PTN

PETROLEUM NAPHTHA

CAUTIONARY RESPONSE INFORMATION 4. FIRE HAZARDS 7. SHIPPING INFORMATION

4.1 Flash Point: 7.1 Grades of Purity: Currently not available
Common Synonyms Liquid Colorless Gasoline odor 20°F (approx.) C.C. 7.2 Storage Temperature: Ambient
Petroleum solvent 4.2 Flammable Limits in Air: 0.9%-6.0% 7.3 Inert Atmosphere: No requirement
Floats on water. Flammable vapor is produced. 4.3 Fire Extinguishing Agents: Foam,
7.4 Venting: Open (flame arrester) or pressure-
carbon dioxide, or dry chemical
vacuum
Keep people away. 4.4 Fire Extinguishing Agents Not to Be
Shut off ignition sources and call fire department. Used: Water may be ineffective. 7.5 IMO Pollution Category: Currently not available
Stay upwind and use water spray to ``knock down'' vapor. 4.5 Special Hazards of Combustion 7.6 Ship Type: Currently not available
Avoid contact with liquid. Products: Not pertinent 7.7 Barge Hull Type: Currently not available
Notify local health and pollution control agencies.
4.6 Behavior in Fire: Not pertinent
Protect water intakes.
4.7 Auto Ignition Temperature: 450°F 8. HAZARD CLASSIFICATIONS
(approx.)
FLAMMABLE. 8.1 49 CFR Category: Flammable liquid
Fire Flashback along vapor trail may occur. 4.8 Electrical Hazards: Not pertinent
8.2 49 CFR Class: 3
Vapor may explode if ignited in an enclosed area. 4.9 Burning Rate: 4 mm/min.
Extinguish with foam, dry chemical, or carbon dioxide. 8.3 49 CFR Package Group: II
4.10 Adiabatic Flame Temperature: Currently
Cool exposed containers with water. not available 8.4 Marine Pollutant: No
4.11 Stoichometric Air to Fuel Ratio: Not 8.5 NFPA Hazard Classification:
CALL FOR MEDICAL AID.
Exposure pertinent.
Category Classification
VAPOR 4.12 Flame Temperature: Currently not Health Hazard (Blue).......... 1
Not irritating to eyes, nose, or throat. available
Flammability (Red)............. 4
4.13 Combustion Molar Ratio (Reactant to
Instability (Yellow)............. 0
LIQUID Product): Not pertinent.
Harmful if swallowed. 4.14 Minimum Oxygen Concentration for 8.6 EPA Reportable Quantity: Not listed.
IF SWALLOWED and victim is CONSCIOUS, have victim drink water Combustion (MOCC): Not listed 8.7 EPA Pollution Category: Not listed.
or milk.
DO NOT INDUCE VOMITING. 8.8 RCRA Waste Number: Not listed
5. CHEMICAL REACTIVITY 8.9 EPA FWPCA List: Not listed
Effect of low concentrations on aquatic life is unknown.
Water Fouling to shoreline.
5.1 Reactivity with Water: No reaction
Pollution May be dangerous if it enters water intakes. 5.2 Reactivity with Common Materials: No 9. PHYSICAL & CHEMICAL
Notify local health and wildlife officials. reaction PROPERTIES
Notify operators of nearby water intakes. 5.3 Stability During Transport: Stable
9.1 Physical State at 15° C and 1 atm: Liquid
5.4 Neutralizing Agents for Acids and
Caustics: Not pertinent 9.2 Molecular Weight: Not pertinent
5.5 Polymerization: Not pertinent 9.3 Boiling Point at 1 atm: 207.0°F = 97.2°C =
1. CORRECTIVE RESPONSE ACTIONS 2. CHEMICAL DESIGNATIONS 5.6 Inhibitor of Polymerization: Not pertinent 370.4°K
Stop discharge 2.1 CG Compatibility Group: 33; 9.4 Freezing Point: Not pertinent
Contain Miscellaneous Hydrocarbon Mixtures 9.5 Critical Temperature: Not pertinent
Collection Systems: Skim 6. WATER POLLUTION
2.2 Formula: Not applicable 9.6 Critical Pressure: Not pertinent
Chemical and Physical Treatment: Burn; 2.3 IMO/UN Designation: 3.2/1255 6.1 Aquatic Toxicity:
Absorb 2.4 DOT ID No.: 1268 Currently not available 9.7 Specific Gravity: 0.74 at 20°C (liquid)
Clean shore line 2.5 CAS Registry No.: 8030-30-6 9.8 Liquid Surface Tension: 19–23 dynes/cm =
Salvage waterfowl 6.2 Waterfowl Toxicity: Currently not
2.6 NAERG Guide No.: 128 available 0.019–0.023 N/m at 20°C
2.7 Standard Industrial Trade Classification: 9.9 Liquid Water Interfacial Tension: 39–51
33429 6.3 Biological Oxygen Demand (BOD):
Currently not available dynes/cm = 0.039–0.051 N/m at 20°C
3. HEALTH HAZARDS 6.4 Food Chain Concentration Potential: 9.10 Vapor (Gas) Specific Gravity: Not pertinent
None 9.11 Ratio of Specific Heats of Vapor (Gas):
3.1 Personal Protective Equipment: Goggles or face shield (as for gasoline).
6.5 GESAMP Hazard Profile: Not listed (est.) 1.030
3.2 Symptoms Following Exposure: Inhalation of concentrated vapor may cause intoxication. Liquid is
not very irritating to skin or eyes but may get into lungs by aspiration. 9.12 Latent Heat of Vaporization: 130–150
3.3 Treatment of Exposure: INHALATION: remove victim to fresh air and treat symptoms. INGESTION: Btu/lb = 71–81 cal/g = 3.0–3.4 X 105 J/kg
have victim drink water or milk; do NOT induce vomiting. EYES: flush with water for 15 min. 9.13 Heat of Combustion: Currently not available
SKIN: wipe off and wash with soap and water. 9.14 Heat of Decomposition: Not pertinent
3.4 TLV-TWA: 400 ppm
9.15 Heat of Solution: Not pertinent
3.5 TLV-STEL: Not listed.
9.16 Heat of Polymerization: Not pertinent
3.6 TLV-Ceiling: Not listed.
3.7 Toxicity by Ingestion: Grade 2; LD50 = 0.5 to 5 g/kg 9.17 Heat of Fusion: Currently not available
3.8 Toxicity by Inhalation: Currently not available. 9.18 Limiting Value: Currently not available
3.9 Chronic Toxicity: None 9.19 Reid Vapor Pressure: Currently not
3.10 Vapor (Gas) Irritant Characteristics: Vapors are non-irritating to the eyes and throat. available
3.11 Liquid or Solid Characteristics: No appreciable hazard. Practically harmless to the skin.
3.12 Odor Threshold: Currently not available NOTES
3.13 IDLH Value: 1,000 ppm
3.14 OSHA PEL-TWA: 100 ppm
3.15 OSHA PEL-STEL: Not listed.
3.16 OSHA PEL-Ceiling: Not listed.
3.17 EPA AEGL: Not listed

JUNE 1999
PTN
PETROLEUM NAPHTHA

9.20 9.21 9.22 9.23

SATURATED LIQUID DENSITY LIQUID HEAT CAPACITY LIQUID THERMAL CONDUCTIVITY LIQUID VISCOSITY

Temperature Pounds per cubic foot Temperature British thermal unit per Temperature British thermal unit inch Temperature Centipoise
(degrees F) (degrees F) pound-F (degrees F) per hour-square foot-F (degrees F)

52 46.750 10 0.456 50 1.040 50 9.343

54 46.680 15 0.459 52 1.040 52 8.841
56 46.610 20 0.461 54 1.040 54 8.370
58 46.540 25 0.464 56 1.040 56 7.927
60 46.470 30 0.467 58 1.040 58 7.511
62 46.400 35 0.469 60 1.040 60 7.119
64 46.330 40 0.472 62 1.040 62 6.751
66 46.260 45 0.474 64 1.040 64 6.404
68 46.190 50 0.477 66 1.040 66 6.078
70 46.120 55 0.480 68 1.040 68 5.770
72 46.050 60 0.482 70 1.040 70 5.481
74 45.980 65 0.485 72 1.040 72 5.207
76 45.920 70 0.488 74 1.040 74 4.950
78 45.850 75 0.490 76 1.040 76 4.707
80 45.780 80 0.493 78 1.040 78 4.477
82 45.710 85 0.495 80 1.040 80 4.260
84 45.640 90 0.498 82 1.040 82 4.056
86 45.570 95 0.501 84 1.040 84 3.862
100 0.503 86 1.040 86 3.679
105 0.506 88 1.040 88 3.506
90 1.040 90 3.342
92 1.040 92 3.187
94 1.040 94 3.040
96 1.040 96 2.901
98 1.040 98 2.770
100 1.040 100 2.645

9.24 9.25 9.26 9.27

SOLUBILITY IN WATER SATURATED VAPOR PRESSURE SATURATED VAPOR DENSITY IDEAL GAS HEAT CAPACITY

Temperature Pounds per 100 pounds Temperature Pounds per square inch Temperature Pounds per cubic foot Temperature British thermal unit per
(degrees F) of water (degrees F) (degrees F) (degrees F) pound-F

I 90 0.094 N N
N 100 0.124 O O
S 110 0.163 T T
O 120 0.211
L 130 0.272 P P
U 140 0.347 E E
B 150 0.440 R R
L 160 0.553 T T
E 170 0.691 I I
180 0.856 N N
190 1.054 E E
200 1.290 N N
210 1.569 T T
220 1.897
230 2.281
240 2.728
250 3.247
260 3.846
270 4.535
280 5.323
290 6.221
300 7.241
310 8.394
320 9.695
330 11.160
340 12.790

JUNE 1999