10 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.005 tonnes
Maximum daily site tonnage: 14 g

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

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Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.99

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.01

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.005

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 3 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Non-industrial - Health 1)

Other given operational conditions affecting Non-industrial exposure

Consumer information Do not ingest. If swallowed, then seek immediate medical assistance.

No additional risk management measures required.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures.

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Cleaning Agents - Industrial

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES04a

1. Title of exposure scenario

Main title Use in Cleaning Agents - Industrial

Process scope Covers the use as a component of cleaning products, including transfer from storage,
pouring/unloading from drums or containers and exposures during mixing/diluting in the
preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping,
automated and by hand), related equipment cleaning and maintenance.

Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category

SPERC ESVOC SPERC 4.4a.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC7 Industrial spraying
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC10 Roller application or brushing
PROC13 Treatment of articles by dipping and pouring.

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 10 tonnes/year
Fraction of Regional tonnage used locally: 1
Annual site tonnage: 1 tonnes
Maximum daily site tonnage: 50 kg

Frequency and duration of use

Continuous release.
Emission days: 20 days/year

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Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (initial release prior to RMM): 1.0

Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 3.0E-07

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by terrestrial secondary poisoning.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 2.9 tonne/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 70%.

Water No wastewater treatment required. Prevent discharge of undissolved substance to or recover

from onsite waste water.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.017

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

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4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Use in Cleaning Agents - Professional

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES04b

1. Title of exposure scenario

Main title Use in Cleaning Agents - Professional

Process scope Covers the use as a component of cleaning products, including pouring/unloading from drums
or containers and exposures during mixing/diluting in the preparatory phase and cleaning
activities (including spraying, brushing, dipping, wiping, automated and by hand).

Environment
Environmental release ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
category indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 8.4b.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC10 Roller application or brushing
PROC11 Non industrial spraying
PROC13 Treatment of articles by dipping and pouring.
PROC19 Manual activities involving hand contact

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 1 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.0005 tonnes
Maximum daily site tonnage: 1.4 g

Frequency and duration of use

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Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.02

Emission factor - water Release fraction to wastewater from wide dispersive use: 1.0E-06

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Technical measures Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 0.3 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water No wastewater treatment required. Prevent discharge of undissolved substance to or recover

from onsite waste water.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

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Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Cleaning Agents - Consumer

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES04c

1. Title of exposure scenario

Main title Use in Cleaning Agents - Consumer

Process scope Covers general exposures to consumers arising from the use of household products sold as
washing and cleaning products, aerosols, coatings, de-icers, lubricants and air care products.

Product category PC3 Air care products.

PC4 Anti-freeze and de-icing products.
PC8a Excipient only
PC9a Coatings and paints, thinners, paint removers.
PC24 Lubricants, greases and release products.
PC35 Washing and cleaning products
PC38 Welding and soldering products, flux products

Environment
Environmental release ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
category indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 8.4c.v1

2. Conditions of use affecting exposure (Non-industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 1 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.0005 tonnes
Maximum daily site tonnage: 1.4 g

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.95

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.025

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.025

Environmental factors not influenced by risk management measures

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Dilution Local freshwater dilution factor: 10

Local marine water dilution factor: 100

Risk management measures

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 0.3 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Non-industrial - Health 1)

Other given operational conditions affecting Non-industrial exposure

Consumer information Do not ingest. If swallowed, then seek immediate medical assistance.

No additional risk management measures required.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures.

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Oil and Gas Field Drilling and Production Operations - Industrial

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES05a

1. Title of exposure scenario

Main title Use in Oil and Gas Field Drilling and Production Operations - Industrial

Process scope Offshore and onshore oil field well drilling (including drilling muds use and well cleaning) and
hydraulic fracturing operations; including material transfers, on-site formulation of
drilling/fracturing fluid, well head/well bore operations, shaker room activities and related
maintenance.

Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category

SPERC Not determined.

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 1
Regional use tonnage: 100 tonnes/year
Fraction of Regional tonnage used locally: N/A
Annual site tonnage: N/A tonnes
Maximum daily site tonnage: N/A

Frequency and duration of use

Emission days: N/A

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (initial release prior to RMM): N/A

Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): N/A

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Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: N/A
Local marine water dilution factor: N/A

Risk management measures

Technical measures Prevent environmental discharge consistent with regulatory requirements.

STP details Not determined.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water Not determined.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Quantitative exposure and risk assessment not possible due to lack of emissions to aquatic
environment. Qualitative approach used to conclude safe use.

4. Guidance to check compliance with the exposure scenario (Environment 1)

OFFSHORE DRILLLING: Discharge to aquatic environment is restricted by law and industry

prohibits release. OSPAR Commission 2009. Discharges, Spills and Emissions from Offshore
Oil and Gas Installations in 2007, including the assessment of data reported in 2006 and
2007. ONSHORE DRILLING: Environmental releases are minimized during onshore drilling
operations; waste recycling and disposal is managed according to national and/or local
regulations. International Finance Corporation 2007. Environmental, Health, and Safety
Guidelines: onshore oil and gas development. Mining Waste Directive (2006/21/EC),
European Waste Directive (2008/98/EC) and national transpositions, e.g. Novelle des
Kreislaufwirtschaftsgesetzes (KrWG) in Germany.

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Use in Oil and Gas Field Drilling and Production Operations - Professional

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES05b

1. Title of exposure scenario

Main title Use in Oil and Gas Field Drilling and Production Operations - Professional

Process scope Offshore and onshore oil field well drilling (including drilling muds use and well cleaning) and
hydraulic fracturing operations; including material transfers, on-site formulation of
drilling/fracturing fluid, well head/well bore operations, shaker room activities and related
maintenance.

Environment
Environmental release ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
category outdoor)

SPERC Not determined.

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 1
Regional use tonnage: 100 tonnes/year
Fraction of Regional tonnage used locally: N/A
Annual site tonnage: N/A tonnes
Maximum daily site tonnage: N/A

Frequency and duration of use

Emission days: N/A

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): N/A

Emission factor - water Release fraction to wastewater from wide dispersive use: N/A

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Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: N/A
Local marine water dilution factor: N/A

Risk management measures

Technical measures Prevent environmental discharge consistent with regulatory requirements.

STP details Not determined.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water Not determined.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Quantitative exposure and risk assessment not possible due to lack of emissions to aquatic
environment. Qualitative approach used to conclude safe use.

4. Guidance to check compliance with the exposure scenario (Environment 1)

OFFSHORE DRILLING: Discharge to aquatic environment is restricted by law and industry

prohibits release. OSPAR Commission 2009. Discharges, Spills and Emissions from Offshore
Oil and Gas Installations in 2007, including the assessment of data reported in 2006 and
2007. ONSHORE DRILLING: Environmental releases are minimized during onshore drilling
operations; waste recycling and disposal is managed according to national and/or local
regulations. International Finance Corporation 2007. Environmental, Health and Safety
Guidelines: onshore oil and gas development. Mining Waste Directive (2006/21/EC).
European Waste Directive (2008/98/EC) and national transpositions, e.g. Novelle des
Kreislaufwirtschaftgesetzes (KrWG) in Germany.

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Metal Working Fluids/Rolling Oils - Industrial

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES07a

1. Title of exposure scenario

Main title Use in Metal Working Fluids/Rolling Oils - Industrial

Process scope Covers the use in formulated MWFs/rolling oils, including transfer operations, rolling and
annealing activities, cutting/machining activities, automated and manual application of
corrosion protections (including brushing, dipping and spraying), equipment maintenance,
draining and disposal of waste oils.

Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category

SPERC ESVOC SPERC 4.7a.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC5 Mixing or blending in batch processes
PROC7 Industrial spraying
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including
weighing)
PROC10 Roller application or brushing
PROC13 Treatment of articles by dipping and pouring.
PROC17 Lubrication at high energy conditions in metal working operations

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 100 tonnes/year
Fraction of Regional tonnage used locally: 1
Annual site tonnage: 100 tonnes
Maximum daily site tonnage: 5.0 tonnes

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Frequency and duration of use

Continuous release.
Emission days: 20 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (initial release prior to RMM): 0.02

Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 3.0E-06

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by terrestrial secondary poisoning.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 290 tonne/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 70%.

Water No wastewater treatment required. Prevent discharge of undissolved substance to or recover

from onsite waste water.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

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Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.017 Risk-driving RCR - water
compartment driven RCR(water) ≤ 0.0045

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Metal Working Fluids/Rolling Oils - Professional

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES07b

1. Title of exposure scenario

Main title Use in Metal Working Fluids/Rolling Oils - Professional

Process scope Covers the use in formulated MWFs, including transfer operations, open and contained
cutting/machining activities, automated and manual application of corrosion protections,
draining and working on contaminated/ reject articles and disposal of waste oils.

Environment
Environmental release ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
category indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 8.7c.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC5 Mixing or blending in batch processes
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including
weighing)
PROC10 Roller application or brushing
PROC11 Non industrial spraying
PROC13 Treatment of articles by dipping and pouring.
PROC17 Lubrication at high energy conditions in metal working operations

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 1000 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.5 tonnes
Maximum daily site tonnage: 1.4 kg

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Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.005

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.05

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.05

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by freshwater secondary poisoning.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 130 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

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Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0025

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0066

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use as Release Agents or Binders - Industrial

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES10a

1. Title of exposure scenario

Main title Use as Release Agents or Binders - Industrial

Process scope Covers the use as binders and release agents, including material transfers, mixing,
application (including spraying and brushing), mould forming and casting and handling of
waste.

Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category

SPERC ESVOC SPERC 4.10a.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC6 Calendering operations.
PROC7 Industrial spraying
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC10 Roller application or brushing
PROC13 Treatment of articles by dipping and pouring.
PROC14 Tabletting, compression, extrusion, pelletisation, granulation

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 1 tonnes/year
Fraction of Regional tonnage used locally: 1
Annual site tonnage: 1 tonnes
Maximum daily site tonnage: 50 kg

Frequency and duration of use

Continuous release.
Emission days: 20 days/year

Other given operational conditions affecting environmental exposure

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Emission factor - air Release fraction to air from process (initial release prior to RMM): 1.0

Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 3.0E-07

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by terrestrial secondary poisoning.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 2.9 tonne/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 80%.

Water No wastewater treatment required. Prevent discharge of undissolved substance to or recover

from onsite waste water.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.017 Risk-driving RCR - water
compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

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Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use as Release Agents or Binders - Professional

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES10b

1. Title of exposure scenario

Main title Use as Release Agents or Binders - Professional

Process scope Covers the use as binders and release agents, including material transfers, mixing,
application by spraying, brushing and handling of waste.

Environment
Environmental release ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
category indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 8.10b.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC6 Calendering operations.
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC10 Roller application or brushing
PROC11 Non industrial spraying
PROC14 Tabletting, compression, extrusion, pelletisation, granulation

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 1 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.0005 tonnes
Maximum daily site tonnage: 1.4 g

Frequency and duration of use

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Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.95

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.025

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.025

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 0.3 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

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Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Agrochemicals - Professional

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES11a

1. Title of exposure scenario

Main title Use in Agrochemicals - Professional

Process scope Use as an agrochemical excipient for application by manual or machine spraying, smokes and
fogging, including equipment clean-downs and disposal.

Environment
Environmental release ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
category indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 8.11a.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC4 Chemical production where opportunity for exposure arises
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC11 Non industrial spraying
PROC13 Treatment of articles by dipping and pouring.

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 0.1 tonnes/year
Fraction of Regional tonnage used locally: 0.002
Annual site tonnage: 0.0002 tonnes
Maximum daily site tonnage: 0.55 g

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.9

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Emission factor - water Release fraction to wastewater from wide dispersive use: 0.01

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.09

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 0.12 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

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Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Agrochemicals - Consumer

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES11b

1. Title of exposure scenario

Main title Use in Agrochemicals - Consumer

Process scope Covers the consumer use in agrochemicals in liquid and solid forms.

Product category PC12 Lawn and garden preparations (- fertilizers).

PC27 Plant protection products.

Environment
Environmental release ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
category indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 8.11b.v1

2. Conditions of use affecting exposure (Non-industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 0.1 tonnes/year
Fraction of Regional tonnage used locally: 0.002
Annual site tonnage: 0.0002 tonnes
Maximum daily site tonnage: 0.55 g

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.9

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.01

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.09

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

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STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 0.12 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Non-industrial - Health 1)

Other given operational conditions affecting Non-industrial exposure

Consumer information Do not ingest. If swallowed, then seek immediate medical assistance.

No additional risk management measures required.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures.

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Rubber Production and Processing - Industrial

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES19

1. Title of exposure scenario

Main title Rubber Production and Processing - Industrial

Process scope Manufacture of tyres and general rubber articles, including processing of raw (uncured)
rubber, handling and mixing of rubber additives, vulcanising, cooling and finishing.

Sector of use SU10 Formulation [mixing] of preparations and/or re-packaging

SU11 Manufacture of rubber products

Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category ERC6d Use of reactive process regulators in polymerisation processes at industrial site
(inclusion or not into/onto article)

SPERC ESVOC SPERC 4.19.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC5 Mixing or blending in batch processes
PROC6 Calendering operations.
PROC7 Industrial spraying
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including
weighing)
PROC13 Treatment of articles by dipping and pouring.
PROC14 Tabletting, compression, extrusion, pelletisation, granulation
PROC15 Use as laboratory reagent.
PROC21 Low energy manipulation and handling of substances bound in/on materials or
articles

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used

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Fraction of EU tonnage used in region: 0.1

Regional use tonnage: 10 tonnes/year
Fraction of Regional tonnage used locally: 1
Annual site tonnage: 10 tonnes
Maximum daily site tonnage: 0.5 tonnes

Frequency and duration of use

Continuous release.
Emission days: 20 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (initial release prior to RMM): 0.01

Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 0.00003

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0.0001

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by terrestrial secondary poisoning.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 29 tonne/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 0%.

Water No wastewater treatment required. Prevent discharge of undissolved substance to or recover

from onsite waste water.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

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Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.017

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0045

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Polymer Processing - Industrial

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES21a

1. Title of exposure scenario

Main title Use in Polymer Processing - Industrial

Process scope Processing of formulated polymers, including material transfers, additives handling (e.g.
pigments, stabilisers, fillers, plasticisers etc.), moulding, curing and forming activities, material
reworks, storage and associated maintenance.

Sector of use SU10 Formulation [mixing] of preparations and/or re-packaging

Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category

SPERC ESVOC SPERC 4.21a.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC5 Mixing or blending in batch processes
PROC6 Calendering operations.
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including
weighing)
PROC13 Treatment of articles by dipping and pouring.
PROC14 Tabletting, compression, extrusion, pelletisation, granulation
PROC21 Low energy manipulation and handling of substances bound in/on materials or
articles

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used

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Fraction of EU tonnage used in region: 0.1

Regional use tonnage: 10 tonnes/year
Fraction of Regional tonnage used locally: 1
Annual site tonnage: 10 tonnes
Maximum daily site tonnage: 0.5 tonnes

Frequency and duration of use

Continuous release.
Emission days: 20 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (initial release prior to RMM): 0.1

Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 0

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0.00001

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by terrestrial secondary poisoning.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 29 tonne/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 80%.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

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Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.017

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Polymer Processing - Professional

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES21b

1. Title of exposure scenario

Main title Use in Polymer Processing - Professional

Process scope Processing of formulated polymers, including material transfers, moulding and forming
activities, material reworks and associated maintenance.

Environment
Environmental release ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
category indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 8.21b.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC6 Calendering operations.
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC14 Tabletting, compression, extrusion, pelletisation, granulation
PROC21 Low energy manipulation and handling of substances bound in/on materials or
articles

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 10 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.005 tonnes
Maximum daily site tonnage: 14 g

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

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Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.98

Emission factor - water Release fraction to wastewater from wide dispersive use: 0,01

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0,01

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 3 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

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Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Lubricants - Industrial

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES06a

1. Title of exposure scenario

Main title Lubricants - Industrial

Process scope Covers the use of formulated lubricants in closed and open systems, including transfer
operations, operation of machinery/engines and similar articles, reworking on reject articles,
equipment maintenance and disposal of wastes.

Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category ERC7 Use of functional fluid at industrial site

SPERC ESVOC SPERC 4.6a.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC7 Industrial spraying
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including
weighing)
PROC10 Roller application or brushing
PROC13 Treatment of articles by dipping and pouring.
PROC17 Lubrication at high energy conditions in metal working operations
PROC18 General greasing/lubrication at high kinetic energy conditions

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 2 000 tonnes/year
Fraction of Regional tonnage used locally: 0.05
Annual site tonnage: 100 tonnes
Maximum daily site tonnage: 5.0 tonnes

Frequency and duration of use

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Continuous release.
Emission days: 20 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (initial release prior to RMM): 0.0005

Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 3.0E-06

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0.001

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by terrestrial secondary poisoning.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 290 tonne/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 70%.

Water No wastewater treatment required. Prevent discharge of undissolved substance to or recover

from onsite waste water.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

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Risk-driving RCR - air compartment driven RCR(air) ≤ 0.017

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0045

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Lubricants - Professional

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES06b, ES06c

1. Title of exposure scenario

Main title Lubricants - Professional

Process scope Covers the use of formulated lubricants within closed or contained systems, including
incidental exposures during material transfers, operation of engines and similar articles,
equipment maintenance and disposal of waste oil.

Environment
Environmental release Low environmental release:
category ERC9a Widespread use of functional fluid (indoor)
ERC9b Widespread use of functional fluid (outdoor)
High environmental release:
ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 9.6b.v1 ESVOC SPERC 8.6c.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including
weighing)
PROC10 Roller application or brushing
PROC11 Non industrial spraying
PROC13 Treatment of articles by dipping and pouring.
PROC17 Lubrication at high energy conditions in metal working operations
PROC18 General greasing/lubrication at high kinetic energy conditions
PROC20 Use of functional fluids in small devices

2. Conditions of use affecting exposure (Industrial - Environment 1)

Control of environmental exposure

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Environmental release Low environmental release:

category ERC9a Widespread use of functional fluid (indoor)
ERC9b Widespread use of functional fluid (outdoor)

SPERC ESVOC SPERC 9.6b.v1

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 15 000 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 7.6 tonnes
Maximum daily site tonnage: 21 kg

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.01

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.01

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.01

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 1 600 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

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2. Conditions of use affecting exposure (Industrial - Environment 2)

Control of environmental exposure

Environmental release High environmental release:
category ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 8.6c.v1

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 100 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.05 tonnes
Maximum daily site tonnage: 0.14 kg

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.005

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.05

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.05

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via on-site sewage treatment: 94.7%
Removal efficiency (total): 94.7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 29 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

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Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Low environmental release:

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0051
Risk-driving RCR - water compartment driven RCR(water) ≤ 0.012

High environmental release:

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022
Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0041

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Lubricants - Consumer

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES06d, ES06e

1. Title of exposure scenario

Main title Lubricants - Consumer

Process scope Covers the use of formulated lubricants within closed or contained systems, including
incidental exposures during material transfers, operation of engines and similar articles,
equipment maintenance and disposal of waste oil.

Product category PC1 Adhesives, sealants.

PC24 Lubricants, greases and release products.
PC31 Polishes and wax blends.

Environment
Environmental release Low environmental release:
category ERC9a Widespread use of functional fluid (indoor)
ERC9b Widespread use of functional fluid (outdoor)
High environmental release:
ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 9.6d.v1 ESVOC SPERC 8.6e.v1

2. Conditions of use affecting exposure (Non-industrial - Environment 1)

Control of environmental exposure (Non-industrial)

Environmental release Low environmental release:
category ERC9a Widespread use of functional fluid (indoor)
ERC9b Widespread use of functional fluid (outdoor)

SPERC ESVOC SPERC 9.6d.v1

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 5 000 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 2.5 tonnes
Maximum daily site tonnage: 6.8 kg/day

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

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Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.01

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.01

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.01

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 630 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Non-industrial - Environment 2)

Control of environmental exposure (Non-industrial)

Environmental release High environmental release:
category ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
outdoor)

SPERC ESVOC SPERC 8.6e.v1

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 100 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.05 tonnes
Maximum daily site tonnage: 0.14 kg

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.005

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.05

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.05

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Lubricants - Consumer

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 29 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Non-industrial - Health 1)

Other given operational conditions affecting Non-industrial exposure

Consumer information Do not ingest. If swallowed, then seek immediate medical assistance.

No additional risk management measures required.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Low environmental release:

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0025
Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0066

High environmental release:

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022
Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0041

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures.

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Laboratories - Industrial

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES17a

1. Title of exposure scenario

Main title Use in Laboratories - Industrial

Process scope Use of the substance within laboratory settings, including material transfers and equipment
cleaning.

Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category

SPERC Not determined.

Worker
Process category PROC10 Roller application or brushing
PROC15 Use as laboratory reagent.

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 0.1 tonnes/year
Fraction of Regional tonnage used locally: 1
Annual site tonnage: 0.1 tonnes
Maximum daily site tonnage: 5 kg

Frequency and duration of use

Continuous release.
Emission days: 20 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (initial release prior to RMM): 0.025

Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 0.02

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0.0001

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

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Risk from environmental exposure is driven by terrestrial secondary poisoning.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 300 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 0%.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.016

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0079

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Laboratories - Professional

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES17b

1. Title of exposure scenario

Main title Use in Laboratories - Professional

Process scope Use of the substance within laboratory settings, including material transfers and equipment
cleaning.

Environment
Environmental release ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
category indoor)

SPERC ESVOC SPERC 8.17.v1

Worker
Process category PROC10 Roller application or brushing
PROC15 Use as laboratory reagent.

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 0.1 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.00005 tonnes
Maximum daily site tonnage: 0.14 g

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.5

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.5

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

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Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 0.03 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 0%.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use in Water Treatment Chemicals - Industrial

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES22a

1. Title of exposure scenario

Main title Use in Water Treatment Chemicals - Industrial

Process scope Covers the use of the substance for the treatment of water at industrial facilities in open and
closed systems.

Sector of use SU10 Formulation [mixing] of preparations and/or re-packaging

Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category

SPERC ESVOC SPERC 3.22a.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC13 Treatment of articles by dipping and pouring.

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 0.1 tonnes/year
Fraction of Regional tonnage used locally: 1
Annual site tonnage: 0.1 tonnes
Maximum daily site tonnage: 0.33 kg

Frequency and duration of use

Continuous release.
Emission days: 300 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (initial release prior to RMM): 0.05

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Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 0.95

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94.7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 19 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 0%.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.014

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.017

4. Guidance to check compliance with the exposure scenario (Environment 1)

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Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Use in Water Treatment Chemicals - Professional

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES22b

1. Title of exposure scenario

Main title Use in Water Treatment Chemicals - Professional

Process scope Covers the use of the substance for the treatment of water in open and closed systems.

Environment
Environmental release ERC8f Widespread use leading to inclusion into/onto article (outdoor)
category

SPERC ESVOC SPERC 8.22b.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC13 Treatment of articles by dipping and pouring.

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 0.1 tonnes/year
Fraction of Regional tonnage used locally: 1
Annual site tonnage: 0.1 tonnes
Maximum daily site tonnage: 0.27 kg

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.01

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.99

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Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 18 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCr(air) ≤ 0.0066

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.015

4. Guidance to check compliance with the exposure scenario (Environment 1)

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Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Explosives Manufacture and Use - Professional

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES18b

1. Title of exposure scenario

Main title Explosives Manufacture and Use - Professional

Process scope Covers exposures arising from the manufacture and use of slurry explosives (including
materials transfer, mixing and charging) and equipment cleaning.

Environment
Environmental release ERC8e Widespread use of reactive processing aid (no inclusion into or onto article, outdoor)
category

SPERC Not determined.

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC5 Mixing or blending in batch processes
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 0.1 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.00005 tonnes
Maximum daily site tonnage: 0.14 g

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.001

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.02

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.01

Environmental factors not influenced by risk management measures

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Dilution Local freshwater dilution factor: 10

Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by freshwater sediment.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 0.03 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Not determined.

Water No wastewater treatment required.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

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3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use as Functional Fluids - Industrial

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES13a

1. Title of exposure scenario

Main title Use as Functional Fluids - Industrial

Process scope Use as functional fluids e.g. cable oils, transfer oils, coolants, insulators, refrigerants,
hydraulic fluids in industrial equipment, including maintenance and related material transfers.

Environment
Environmental release ERC7 Use of functional fluid at industrial site
category

SPERC ESVOC SPERC 7.13a.v1

Worker
Process category PROC1 Chemical production or refinery in closed process without likelihood of exposure or
processes with equivalent containment conditions
PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition
PROC4 Chemical production where opportunity for exposure arises
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including
weighing)

2. Conditions of use affecting exposure (Industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 100 tonnes/year
Fraction of Regional tonnage used locally: 0.1
Annual site tonnage: 10 tonnes
Maximum daily site tonnage: 500 kg

Frequency and duration of use

Continuous release.
Emission days: 20 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from process (initial release prior to RMM): 0.0005

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Emission factor - water Release fraction to wastewater from process (initial release prior to RMM): 3.0E-06

Emission factor - soil Release fraction to soil from process (initial release prior to RMM): 0.001

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

Good practice Common practices vary across sites, thus conservative process release estimates used.

Risk from environmental exposure is driven by terrestrial secondary poisoning.

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Removal efficiency (total): 94,7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 29 tonne/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil
Air Treat air emission to provide a typical removal efficiency of 0%.

Water No wastewater treatment required. Prevent discharge of undissolved substance to or recover

from onsite waste water.

Soil Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Risk management measures

Avoid splashing.
Avoid contact with contaminated tools and objects.
Handle in accordance with good industrial hygiene and safety practice.
Assumes a good basic standard of occupational hygiene is implemented.
Supervision in place to check that the RMMs in place are being used correctly and OCs
followed.

Additional advice Do not ingest. If swallowed, then seek immediate medical assistance.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.017

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.0039

4. Guidance to check compliance with the exposure scenario (Environment 1)

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Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures. Required removal efficiency for wastewater can be achieved using onsite/offsite
technologies, either alone or in combination. Required removal efficiency for air can be
achieved using onsite technologies, either alone or in combination. Further details on scaling
and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-
industries-libraries.html).

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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Exposure scenario
Use as Functional Fluids - Consumer

Identification

Product name Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based

CAS number 72623-87-1

Version number 2017

Es reference ES13c

1. Title of exposure scenario

Main title Use as Functional Fluids - Consumer

Process scope Use of sealed items containing functional fluids e.g. transfer oils, hydraulic fluids, refrigerants.

Product category PC16 Heat transfer fluids.

PC17 Hydraulic fluids.

Environment
Environmental release ERC9a Widespread use of functional fluid (indoor)
category ERC9b Widespread use of functional fluid (outdoor)

SPERC ESVOC SPERC 9.13c.v1

2. Conditions of use affecting exposure (Non-industrial - Environment 1)

Product characteristics
Substance is complex UVCB. Predominantly hydrophobic.

Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage: 100 tonnes/year
Fraction of Regional tonnage used locally: 0.0005
Annual site tonnage: 0.05 tonnes
Maximum daily site tonnage: 0.14 kg/day

Frequency and duration of use

Continuous release.
Emission days: 365 days/year

Other given operational conditions affecting environmental exposure

Emission factor - air Release fraction to air from wide dispersive use (regional only): 0.05

Emission factor - water Release fraction to wastewater from wide dispersive use: 0.025

Emission factor - soil Release fraction to soil from wide dispersive use (regional only): 0.025

Environmental factors not influenced by risk management measures

Dilution Local freshwater dilution factor: 10
Local marine water dilution factor: 100

Risk management measures

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Revision date: 18/05/2021

Use as Functional Fluids - Consumer

STP details Estimated substance removal from wastewater via domestic sewage treatment: 94.7%
Maximum allowable site tonnage (Msafe), based on release following total wastewater
treatment removal: 29 kg/day
Assumed domestic sewage treatment plant flow (m³/day):
2000.

Conditions and measures related to external treatment of waste for disposal

Waste treatment External treatment and disposal of waste should comply with applicable local and/or national
regulations.

Conditions and measures related to external recovery of waste

Recovery method External recovery and recycling of waste should comply with applicable local and/or national
regulations.

2. Conditions of use affecting exposure (Non-industrial - Health 1)

Other given operational conditions affecting Non-industrial exposure

Consumer information Do not ingest. If swallowed, then seek immediate medical assistance.

No additional risk management measures required.

3. Exposure estimation (Environment 1)

Assessment method Used Petrorisk model. (Hydrocarbon Block Method)

Risk-driving RCR - air compartment driven RCR(air) ≤ 0.0022

Risk-driving RCR - water compartment driven RCR(water) ≤ 0.004

4. Guidance to check compliance with the exposure scenario (Environment 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,
thus, scaling may be necessary to define appropriate site-specific risk management
measures.

3. Exposure estimation (Health 1)

Qualitative approach used to conclude safe use.

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