Paint Manufacturing Process: Pigments
Paint Manufacturing Process: Pigments
Prime pigments are those that contribute to both wet and dry hide in paint. Titanium dioxide
(TiO2 ) is the most costly pigment and it contributes directly to a paint's wet hide, while providing
whiteness Colorants are prime pigments that provide the actual color within the can.
Inorganic colorants: are the duller, earthy colors and are more durable for exterior
paint application. Examples of these kinds of pigments include red oxide, yellow ochre
and umber.
Alkyd (oil) based binders are made from various oil derivatives such as linseed oil, tung
oil, and soya oil. Traditional alkyd paints dry to a very hard finish and provide superior
adhesion and flow and leveling; however, they will yellow in light colors and are prone
to oxidation and chalking when used on exterior surfaces. As technology and VOC
restrictions have changed over the years, fewer paints today are made with traditional
alkyd binders. A newer technology based on modified oil binders is available; alkyd
emulsion.. This type of hybrid binder gives you oil-like performance with the ease of
soap and water clean-up. Alkyd-emulsion paints dry harder, flow more smoothly than
typical latex paints; however, they may still yellow in lighter colors. If used on exterior
surfaces subjected to UV exposure, alkyd-emulsion paints may eventually oxidize, and
chalk over time.
performance characteristics .
Acrylic Paint and Ingredients
100% Acrylic binders: often used in exterior paints as the benefits include
adhesion (both wet and dry), fade resistance, alkali and efflorescence
resistance. 100% acrylic binders are typically regarded as the best overall
performing.
Adhesion under wet conditions allow for greater performance in blister, cracking and
peeling resistance.
UV fade resistance allows the painted surface to retain its color and sheen longer.
Alkali resistance means the paint is less likely to “burn" over fresh concrete or
masonry.
Vinyl acrylic, also called PVA, binders: often used in interior paints as the benefits
include scrub resistance and washability.
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Styrenated acrylic binders: often used in masonry primer/sealers and top coats due to
--- Provides a vehicle for the pigment and binder to get from the can
onto the surface
Solvents, or liquids, are the vehicle for allowing paint to get from the can to the
surfaces and these types of liquids differ depending on the type of paint. Combining
the pigments and binders, considered solids, with the liquids, creates the paint
coating you see in the paint can
Oil-based and alkyd paints: the liquid is typically paint thinner or other type of
solvent.
4 ,Whether created by a sand mill or a dispersion tank, the paste must now be thinned to produce
the final product. Transferred to large kettles, it is agitated with the proper amount of solvent for
the type of paint desired.
Quality Control
Paint manufacturers utilize an extensive array of quality control measures. The ingredients and the
manufacturing process undergo stringent tests, and the finished product is checked to insure that it
is of high quality. A finished paint is inspected for its density, fineness of grind, dispersion, and
viscosity. Paint is then applied to a surface and studied for bleed resistance, rate of drying, and
texture.
In terms of the paint's aesthetic components, color is checked by an experienced observer and by
spectral analysis to see if it matches a standard desired color. Resistance of the color to fading
caused by the elements is determined by exposing a portion of a painted surface to an arc light and
comparing the amount of fading to a painted surface that was not so exposed. The paint's hiding
power is measured by painting it over a black surface and a white surface. The ratio of coverage on
the black surface to coverage on the white surface is then determined, with .98 being high-quality
paint. Gloss is measured by determining the amount of reflected light given off a painted surface.
Tests to measure the paint's more functional qualities include one for mar resistance, which entails
scratching or abrading a dried coat of paint. Adhesion is tested by making a crosshatch, calibrated to
.07 inch (2 millimeters), on a dried paint surface. A piece of tape is applied to the crosshatch, then
pulled off; good paint will remain on the surface. Scrubbability is tested by a machine that rubs a
soapy brush over the paint's surface. A system also exists to rate settling. An excellent paint can sit
for six months with no settling and rate a ten. Poor paint, however, will settle into an immiscible
lump of pigment on the bottom of the can and rate a zero. Weathering is tested by exposing the
paint to outdoor conditions. Artificial weathering exposes a painted surface to sun, water, extreme
temperature, humidity, or sulfuric gases. Fire retardancy is checked by burning the paint and
determining its weight loss. If the amount lost is more than 10 percent, the paint is not considered
fire-resistant.
Byproducts/Waste
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A recent regulation (California Rule 66) concerning the emission of volatile organic compounds
(VOCs) affects the paint industry, especially manufacturers of industrial oil-based paints. It is
estimated that all coatings, including stains and varnishes, are responsible for 1.8 percent of the 2.3
million metric tons of VOCs released per year. The new regulation permits each liter of paint to
contain no more than 250 grams (8.75 ounces) of solvent. Paint manufacturers can replace the
solvents with pigment, fillers, or other solids inherent to the basic paint formula. This method
produces thicker paints that are harder to apply, and it is not yet known if such paints are long
lasting. Other solutions include using paint powder coatings that use no solvents, applying paint in
closed systems from which VOCs can be retrieved, using water as a solvent, or using acrylics that dry
under ultraviolet light or heat. A consumer with some unused paint on hand can return it to the
point of purchase for proper treatment.
A large paint manufacturer will have an in-house wastewater treatment facility that treats all liquids
generated on-site, even storm water run-off. The facility is monitored 24 hours a day, and the
Environmental Protection Agency (EPA) does a periodic records and systems check of all paint
facilities. The liquid portion of the waste is treated on-site to the standards of the local publicly
owned wastewater treatment facility; it can be used to make low-quality paint. Latex sludge can be
retrieved and used as fillers in other industrial products. Waste solvents can be recovered and used
as fuels for other industries. A clean paint container can be reused or sent to the local landfill.