PTE

1-PENTENE

CAUTIONARY RESPONSE INFORMATION 4. FIRE HAZARDS 7. SHIPPING INFORMATION

4.1 Flash Point: 7.1 Grades of Purity: Research: 99.9%; pure:
Common Synonyms Liquid Colorless Gasoline odor –60°F C.C.; 0°F O.C. 99.4%; technical: 97.0%
alpha-n-Amylene 4.2 Flammable Limits in Air: 1.4%-8.7% 7.2 Storage Temperature: Ambient
Propylethylene
Floats on water. Flammable vapor is produced. Boiling point is 86°F. 4.3 Fire Extinguishing Agents: Foam, dry 7.3 Inert Atmosphere: No requirement
chemical, or carbon dioxide. Stop flow of
7.4 Venting: Open (flame arrester) or pressure-
Evacuate. vapor.
vacuum
Keep people away. 4.4 Fire Extinguishing Agents Not to Be
Shut off ignition sources and call fire department. Used: Water may be ineffective. 7.5 IMO Pollution Category: C
Stay upwind and use water spray to ``knock down'' vapor. 4.5 Special Hazards of Combustion 7.6 Ship Type: 3
Avoid contact with vapor. Products: Not pertinent 7.7 Barge Hull Type: Currently not available
Notify local health and pollution control agencies.
4.6 Behavior in Fire: Containers may explode
Protect water intakes.
in fire. 8. HAZARD CLASSIFICATIONS
4.7 Auto Ignition Temperature: 527°F
FLAMMABLE. 8.1 49 CFR Category: Flammable liquid
Fire Flashback along vapor trail may occur. 4.8 Electrical Hazards: Currently not
available 8.2 49 CFR Class: 3
Containers may explode when heated.
Vapor may explode if ignited in an enclosed area. 4.9 Burning Rate: 9.1 mm/min. 8.3 49 CFR Package Group: I
Extinguish with dry chemical, foam, or carbon dioxide. 4.10 Adiabatic Flame Temperature: Currently 8.4 Marine Pollutant: No
Water may be ineffective on fire. not available 8.5 NFPA Hazard Classification:
Cool exposed containers with water.
4.11 Stoichometric Air to Fuel Ratio: 35.7
Category Classification
(calc.) Health Hazard (Blue).......... 2
CALL FOR MEDICAL AID.
Exposure 4.12 Flame Temperature: Currently not Flammability (Red)............. 4
VAPOR available
Instability (Yellow)............. 0
If inhaled, will cause dizziness. 4.13 Combustion Molar Ratio (Reactant to
Move to fresh air. Product): 10.0 (calc.) 8.6 EPA Reportable Quantity: Not listed.
If breathing has stopped, give artificial respiration. 4.14 Minimum Oxygen Concentration for 8.7 EPA Pollution Category: Not listed.
If breathing is difficult, give oxygen. Combustion (MOCC): Not listed 8.8 RCRA Waste Number: Not listed
LIQUID 8.9 EPA FWPCA List: Not listed
Harmful if swallowed. 5. CHEMICAL REACTIVITY
IF SWALLOWED and victim is CONSCIOUS, have victim drink water
or milk. 5.1 Reactivity with Water: No reaction 9. PHYSICAL & CHEMICAL
DO NOT INDUCE VOMITING. 5.2 Reactivity with Common Materials: No PROPERTIES
reaction
Effect of low concentrations on aquatic life is unknown. 5.3 Stability During Transport: Stable 9.1 Physical State at 15° C and 1 atm: Liquid
Water May be dangerous if it enters water intakes. 9.2 Molecular Weight: 70.13
5.4 Neutralizing Agents for Acids and
Pollution Notify local health and wildlife officials. Caustics: Not pertinent 9.3 Boiling Point at 1 atm: 85.8°F = 29.9°C =
Notify operators of nearby water intakes. 303.1°K
5.5 Polymerization: Not pertinent
5.6 Inhibitor of Polymerization: Not pertinent 9.4 Freezing Point: –265°F = –165°C = 108°K
9.5 Critical Temperature: 376.9°F = 191.6°C =
6. WATER POLLUTION 464.8°K
1. CORRECTIVE RESPONSE ACTIONS 2. CHEMICAL DESIGNATIONS 9.6 Critical Pressure: 588 psia = 40 atm = 4.05
Stop discharge 2.1 CG Compatibility Group: 30; Olefin 6.1 Aquatic Toxicity: MN/m2
Contain 2.2 Formula: CH3(CH2)2CH=CH2 655 ppm/1 hr/sunfish/lethal/fresh water
Collection Systems: Skim 9.7 Specific Gravity: 0.641 at 20°C (liquid)
2.3 IMO/UN Designation: 3.1/1108 6.2 Waterfowl Toxicity: Currently not
Chemical and Physical Treatment: Burn 2.4 DOT ID No.: 1108 9.8 Liquid Surface Tension: 16.5 dynes/cm =
available
Salvage waterfowl 2.5 CAS Registry No.: Currently not available 0.0165 N/m at 20°C
6.3 Biological Oxygen Demand (BOD): 0.8%
2.6 NAERG Guide No.: 127 (theor.), 0.5 day; 0.5% (theor.), 1 day 9.9 Liquid Water Interfacial Tension: (est.) 50
2.7 Standard Industrial Trade Classification: dynes/cm = 0.05 N/m at 20°C
51119 6.4 Food Chain Concentration Potential:
None 9.10 Vapor (Gas) Specific Gravity: 2.4
3. HEALTH HAZARDS 6.5 GESAMP Hazard Profile: 9.11 Ratio of Specific Heats of Vapor (Gas):
Bioaccumulation: 0 1.083
3.1 Personal Protective Equipment: Goggles or face shield (as for gasoline).
Damage to living resources: (2) 9.12 Latent Heat of Vaporization: 154.6 Btu/lb =
3.2 Symptoms Following Exposure: Acts as a simple asphyxiant or weak anesthetic in high vapor Human Oral hazard: (1)
concentrations. Similar to effects caused by gasoline vapors. 85.87 cal/g = 3.595 X 105 J/kg
Human Contact hazard: 0
3.3 Treatment of Exposure: INHALATION: remove victim from exposure. SKIN: wash with soap and Reduction of amenities: 0 9.13 Heat of Combustion: –19,359 Btu/lb =
water. EYES: flush with water. –10,755 cal/g = –450.29 X 105 J/kg
3.4 TLV-TWA: Not listed. 9.14 Heat of Decomposition: Not pertinent
3.5 TLV-STEL: Not listed. 9.15 Heat of Solution: Not pertinent
3.6 TLV-Ceiling: Not listed. 9.16 Heat of Polymerization: Not pertinent
3.7 Toxicity by Ingestion: Currently not available
9.17 Heat of Fusion: Currently not available
3.8 Toxicity by Inhalation: Currently not available.
9.18 Limiting Value: Currently not available
3.9 Chronic Toxicity: Currently not available
3.10 Vapor (Gas) Irritant Characteristics: Not irritating 9.19 Reid Vapor Pressure: Currently not
available
3.11 Liquid or Solid Characteristics: Not irritating
3.12 Odor Threshold: Currently not available
NOTES
3.13 IDLH Value: Not listed.
3.14 OSHA PEL-TWA: Not listed.
3.15 OSHA PEL-STEL: Not listed.
3.16 OSHA PEL-Ceiling: Not listed.
3.17 EPA AEGL: Not listed

JUNE 1999
PTE
1-PENTENE

9.20 9.21 9.22 9.23

SATURATED LIQUID DENSITY LIQUID HEAT CAPACITY LIQUID THERMAL CONDUCTIVITY LIQUID VISCOSITY

Temperature Pounds per cubic foot Temperature British thermal unit per Temperature British thermal unit inch Temperature Centipoise
(degrees F) (degrees F) pound-F (degrees F) per hour-square foot-F (degrees F)

15 41.850 0 0.493 15 0.943 -35 0.356

20 41.680 10 0.498 20 0.934 -30 0.344
25 41.500 20 0.502 25 0.924 -25 0.332
30 41.330 30 0.507 30 0.915 -20 0.322
35 41.160 40 0.512 35 0.905 -15 0.311
40 40.980 50 0.516 40 0.896 -10 0.302
45 40.810 60 0.521 45 0.887 -5 0.293
50 40.640 70 0.525 50 0.877 0 0.284
55 40.460 80 0.530 55 0.868 5 0.276
60 40.290 60 0.858 10 0.268
65 40.120 65 0.849 15 0.260
70 39.940 70 0.840 20 0.253
75 39.770 75 0.830 25 0.246
80 0.821 30 0.240
85 0.811 35 0.234
40 0.228
45 0.222
50 0.217
55 0.212
60 0.207
65 0.202

9.24 9.25 9.26 9.27

SOLUBILITY IN WATER SATURATED VAPOR PRESSURE SATURATED VAPOR DENSITY IDEAL GAS HEAT CAPACITY

Temperature Pounds per 100 pounds Temperature Pounds per square inch Temperature Pounds per cubic foot Temperature British thermal unit per
(degrees F) of water (degrees F) (degrees F) (degrees F) pound-F

I -70 0.167 -70 0.00280 0 0.330

N -60 0.253 -60 0.00414 25 0.344
S -50 0.374 -50 0.00596 50 0.358
O -40 0.540 -40 0.00841 75 0.372
L -30 0.764 -30 0.01162 100 0.386
U -20 1.061 -20 0.01577 125 0.400
B -10 1.448 -10 0.02104 150 0.413
L 0 1.945 0 0.02764 175 0.427
E 10 2.573 10 0.03579 200 0.440
20 3.359 20 0.04574 225 0.453
30 4.328 30 0.05774 250 0.466
40 5.512 40 0.07206 275 0.479
50 6.942 50 0.08898 300 0.491
60 8.654 60 0.10880 325 0.504
70 10.680 70 0.13180 350 0.516
80 13.070 80 0.15830 375 0.528
90 15.860 90 0.18850 400 0.540
100 19.090 100 0.22290 425 0.551
110 22.820 110 0.26160 450 0.563
120 27.070 120 0.30510 475 0.574
130 31.910 130 0.35350 500 0.585
140 37.370 140 0.40720 525 0.596
150 43.520 150 0.46640 550 0.607
160 50.400 160 0.53140 575 0.618
170 58.060 170 0.60240 600 0.628

JUNE 1999